The appendix contains detailed simulation examples through which readers learn how to format and analyze problems using the LAMMPS molecular dynamics simulator. By means of simulation, readers will determine the thermal expansion coefficient of copper, generate stress-strain plots for aluminum at different temperatures, calculate the surface energy of copper for different crystal orientations, investigate diffusion effects in BCC iron, estimate the sliding friction between graphene layers, compare the stacking fault energy of silver and aluminum, and analyze the properties and behaviors of liquids and gases. All examples employ a systematic problem-solving approach and include necessary input code.

This introduction presents an overview of the discovery of aluminum, the origins of the aluminum industry, and the evolution of the industry.

This chapter describes the process steps in the production of smelter grade aluminum, the environmental issues with aluminum production, and the importance of recycling. It also provides a discussion on the refining, or Bayer, process and the smelting, or Hall-Héroult, process.

Casting is one of the most economical manufacturing processes for providing shape to components of machinery and is used in a wide range of industries. This chapter is a brief account of the advantages, applications, limitations, and market growth of aluminum casting. It also provides information on the process of conversion of steel and iron parts to aluminum.

This chapter provides information on comparative attributes of sand molds and metal molds for aluminum casting. The cooling rates and microstructures obtained with each mold type are discussed. In addition, the chapter explains why sand castings work successfully in certain applications.

This chapter discusses the advantages, limitations, and applications of various aluminum casting processes, namely green sand casting process, air set or no-bake molding process, vacuum molding process, evaporative foam casting process, and die casting process. The processes covered also include gravity permanent molding, low-pressure permanent molding, counter pressure, squeeze casting, investment casting, rapid prototype casting, cast forge hybrid, and semisolid metal processes.

This chapter discusses the development of aluminum, its industry growth, and its modern uses in manufacturing. It begins with the biography of Charles Martin Hall, who invented the process for reducing aluminum from its ore. The evolution of aluminum production from the Pittsburgh Reduction Company to a pilot plant on Smallman Street in Pittsburgh, to a production plant in New Kensington, and to Niagara Falls, New York, is then described. This is followed by a discussion on early aluminum applications and the usage of lower-cost raw materials. The chapter provides information on aluminum production process integrated by Aluminum Company of America (Alcoa) and the numerous technical problems and solutions related to Alcoa's research from World War I to World War II. The aerospace applications for aluminum alloys are also presented. The chapter concludes with a section on aluminum alloys developed by Alcoa.

This chapter describes the effects of metallurgical variables on the corrosion of aluminum alloys. Emphasis is placed on the effect of constituent particles on pitting corrosion of aluminum.

This chapter addresses the general effects of composition, mechanical treatment, surface treatment, processing, and fabrication operations on the corrosion resistance of aluminum and its alloys. Different types of surface treatments covered include claddings, anodizing, and conversion coatings. The processing steps that can have relatively significant impact on corrosion resistance are homogenization, rolling, extrusion, quenching, aging, and annealing.

The properties of cast iron are determined primarily by the form of carbon they contain, which in turn, is controlled by modifying compositions and cooling rates during casting. Certain alloys (such as Si, Al, Ni, Co, and Cu) promote graphite formation, while others (such as S, V, Cr, Sn, Mo, and Mn) promote the formation of cementite. This chapter examines the relative potencies of these alloys and their effect on microstructure. It covers the five most common commercial cast irons, including white, gray, ductile, malleable, and compacted graphite, describing their compositional ranges, distinguishing features, advantages, limitations, and applications.

Aluminum has many outstanding properties, leading it to be used for a wide range of applications. It offers excellent strength-to-weight ratio, good corrosion and oxidation resistance, high electrical and thermal conductivity, exceptional formability, and relatively low cost. This chapter examines the metallurgy, composition, processing, and mechanical properties of aluminum and its alloys, both cast and wrought forms. It also covers heat treating and basic temper designations, including annealed, work hardened, solution heat treated, and solution heated treated and aged. The chapter concludes with information on corrosion and oxidation resistance.

