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Image
Published: 01 November 2007
Fig. 14.15 Type 304H tested in air + 4CO 2 + 8H 2 O at 610 °C (1130 °F) under the strain rate of 3 × 10 –8 /s with about 2% strain, showing preferential oxidation penetration (the authors referred to as ″cracking″). SEM/EDX analysis showed the oxide in area A was Fe-3Cr-4Si-0.5Mo, in area B
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Image
Cross section of a Type 304H reheater tube showing two wastage flats with t...
Available to PurchasePublished: 01 November 2007
Fig. 10.67 Cross section of a Type 304H reheater tube showing two wastage flats with the maximum wastage. Note the wastage flats on both sides of the tube surface where the flue gas impinging at the 90° location (i.e., facing the ruler in the photo). Courtesy of Welding Services Inc.
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Image
Published: 01 November 2007
Fig. 10.70 Optical micrograph showing Type 304H reheater (the same one shown in Fig. 10.67 ) that suffered carburization on the surface where severe coal-ash corrosion took place (about 2 and 10 o’clock positions). Courtesy of Welding Services Inc.
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Image
Type 304H reheater (the same one shown in Fig 10.67) at 3 or 9 o’clock posi...
Available to PurchasePublished: 01 November 2007
Fig. 10.71 Type 304H reheater (the same one shown in Fig 10.67) at 3 or 9 o’clock positions, where no severe coal-ash corrosion attack occurred, showing no carburization attack. Courtesy of Welding Services Inc.
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Image
Cross section of a Type 304H reheater tube suffering fly-ash erosion/corros...
Available to PurchasePublished: 01 November 2007
Fig. 10.75 Cross section of a Type 304H reheater tube suffering fly-ash erosion/corrosion damage. Courtesy of Welding Services Inc.
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Image
The cross section of alloy 72/304H overlay tube after testing as part of th...
Available to PurchasePublished: 01 November 2007
Fig. 10.88 The cross section of alloy 72/304H overlay tube after testing as part of the reheater (1000 °F steam) for 3½ years in a 255 MW(e) subcritical boiler, which burned high chlorine coal (about 0.3%). The 304H reheater tubes exhibited a typical 4 year life. Courtesy of Welding Services
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Image
The cross section of alloy 52/304H overlay tube after testing as part of th...
Available to PurchasePublished: 01 November 2007
Fig. 10.89 The cross section of alloy 52/304H overlay tube after testing as part of the reheater (538 °C, or 1000 °F steam) for 3½ years in a 255 MW(e) subcritical boiler, which burned high chlorine coal (about 0.3%), showing slight pitting attack. The 304H reheater tubes exhibited a typical 4
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Image
Scanning electron micrograph (backscattered electron image) showing fly-ash...
Available to PurchasePublished: 01 November 2007
Fig. 10.76 Scanning electron micrograph (backscattered electron image) showing fly-ash deposits (46.4 Si-21.6Al-20.7Fe) (marked 1) on the surface of Type 304H reheater ( Fig. 10.75 ) that suffered the maximum wastage at location 30° away from the direct flue gas impingement point. The 304H
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Image
Optical micrograph showing the morphology of the corrosion attack on the 30...
Available to PurchasePublished: 01 November 2007
Fig. 10.73 Optical micrograph showing the morphology of the corrosion attack on the 304H superheater tube at the severely wasted area. Courtesy of Welding Services Inc.
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Image
Surface appearance of one of the wastage flats with the maximum wastage of ...
Available to PurchasePublished: 01 November 2007
Fig. 10.68 Surface appearance of one of the wastage flats with the maximum wastage of the 304H reheater tube shown in Fig. 10.67 . Courtesy of Welding Services Inc.
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Image
Scanning electron micrograph showing the oxide scales formed on the nearby ...
Available to PurchasePublished: 01 November 2007
Fig. 10.77 Scanning electron micrograph showing the oxide scales formed on the nearby location of the one shown in Fig. 10.76 on the severely wasted area for Type 304H reheater tube. Courtesy of Welding Services Inc.
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Image
Scanning electron micrograph showing ash deposits that formed at the 12 o’c...
Available to PurchasePublished: 01 November 2007
Fig. 10.78 Scanning electron micrograph showing ash deposits that formed at the 12 o’clock position where the flue gas made a direct impingement on the Type 304H reheater tube ( Fig. 10.75 ). This location showed significantly less tube wall wastage. Courtesy of Welding Services Inc.
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Image
Scanning electron micrograph showing the corrosion products (general corros...
Available to PurchasePublished: 01 November 2007
Fig. 10.74 Scanning electron micrograph showing the corrosion products (general corrosion scales and internal corrosion phases) on Type 304H superheater at the severely wasted area. The EDX analysis showed that the corrosion product (area 1) was Cr-Fe-rich sulfide (45.5Cr-33.5Fe-9.2Ni-8.6S
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Image
Scanning electron micrograph (backscattered electron image) showing the cor...
