This article discusses the properties, behaviors, and uses of cobalt and its alloys. It explains how cobalt alloys are categorized and describes the commercial designations and grades that are available. It also provides composition information and explains how alloying elements and carbides affect toughness, hardness, ductility, and strength as well as resistance to heat, corrosion, and wear.

This chapter discusses the basic principles of friction and the factors that must be considered when determining its effect on moving bodies in contact. It provides an extensive amount of friction data, including static and kinetic friction coefficients for numerous combinations of engineering materials and coatings. It also describes the causes and effects of the most common forms of wear, the conditions under which they occur, the role of lubrication, and wear testing methods.

This chapter describes nondestructive evaluation (NDE) test methods and their relative effectiveness for diagnosing the cause of stress-corrosion cracking (SCC) service failures. It discusses procedures for analyzing various types of damage in carbon and low-alloy steels, high-strength low-alloy steels, hardenable stainless steels, austenitic stainless steels, copper-base alloys, titanium and titanium alloys, aluminum and aluminum alloys, and nickel and nickel alloys. It identifies material-environment combinations where SCC is known to occur, provides guidelines on how to characterize cracking and fracture damage, and explains what to look for during macroscopic and microscopic examinations as well as chemical and metallographic analyses. It also includes nearly a dozen case studies investigating SCC failures in various materials.

This chapter reviews various ways to classify failure categories and summarizes the basic types, causes, and mechanisms of damage, with particular consideration given to whether the likelihood of the types of damage can or cannot be influenced by the heat treating of steel parts. The classical organization for types of damage (failures) is as follows: deformation, fracture, wear, corrosion or other environmental damage, and multiple or complex damage. The chapter also provides some examples of lack of conformance to specification that may at first look like the heat treater did something wrong, but where other contributing factors made it difficult or impossible for the heat treater to meet the specification.

Gaseous ferritic nitrocarburizing, like salt bath nitrocarburizing, involves the introduction of carbon and nitrogen into steel in order to produce a thin layer of iron carbonitride and nitrides, the "white layer" or compound layer, with an underlying diffusion zone containing dissolved nitrogen and iron (or alloy) nitrides. This chapter first presents the development and principles of the process. It then discusses the properties of gaseous ferritic nitrocarburized components. The chapter also presents the applications for the ferritic nitrocarburizing process. It provides an overview of the safety considerations.

This chapter explores the behavior of stainless steel in media that promote corrosion. The forms of corrosion covered are uniform corrosion, atmospheric corrosion, localized corrosion, pitting corrosion, crevice corrosion, and grain boundary corrosion. The chapter discusses the influence of material and environmental variables on stress-corrosion cracking (SCC) and the mechanisms proposed for SCC in stainless steel, comparing the mechanism of SCC with hydrogen embrittlement. In addition, it provides information on biocorrosion and microbiologically induced corrosion in ambient aqueous environments.

This appendix is a compilation of terms and definitions related to metallurgy.

This chapter covers the failure modes and mechanisms of concern in hydroprocessing reactor vessels and the methods used to assess lifetime and performance. It begins with a review of the materials used in the construction of pressure-vessel shells, the challenges they face, and the factors that determine shell integrity. The discussion addresses key properties and design parameters including allowable stress, fracture toughness, the effect of microstructure and composition on embrittlement, high-temperature creep, and subcritical crack growth. The chapter also provides information on the factors that affect cladding integrity and ends with a section on life-assessment techniques.

This chapter reviews and provides data tables for the wide range of properties and performance characteristics that are possible with specific aluminum casting alloys and tempers. Properties and performance attributes addressed include casting and finishing characteristics; typical physical properties; typical and minimum (design) mechanical properties; fatigue strength; fracture resistance, including subcritical crack growth; and resistance to general corrosion and to stress-corrosion cracking. The chapter concludes with information on the properties of cast aluminum matrix composites.

This chapter discusses joining atmospheres that are used for brazing, along with their advantages and disadvantages. It discusses the processes, advantages, and disadvantages of chemical fluxing, self-fluxing, and fluxless brazing. Information on stop-off compounds that are considered as the antithesis of fluxes is also provided.

This chapter discusses various types of material fracture toughness and the methods by which they are determined. It begins with a review of the basic principles of linear elastic fracture mechanics, covering the Griffith-Irwin theory of fracture, the concept of strain energy release rate, the use of fracture indices and failure criteria, and the ramifications of crack-tip plasticity in ductile and brittle fractures. It goes on to describe the different types of plain-strain and plane-stress fracture toughness, explaining how they are measured and how they are influenced by metallurgical and environmental variables and loading conditions. It also examines the crack growth resistance curves of several aluminum alloys and describes the characteristics of fracture when all or some of the applied load is in the plane of the crack.

This chapter discusses the mechanical properties of powder metal stainless steels and the extent to which they can be controlled through appropriate alloying and processing steps. It describes how process-related factors, such as porosity, interstitial content, sintering atmosphere, and heating and cooling profiles, affect strength, ductility, and corrosion resistance. It also provides an extensive amount of property data – including tensile and yield strength, elongation, hardness, and creep and stress rupture measurements as well as fatigue curves – for various grades of powder metal stainless steel.

This chapter reviews the fundamentals of stress, strain, and deformation and demonstrates some of the tools and techniques used to analyze how materials and structures respond to tension, compression, bending, and shear. It begins with an overview of the behavior of perfectly elastic and plastic materials and viscous substances. It then describes the stress-strain response of two- and three-dimensional solids, explaining how to determine principle stresses and strains using Mohr’s circle and how to derive equivalent stress and strain using the von Mises relationship. It then goes on to analyze the stress state of load-bearing members, pressurized tubes, and pin-loaded lugs, accounting for the effect of geometric discontinuities, such as cutouts, fillets, and holes, as well as cracks. It also explains how finite element methods are used to solve problems involving complex geometric and loading conditions.

Forging is a deformation process achieved through the application of compressive stresses. During the stroke, pressures and velocities are continuously changing and the initial lubricant supply must suffice for the duration of the operation. Lubricant residues and pickup products also change with time, further complicating the analysis of friction and wear. This chapter provides a qualitative and quantitative overview of the mechanics and tribology of forging in all of its forms. It discusses the effects of friction, pressures, forces, and temperature on the deformation and flow of metals in open-die, closed-die, and impression-die forging and in back extrusion and piercing operations. It presents various ways to achieve fluid-film lubrication in upset forging processes and examines the cause of barreling, defect formation, and folding in the upsetting of cylinders, rings, and slabs. It also explains how to evaluate lubricants, friction, and wear under hot, cold, and warm forging conditions and how to extend die life and reduce defects when processing different materials.