Nonferrous metals are of commercial interest both as engineering materials and as alloying agents. This chapter addresses both roles, discussing the properties, processing characteristics, and applications of several categories of nonferrous metals, including light metals, corrosion-resistance alloys, superalloys, refractory metals, low-melting-point metals, reactive metals, precious metals, rare earth metals, and metalloids or semimetals. It also provides a brief summary on special-purpose materials, including uranium, vanadium, magnetic alloys, and thermocouple materials.

This chapter discusses the typical compositional ranges of superalloys, the role of major base metals (iron, cobalt, and nickel), and the effects of common alloying additions. It describes how chromium, aluminum, and titanium as well as refractory elements, grain-boundary elements, reactive elements, and oxides influence mechanical properties and behaviors. It also discusses the effect of trace elements.

The properties of cast iron are determined primarily by the form of carbon they contain, which in turn, is controlled by modifying compositions and cooling rates during casting. Certain alloys (such as Si, Al, Ni, Co, and Cu) promote graphite formation, while others (such as S, V, Cr, Sn, Mo, and Mn) promote the formation of cementite. This chapter examines the relative potencies of these alloys and their effect on microstructure. It covers the five most common commercial cast irons, including white, gray, ductile, malleable, and compacted graphite, describing their compositional ranges, distinguishing features, advantages, limitations, and applications.

The refractory metals include niobium, tantalum, molybdenum, tungsten, and rhenium. These metals are considered refractory because of their high melting points, high-temperature mechanical stability, and resistance to softening at elevated temperatures. This article discusses the composition, properties, fabrication procedures, advantages and disadvantages, and applications of these refractory metals and their alloys. A comparison of some of the properties of the refractory metals with those of iron, copper, and aluminum is given in a table. The article concludes with a brief section on refractory metal protective coatings.

This article discusses the general purpose of alloying and identifies some of the material properties and behaviors that can be improved by adding various elements to the base metal. It explains how alloying can make metals stronger and more resistant to corrosion and wear as well as easier to cast, weld, form, and machine. It also discusses some of the alloying techniques that have been developed to address problems stemming from dissimilarities between the base metal and alloying or inoculate material.

This article covers the metallurgy and properties of gray irons. It describes the classes or grades of gray iron, the types of applications for which they are suited, and the corresponding compositional ranges. It discusses the role of major, minor, and trace elements, how they are added, and how they affect various properties, behaviors, and processing characteristics. It explains how silicon, chromium, and nickel, in particular, improve high-temperature, corrosion, and wear performance.

This article discusses the metallurgy and properties of ductile cast iron. It begins with an overview of ductile or spheroidal-graphite iron, describing the specifications, applications, and compositions. It then discusses the importance of composition control and explains how various alloying elements affect the properties, behaviors, and processing characteristics of ductile iron. The article describes the benefits of nickel and silicon additions in particular detail, explaining how they make ductile iron more resistant to corrosion, heat, and wear.

This article discusses the composition and morphology of compacted graphite (CG) iron relative to that of gray and ductile iron. It explains that the graphite in CG iron is intermediate in shape between the spheroidal graphite found in ductile iron and the flake graphite in gray iron, giving it distinct advantages in a number of applications. The article also discusses the role of melt treatment elements and explains how alloying and heat treatment affect tensile strength, hardness, toughness, and ductility.

This article explains how malleable iron is produced and how its microstructure and properties differ from those of gray and ductile iron. Malleable iron is first cast as white iron then annealed to convert the iron carbide into irregularly shaped graphite particles called temper carbon. Although malleable iron has largely been replaced by ductile iron, the article explains that it is still sometimes preferred for thin-section castings that require maximum machinability and wear resistance. The article also discusses the annealing and alloying processes by which these properties are achieved.

This article discusses the production, properties, and uses of high-alloy white irons. It explains how the composition and melt are controlled to produce a large volume of eutectic carbides, making these irons particularly hard and resistant to wear, and how the metallic matrix supporting the carbide phase can be adjusted via alloy content and heat treatment to optimize the balance between abrasion resistance and impact toughness. It also describes the effect of alloying elements and inoculants on various properties and behaviors and provides information on commercial alloy grades and applications.

