This chapter describes the metallurgy, composition, and properties of steels and other alloys. It provides information on the atomic structure of metals, the nature of alloy phases, and the mechanisms involved in phase transformations, including time-temperature effects and the role of diffusion, nucleation, and growth. It also discusses alloying, heat treating, and defect formation and briefly covers condenser tube materials.

Boilers are often classified based on the maximum operating temperature and pressure for which they are designed. Classifications, in ascending order, are subcritical, supercritical, ultra-supercritical, and to advanced ultra-supercritical. At each higher operating point comes greater efficiency, as well as greater demand on construction materials. This chapter discusses the primary requirements for boiler tube materials, including oxidation and corrosion resistance, fatigue strength, thermal conductivity, and the ability to resist creep and rupture. It also provides information on various steels and alloys, covering cost, engineering specifications, and ease of use.

This chapter is a compilation of terms and definitions related to corrosion in the petrochemical industry.

This chapter reviews the major marine applications of stainless steels, including the desalination equipment, shipping containers, and heat exchangers that handle seawater.

This chapter focuses on the applications of stainless steels in chemical and process industry, covering what data are necessary and how they can be found. It begins with an overview of single- and dual-environment systems and the corrosion issues they face. This is followed by a discussion on the causes of the various forms of corrosion associated with liquids, namely pitting corrosion, crevice corrosion, intergranular corrosion, stress corrosion cracking, and erosion corrosion. The chapter also contains tables listing corrosion rates of sulfuric acid and fuming sulfuric acid. It ends with a section providing information on specific environments against which stainless steels are resistant to select for use in the chemical process industries.

This chapter reviews weld corrosion in three key application areas: petroleum refining and petrochemical operations, boiling water reactor piping systems, and components used in pulp and paper plants. The discussion of each area addresses general design and service characteristics, types of weld corrosion issues, and prevention or mitigation strategies.

Two compressor rotors of similar design and construction were severely damaged during operation. In one rotor, all the blades in the third and fourth stages had been sheared off and some had lifted from the dovetail portion of the drum. The damage in the other rotor was more extensive. Most of the blades in the first four stages had sheared off and many lifted from the dovetail region, particularly in the first two stages where several mounting dovetails had also fractured. Based on visual examination and the results of SEM fractography, metallography, and chemical analysis, investigators concluded that the compressor rotors failed due to stress-corrosion cracking in the dovetail mountings. They also provided recommendations to prevent or mitigate future occurrences.

A titanium alloy disc on the fourth stage of an aircraft engine compressor was found cracked in the course of a defect investigation. The disc had not yet reached the halfway point of its expected service life. The chapter explains how the crack was examined and provides relevant details about its location on the disc and various aspects of its appearance. It also explains how failure analysts concluded that the disc had been subjected to a fluctuating load of high magnitude and that the crack was the result of two fatigue cracks, originating from opposite sides of the diaphragm.

The ability to accurately assess the remaining life of components is essential to the operation of plants and equipment, particularly those in service beyond their design life. This, in turn, requires a knowledge of material failure modes and a proficiency for predicting the near and long term effects of mechanical, chemical, and thermal stressors. This chapter presents a broad overview of the types of damage to which materials are exposed at high temperatures and the approaches used to estimate remaining service life. It explains how operating conditions in power plants and oil refineries can cause material-related problems such as embrittlement, creep, thermal fatigue, hot corrosion, and oxidation. It also discusses the factors and considerations involved in determining design life, defining failure criteria, and implementing remaining-life-assessment procedures.

This chapter covers the failure modes and mechanisms of concern in hydroprocessing reactor vessels and the methods used to assess lifetime and performance. It begins with a review of the materials used in the construction of pressure-vessel shells, the challenges they face, and the factors that determine shell integrity. The discussion addresses key properties and design parameters including allowable stress, fracture toughness, the effect of microstructure and composition on embrittlement, high-temperature creep, and subcritical crack growth. The chapter also provides information on the factors that affect cladding integrity and ends with a section on life-assessment techniques.