Available to PurchasePublished: 01 November 2007
Fig. 10.69 Scanning electron micrograph (backscattered electron image) showing the corrosion products formed on the maximum wastage area of Type 304H reheater shown in Fig. 10.67 . Semiquantative EDX analysis shows the compositions (wt%) at different locations as indicated below. Courtesy
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Book Chapter
300-Series PM Stainless Steels
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 June 2007
DOI: 10.31399/asm.tb.pmsspmp.t52000219
EISBN: 978-1-62708-312-6
... 38 61 ND 15 6.4 SS-304N2-33 33 … 5.0 57 40 10.0 16.5 0.25 25.0 127 47 62 ND 18 6.5 SS-304N2-38 38 … 8.0 70 45 13.0 20.0 0.27 55.0 ND 47 68 ND 23 6.9 SS-304H-20 20 … 7.0 40 25 10.0 17.0 0.25 20.0 85 25 35 ND (c) 6.6 SS-304L-13 13 … 15.0...
Abstract
This appendix provides property data, including strength, tensile properties, elastic constants, and hardness, for 300-series powder metal stainless steels.
Book Chapter
Coal-Fired Boilers
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 November 2007
DOI: 10.31399/asm.tb.htcma.t52080259
EISBN: 978-1-62708-304-1
Abstract
This chapter discusses material-related problems associated with coal-fired burners. It explains how high temperatures affect heat-absorbing surfaces in furnace combustion areas and in the convection pass of superheaters and reheaters. It describes how low-NOx combustion technology, intended to reduce NOx emissions, accelerates tube wall wastage. It also covers circumferential cracking in furnace waterwalls, thermal fatigue cracking induced by waterlances and water cannons, superheater-reheater corrosion, and erosion in fluidized-bed boilers.
Book Chapter
Materials for Boiler Tubes
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 2018
DOI: 10.31399/asm.tb.fibtca.t52430087
EISBN: 978-1-62708-253-2
... … … … … … Super 304H 0.10 0.2 0.8 18.0 9.0 … … 0.4 0.10N 3.0Cu AISI 310 0.25 1.5 2.0 24.0 19.0 … … … … … AISI 316 0.08 1.0 2.0 17.0 12.0 2.5 … … … … TP316H 0.08 0.6 1.6 16.0 12.0 2.5 … … … … AISI 321 0.09 1.0 2.0 17.0 11.0 … … … … 0.15Ti TP321H...
Abstract
Boilers are often classified based on the maximum operating temperature and pressure for which they are designed. Classifications, in ascending order, are subcritical, supercritical, ultra-supercritical, and to advanced ultra-supercritical. At each higher operating point comes greater efficiency, as well as greater demand on construction materials. This chapter discusses the primary requirements for boiler tube materials, including oxidation and corrosion resistance, fatigue strength, thermal conductivity, and the ability to resist creep and rupture. It also provides information on various steels and alloys, covering cost, engineering specifications, and ease of use.
Book Chapter
Stress-Assisted Corrosion and Cracking
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 November 2007
DOI: 10.31399/asm.tb.htcma.t52080379
EISBN: 978-1-62708-304-1
.... The stress-assisted preferential corrosion attack is quite sensitive to the environment. Le Calvar et al. ( Ref 10 ) performed low strain rate tests in air + 4CO 2 + 8H 2 O at 610 °C (1130 °F). Figure 14.15 shows Type 304H suffering preferential oxidation penetration under this test condition at a strain...
Abstract
This chapter discusses two damage mechanisms in which stress plays a major role. In the one case, stress causes cracks in the oxide scale on metals, leading to preferential corrosion attack. An example from industry of this type of failure is the circumferential cracking that occurs on the waterwall tubes of supercritical coal-fired boilers fired under low NOx combustion conditions, conducive to the production of sulfidizing environments. In the other case, stress contributes to brittle fracture in the form of intergranular cracking. The phenomenon, which is known by various names, typically occurs at the lower end of the intermediate temperature range and has been observed in ferritic steels, stainless steels, Fe-Ni-Cr alloys, and nickel-base alloys, as described in the chapter.
Book Chapter
Compositions
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.ssde.t52310269
EISBN: 978-1-62708-286-0
... 0.030 … … 304L S30403 0.03 0.10 18.0–20.0 8.0–10.5 2.0 … 1.00 0.045 0.030 … … 304H S30409 0.04–0.10 … 18.0–20.0 8.0–10.5 2.0 … 1.00 0.045 0.030 … … 304N S30451 0.08 0.10–0.16 18.0–20.0 8.0–10.5 2.0 … 1.00 0.045 0.030 … … 304HN S30452 0.08 0.16–0.30...
Abstract
This appendix contains tables listing the composition of austenitic, ferrite, martensitic, precipitation-hardenable, and duplex stainless steels and of Alloy Casting Institute heat- and corrosion-resisting casting alloys.
Book Chapter
The Naming and Numbering of Stainless Steels
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 June 2010
DOI: 10.31399/asm.tb.hss.t52790241
EISBN: 978-1-62708-356-0
..., and 501. Forty-six AISI numbers and their corresponding chemical compositions were published in 1932, twenty-eight of which are still in use. Many new AISI numbers were added that were primarily modifications, using suffix letters, such as 304L, 304H, 304N, and 420F. AISI 329 was the only duplex...
Abstract
This chapter presents the early classes of stainless steel. These include martensitic alloys, austenitic alloys, and ferritic alloys. It also presents stainless steel trade names. The chapter describes standardized designation for type 304 stainless steel by various specification organizations.
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