This article discusses the role of alloying in the production and use of carbon and low-alloy steels. It explains how steels are defined and selected based on alloy content and provides composition and property data for a wide range of designations and grades. It describes the effect of alloying on structure and composition and explains how alloy content can be controlled to optimize properties and behaviors such as ductility, strength, toughness, fatigue and fracture resistance, and resistance to corrosion, wear, and high-temperature creep. It also examines the effect of alloying on processing characteristics such as hardenability, formability, weldability, machinability, and temper embrittlement. In addition, the article provides an extensive amount of engineering data with relevance in materials selection.

This article discusses the effect of alloying on high-strength low-alloy (HSLA) steels. It explains where HSLA steels fit in the continuum of commercial steels and describes the six general categories into which they are divided. It provides composition data for standard types or grades of HSLA steel along with information on available mill forms, key characteristics, and intended uses. The article explains how small amounts of alloying elements, particularly vanadium, niobium, and titanium, control not only the properties of HSLA steels, but also their manufacturability.

This article provides an overview of tool steels, discussing their composition, properties, and behaviors. It covers all types and classes of wrought and powder metal tool steels, including high-speed steels, hot and cold-work steels, shock-resisting steels, and mold steels. It explains how the properties of these steels are determined by alloying elements, such as tungsten, molybdenum, vanadium, manganese, and chromium, and the presence of alloy carbides. It describes the types of carbides that form and how they contribute to wear resistance, toughness, high-temperature strength, and other properties.

This article discusses the effects of alloying on the properties and behaviors of maraging steels. It describes how maraging steels differ from conventional steels in that they are strengthened, not by carbon, but by the precipitation of intermetallic compounds. It explains how maraging steels typically have high levels of nickel, cobalt, and molybdenum with little carbon content and how that affects their dimensional stability, fracture toughness, weldability, and resistance to stress-corrosion cracking.

This article provides an overview of austenitic manganese steels. It describes the standard composition ranges of commercial products and explains how various alloying elements affect mechanical properties, processing, and performance. The article also discusses special grades of manganese steels and the types of applications for which they have been developed.

This article covers the metallurgy and properties of stainless steels. It provides composition information on all types of ferritic, austenitic, martensitic, duplex, and precipitation-hardening stainless steels, including proprietary and nonstandard grades, along with corresponding property and performance data. It also discusses the effect of various alloying elements on pitting, crevice corrosion, sensitization, stress-corrosion cracking, and oxidation resistance.

This article discusses the composition, structure, and properties of iron-nickel-, nickel-, and cobalt-base superalloys and the effect of major alloying and trace elements. It describes the primary and secondary roles of each alloying element, the amounts typically used, and the corresponding effect on properties and microstructure. It also covers mechanical alloying and weldability and includes nominal composition data on many wrought and cast superalloys.

This article discusses the role of alloying in the production and use of common refractory metals, including molybdenum, tungsten, niobium, tantalum, and rhenium. It provides an overview of each metal and its alloys, describing the compositions, properties, and processing characteristics as well as the effect of alloying elements. It also discusses strengthening mechanisms and, where appropriate, corrosion behavior.

This article discusses the effect of alloying on the composition, structure, properties, and processing characteristics of ordered intermetallic compounds, including nickel aluminides, iron aluminides, and titanium aluminides. It includes several data tables along with a list of typical applications.

This article discusses the composition, structures, properties, and behaviors of aluminum alloys and explains how they correspond to specific alloying elements. It begins with an overview of the general characteristics of wrought and cast aluminum alloys, the four-digit classification system by which they are defined, and the applications for which they are suited. It then explains how primary alloying elements, second-phase constituents, and impurities affect yield strength, phase formation, and grain size and how they induce structural changes that help refine certain alloys. The article also explains how primary alloying elements affect corrosion and wear behaviors and how they influence fabrication processes such as forming, forging, welding, brazing, and soldering.