This appendix contains tables listing the composition of austenitic, ferrite, martensitic, precipitation-hardenable, and duplex stainless steels and of Alloy Casting Institute heat- and corrosion-resisting casting alloys.

This appendix is a collection of tables listing the chemical compositions of wrought ferritic steels; wrought stainless steels; cast corrosion- and heat-resistant alloys; wrought iron-, nickel-, and cobalt-base alloys; cast nickel- and cobalt-base alloys; oxide-dispersion-strengthened alloys; and iron-, nickel- and cobalt-base filler metals.

This chapter provides a detailed discussion on the definitions, alloy classification, alloy selection, mechanical properties, hot gas corrosion resistance, and formability of heat-resistant high alloy steels. In addition, the applications of cast heat-resistant alloys are also discussed.

This chapter discusses the processes involved in heat treating of stainless steels, providing information on the classification, chemical compositions, and corrosion resistance of stainless steels and the effect of specific elements on the characteristics of iron-base alloys. Five groups of stainless steels are discussed: austenitic, ferritic, martensitic, precipitation-hardening, and duplex grades. The chapter also describes the heat treatment conditions that should be maintained for processing of stainless steels.

This article covers the metallurgy and properties of stainless steels. It provides composition information on all types of ferritic, austenitic, martensitic, duplex, and precipitation-hardening stainless steels, including proprietary and nonstandard grades, along with corresponding property and performance data. It also discusses the effect of various alloying elements on pitting, crevice corrosion, sensitization, stress-corrosion cracking, and oxidation resistance.

Ferritic stainless steels are essentially iron-chromium alloys with body-centered cubic crystal structures. Chromium content is usually in the range of 11 to 30%. The primary advantage of the ferritic stainless steels, and in particular the high-chromium, high-molybdenum grades, is their excellent stress-corrosion cracking resistance and good resistance to pitting and crevice corrosion in chloride environments. This chapter provides information on the classifications, properties, and general welding considerations of ferritic stainless steels. The emphasis is placed on intergranular corrosion, which is the most common cause of failure in ferritic stainless steel weldments. Two case histories involving intergranular corrosion failures of ferritic stainless steel weldments are included. A brief discussion on hydrogen embrittlement is also provided.

This chapter discusses material-related problems associated with coal-fired burners. It explains how high temperatures affect heat-absorbing surfaces in furnace combustion areas and in the convection pass of superheaters and reheaters. It describes how low-NOx combustion technology, intended to reduce NOx emissions, accelerates tube wall wastage. It also covers circumferential cracking in furnace waterwalls, thermal fatigue cracking induced by waterlances and water cannons, superheater-reheater corrosion, and erosion in fluidized-bed boilers.

With typical alloy systems, casting is often the most convenient method by which to produce components. This is true for stainless steels, both for corrosion-resisting and for heat-resisting applications. This chapter discusses stainless steel casting alloys and their metallurgy. Foundry methods are discussed to the degree they are specific to the stainless alloys.

Steels that resist corrosive attack from normal atmospheric exposure and contain a minimum of 10.5% Cr and 50% Fe are generally classified as stainless steels. Their special qualities lie in a chromium-rich oxide surface film that quickly regrows when damaged. This chapter discusses the classification, composition, properties, treatments, and applications of austenitic, ferritic, martensitic, duplex, precipitation-hardening, powder metallurgy, and cast stainless steels. It also reviews the history of stainless steels and provides information on alloy designation systems.

This chapter discusses the classification, composition, properties, and applications of five types of stainless steels: austenitic, ferritic, duplex, martensitic, and precipitation-hardening steels. It discusses the process involved in argon oxygen decarburization that is used to refine stainless steel. The chapter also provides information on the classification and composition of stainless steel castings. It concludes with a brief description of the Schaeffler constitution diagram which is useful in predicting the type of stainless steel as a function of its alloy content.

This chapter discusses the composition and classification of stainless steels and focuses on the processes involved in heat treatment and applications of these steels. The wrought and the cast stainless steels covered are ferritic, austenitic, duplex (ferritic-austenitic), martensitic, and precipitation-hardening. In addition, information on special considerations for stainless steel castings is also provided. The heat treatment processes explained in the chapter are preheating, annealing, stress relieving, hardening, tempering, austenite conditioning, heat aging, and nitride surface hardening. Finally, some special considerations for stainless steel castings are discussed.