The refractory metals include niobium, tantalum, molybdenum, tungsten, and rhenium. These metals are considered refractory because of their high melting points, high-temperature mechanical stability, and resistance to softening at elevated temperatures. This article discusses the composition, properties, fabrication procedures, advantages and disadvantages, and applications of these refractory metals and their alloys. A comparison of some of the properties of the refractory metals with those of iron, copper, and aluminum is given in a table. The article concludes with a brief section on refractory metal protective coatings.

The nonferrous alloys described in this chapter include aluminum and aluminum alloys, copper and copper alloys, titanium and titanium alloys, zirconium and zirconium alloys, and tantalum and tantalum alloys. Some of the factors that affect the corrosion performance of welded nonferrous assemblies include galvanic effects, crevices, assembly stresses in products susceptible to stress-corrosion cracking, and hydrogen pickup and subsequent cracking. The emphasis is placed on the compositions, general welding considerations, and corrosion behavior of these alloys.

Porosity in aluminum is caused by the precipitation of hydrogen from liquid solution or by shrinkage during solidification, and more usually by a combination of these effects. Nonmetallic inclusions entrained before solidification influence porosity formation and mechanical properties. This chapter describes the causes and control of porosity and inclusions in aluminum castings as well as the combined effects of hydrogen, shrinkage, and inclusions on the properties of aluminum alloys. In addition, it discusses the applications of radiography to reveal internal discontinuities in aluminum.

This chapter provides guidelines on how to set up and run an effective quality-improvement program for aluminum extrusion operations. It begins by identifying production processes and variables that impact the quality of hard and soft alloy extrusions. It then presents a series of checklists and flowcharts that can be used to monitor and troubleshoot billet-making and extrusion processes, die construction, equipment maintenance, heat treating, and sawing and stretching procedures. It also discusses the importance of charting test results and monitoring surface treatments that may be required to improve corrosion, oxidation, or wear resistance.

This chapter discusses the principles of corrosion of metals in aqueous environments. The thermodynamics of aqueous corrosion is the subject of the first half of this chapter, which addresses concepts such as corrosion reactions and free-energy change, the relationship between free energy and electrochemical potential, the effect of ionic concentration on electrode potential, and the corrosion behavior of a metal based on its potential-pH diagram. The corrosion (potential-pH) behavior of iron, gold, copper, zinc, aluminum, and titanium are described. Understanding the kinetics of corrosion and the factors that control the rates of corrosion reactions requires examination of the concepts of polarization behavior and identification of the various forms of polarization in an electrochemical cell. These concepts, addressed in the remaining of this chapter, include anodic and cathodic reactions, the mixed-potential theory, and the exchange currents.

All materials are susceptible to corrosion or some form of environmental degradation. Although no single material is suitable for all applications, usually there are a variety of materials that will perform satisfactorily in a given environment. The intent of this chapter is to review the corrosion behavior of the major classes of metals and alloys as well as some nonmetallic materials, describe typical corrosion applications, and present some unique weaknesses of various types of materials. It also aims to point out some unique material characteristics that may be important in material selection, and discuss, where appropriate, the characteristic forms of corrosion that attack specific materials. The materials addressed in this chapter include carbon steels, weathering steels, and alloy steels; nickel, copper, aluminum, titanium, lead, magnesium, tin, zirconium, tantalum, niobium, and cobalt and their alloys; polymers; and other nonmetallic materials, including rubber, carbon and graphite, and woods.

Aluminum is the second most widely used metal in the world. It is readily available, offers a wide range of properties, and can be shaped, coated, and joined using a variety of methods. This chapter discusses some of the key attributes of wrought and cast aluminum alloys and the classifications, designations, and grades of available product forms. It also explains how aluminum alloys are used in aerospace, automotive, rail, and marine applications as well as in building and construction, electrical products, manufacturing equipment, packaging, and consumer durables such as appliances and furniture.