This article, prepared under the auspices of the ASM Thermal Spray Society Committees on Accepted Practices, describes a procedure for evaluating residual stresses in thermal spray coatings, which is an extension of the well-known layer removal method to include the Young’s modulus and Poisson’s ratio properties of the thermal spray coating material and the substrate. It presents questions and answers that were selected to introduce residual stresses in thermal spray coatings. The article describes equipment and the laboratory procedure for the modified layer removal method and provides the description of the residual stress specimen. It also describes the procedures for applying or installing bonded resistance strain gages, the dimensions of the test specimen, the procedure for removing layers, and the method for interpreting the data to evaluate residual stresses. The spreadsheet program, “ MLRM for Residual Stresses ,” is available as a supplement to this document.

This chapter, presented in a question-and-answer format, covers many practical aspects of high-entropy alloys (HEAs). It provides clear and concise answers to more than 50 questions, imparting knowledge on alloying elements, heat treatments, diffusion mechanisms, phase formation, lattice distortion, crystal and grain structures, structure-property relationships, microstructure control, and characterization methods. It likewise explains how to calculate the effect of strengthening processes on the mechanical properties of HEAs and offers insights on how to balance strength, ductility, and density for specific applications. It also provides information on twinning behaviors, stacking faults, elastic properties, coating and film deposition methods, manufacturing challenges, and the use of computational techniques for alloy design.

Product design requires an understanding of the mechanical properties of materials, much of which is based on tensile testing. This chapter describes how tensile tests are conducted and how to extract useful information from measurement data. It begins with a review of the different types of test equipment used and how they compare in terms of loading force, displacement rate, accuracy, and allowable sample sizes. It then discusses the various ways tensile measurements are plotted and presents examples of each method. It examines a typical load-displacement curve as well as engineering and true stress-strain curves, calling attention to certain points and features and what they reveal about the test sample and, in some cases, the cause of the behavior observed. It explains, for example, why some materials exhibit discontinuous yielding while others do not, and in such cases, how to determine when yielding begins. It also explains how to determine other properties via tensile tests, including ductility, toughness, and modulus of resilience.

This appendix provides readers with worked solutions to 25 problems involving calculations associated with tensile testing and the determination of mechanical properties and variables. The problems deal with engineering factors and considerations such as stress and strain, loading force, sample lengthening, and machine stiffness, and with mechanical properties and parameters such as elastic modulus, Young’s modulus, strength coefficient, strain-hardening exponent, and modulus of resilience. They also cover a wide range of materials including various grades of aluminum and steel as well as iron, titanium, brass, and copper alloys.

This chapter is a detailed account of various attributes related to mixing and testing of powder-binder feedstocks. Mixing parameters and their effects on feedstock properties is discussed. The attributes reviewed include mixture homogeneity, wetting, powder-binder ratio, feedstock density, elastic modulus, rheological behavior, particle size, formulation control, feedstock mixing, and feedstock properties. The chapter also provides information on the processes involved in feedstock preparation and testing.

This chapter provides an overview of the production and use of titanium and its significance as an engineering material. It begins by identifying important deposits and ores and assessing current and future production capacities and how they align with global consumption trends. It then describes the physical and mechanical properties of pure titanium and numerous grades of wrought titanium alloys and explains how they compare with other aerospace materials in terms of processing complexity and cost. The chapter also includes information on extractive metallurgy, current and emerging processes, product forms, and related costs.

The mechanical behavior of a material, in the most practical sense, is how it deforms or breaks under load; in other words, how it responds when stressed. This chapter provides a brief review of the properties associated with mechanical behavior, including stress, strain, elasticity, plastic deformation, ductility, hardness, creep, fatigue, and fracture. It also describes the primary components of a Charpy impact tester and the role they serve.

This chapter provides a brief review of industry’s battle with fatigue and fracture and what has been learned about the underlying failure mechanisms and their effect on product lifetime and service. It recounts some of the tragic events that led to the discovery of fatigue and brittle fracture and explains how they reshaped design philosophies, procedures, and tools. It also discusses the influence of material and manufacturing defects, operating conditions, stress concentration and intensity, temperature and pressure, and cyclic loading, all of which play a role in the onset of fatigue cracking and thus should be considered when predicting useful product life.

This chapter discusses the stress-strain response of materials, how it is measured, and how it used to set performance expectations. It begins by describing the common tensile test and how it sheds light on the elastic design of structures as well as plasticity and fracture behaviors. It explains how engineering and true stress-strain curves differ, how one is used for design and the other for analyzing metal forming operations. It discusses the effect of holes, fillets, and radii on the distribution of stresses and the use of notch tensile testing to detect metallurgical embrittlement. The chapter also covers compression, shear, and torsion testing, the prediction of yielding, residual stress, and hardness.

