This appendix contains sample problems with worked solutions pertaining to the use of binary phase diagrams. The problems require the determination of favorable temperatures and compositions, the amount and composition of phases in an alloy at a given temperature, the amount of a certain phase in different steels, and the microstructure developed in different alloys.

This chapter discusses the unique characteristics of isomorphous alloy systems. It begins with a review of the naming conventions for multi-component systems and the construction of a three-dimensional phase diagram for a two-component alloy system. It explains how phase diagrams can be constructed from time-temperature cooling curves and how they can be used to predict the phases present, their chemical compositions, and relative amounts. It also shows how phase diagrams can be modified to account for nonequilibrium cooling conditions.