This chapter discusses the compositions, mechanical properties, phase structure, stabilization, corrosion resistance, and advantages of austenitic stainless steels. Austenitic alloys are classified and reviewed in three groups: (1) lean alloys, such as 201 and 301, which are generally used when high strength or high formability is the main objective; (2) chromium nickel alloys used for high temperature oxidation resistance; and (3) chromium, molybdenum, nickel, and nitrogen alloys used for applications where corrosion resistance is the main objective.

Black liquor recovery boilers are an integral part of the kraft pulping process used in paper mills. Besides recovering chemicals for reuse, they also produce process steam. High operating temperatures and exposure to process chemicals and combustion byproducts make recovery boilers susceptible to corrosion. This chapter describes some of the problems that the pulp and paper industry has solved as well as ongoing issues and concerns. It includes an in-depth review of 304L cladding failures involving coextruded composite tubes used as floor tunes in the lower furnace, as superheater tubes, and for other purposes such as smelt openings. It provides detailed images showing cracks on the outer surfaces of the tubes and explains where the tubes were used and how they were operated.

This chapter discusses the typical compositional ranges of superalloys, the role of major base metals (iron, cobalt, and nickel), and the effects of common alloying additions. It describes how chromium, aluminum, and titanium as well as refractory elements, grain-boundary elements, reactive elements, and oxides influence mechanical properties and behaviors. It also discusses the effect of trace elements.

This chapter discusses three measurements parameters: temperature, strain, and magnetic field strength. It stresses the measurement of temperature because it is the primary variable in nearly all low-temperature material properties. The chapter contains information on methods and auxiliary materials. Areas of frequent concern, such as thermal contact, heat leak, thermal anchoring, thermal conductivity of greases, insulators, lead wires, ground loops, and feedthroughs are also reviewed. The chapter provides an overview and historical development of temperature scales because the practical use of all thermometers is associated with some approximation of the thermodynamic temperature scale. A short section is devoted to types of temperature measuring devices. The characteristics of commercially available resistance-type strain gauges at low temperatures are stressed.

This chapter describes the metallurgy, composition, and properties of steels and other alloys. It provides information on the atomic structure of metals, the nature of alloy phases, and the mechanisms involved in phase transformations, including time-temperature effects and the role of diffusion, nucleation, and growth. It also discusses alloying, heat treating, and defect formation and briefly covers condenser tube materials.

Austenitic stainless steels exhibit a single-phase, face-centered cubic structure that is maintained over a wide range of temperatures. This chapter provides a basic understanding of grade designations, properties, and welding considerations of austenitic stainless steels. It also discusses general types of corrosive attack and their effects on service integrity as well as detection and control measures. The five corrosive attack mechanisms covered are intergranular corrosion, preferential attack associated with weld metal precipitates, pitting and crevice corrosion, stress-corrosion cracking, and microbiologically influenced corrosion.

This chapter discusses various alloying and processing approaches to increase the strength of low-carbon steels. It describes hot-rolled low-carbon steels, cold-rolled and annealed low-carbon steels, interstitial-free or ultra-low carbon steels, high-strength, low-alloy (HSLA) steels, dual-phase (DP) steels, transformation-induced plasticity (TRIP) steels, and martensitic low-carbon steels. It also discusses twinning-induced plasticity (TWIP) steels along with quenched and partitioned (Q&P) steels.

This chapter discusses two damage mechanisms in which stress plays a major role. In the one case, stress causes cracks in the oxide scale on metals, leading to preferential corrosion attack. An example from industry of this type of failure is the circumferential cracking that occurs on the waterwall tubes of supercritical coal-fired boilers fired under low NOx combustion conditions, conducive to the production of sulfidizing environments. In the other case, stress contributes to brittle fracture in the form of intergranular cracking. The phenomenon, which is known by various names, typically occurs at the lower end of the intermediate temperature range and has been observed in ferritic steels, stainless steels, Fe-Ni-Cr alloys, and nickel-base alloys, as described in the chapter.