This chapter discusses the causes and effects of ductile and brittle fracture and their key differences. It describes the characteristics of ductile fracture, explaining how microvoids develop and coalesce into larger cavities that are rapidly pulled apart, leaving bowl-shaped voids or dimples on each side of the fracture surface. It includes SEM images showing how the cavities form, how they progress to final failure, and how dimples vary in shape based on loading conditions. The chapter, likewise, describes the characteristics of brittle fracture, explaining why it occurs and how it appears under various levels of magnification. It also discusses the ductile-to-brittle transition observed in steel, the characteristics of intergranular fracture, and the causes of embrittlement.

Fracture mechanics is the science of predicting the load-carrying capabilities of cracked structures based on a mathematical description of the stress field surrounding the crack. The fundamental ideas stem from the work of Griffith, who demonstrated that the strain energy released upon crack extension is the driving force for fracture in a cracked material under load. This chapter provides a summary of Griffith’s work and the subsequent development of linear elastic and elastic-plastic fracture mechanics. It includes detailed illustrations and examples, familiarizing readers with the steps involved in determining strain energy release rates, stress intensity factors, J-integrals, R-curves, and crack tip opening displacement parameters. It also covers fracture toughness testing methods and the effect of measurement variables.

This chapter discusses the factors that play a role in fatigue failures and how they affect the service life of metals and structures. It describes the stresses associated with high-cycle and low-cycle fatigue and how they differ from the loading profiles typically used to generate fatigue data. It compares the Gerber, Goodman, and Soderberg methods for predicting the effect of mean stress from bending data, describes the statistical nature of fatigue measurements, and explains how plastic strain causes cyclic hardening and softening. It discusses the work of Wohler, Basquin, and others and how it led to the development of a strain-based approach to fatigue and the use of fatigue strength and ductility coefficients. It reviews the three stages of fatigue, beginning with crack initiation followed by crack growth and final fracture. It explains how fracture mechanics can be applied to crack propagation and how stress concentrations affect fatigue life. It also discusses fatigue life improvement methods and design approaches.

This chapter provides information and data on the fatigue and fracture properties of steel, aluminum, and titanium alloys. It explains how microstructure, grain size, inclusions, and other factors affect the fracture toughness and fatigue life of these materials and the extent to which they can be optimized. It also discusses the effect of metalworking and heat treatment, the influence of loading and operating conditions, and factors such as corrosion damage that can accelerate crack growth rates.

This chapter discusses the fatigue behavior of bolted, riveted, and welded joints. It describes the relative strength of machined and rolled threads and the effect of thread design, preload, and clamping force on the fatigue strength of bolts made from different steels. It explains where fatigue failures are likely to occur in cold-driven rivet and friction joints, and why the fatigue strength of welded joints can be much lower than that of the parent metal, depending on weld shape, joint geometry, discontinuities, and residual stresses. The chapter also explains how to improve the fatigue life of welded joints and discusses the factors that can reduce the fracture toughness of weld metals.

Fracture control can be defined as a concerted effort to maintain operating safety without catastrophic failure by fracture. It requires an understanding of how cracks affect structural integrity and strength and the time that a crack can grow before it exceeds permissible size. The chapter describes some of methods used to determine maximum permissible crack size and predict growth rates. It explains how the information can then be used to control fractures through periodic inspection, fail-safe features, mandated retirement, and proof testing. It presents a number of fracture control plans optimized for different circumstances, examines the damage tolerance requirements used by different industries, and discusses various approaches for fatigue design.

This chapter covers the fatigue and fracture behaviors of ceramics and polymers. It discusses the benefits of transformation toughening, the use of ceramic-matrix composites, fracture mechanisms, and the relationship between fatigue and subcritical crack growth. In regard to polymers, it covers general characteristics, viscoelastic properties, and static strength. It also discusses fatigue life, impact strength, fracture toughness, and stress-rupture behaviors as well as environmental effects such as plasticization, solvation, swelling, stress cracking, degradation, and surface embrittlement.

Unlike metals, in which fatigue failures are due to a single crack that grows to a critical length, the effects of fatigue in composites are much more distributed and varied. As the chapter explains, there are five major damage mechanisms that contribute to the progression of composite fatigue, those being matrix cracking, fiber breaking, crack coupling, delamination initiation, and delamination growth. The chapter describes each mechanism in detail along with related factors. It also discusses the primary differences between composites and metals, the effect of manufacturing defects, damage tolerance, and testing and certification.

This chapter compares and contrasts the high-temperature behaviors of metals and composites. It describes the use of creep curves and stress-rupture testing along with the underlying mechanisms in creep deformation and elevated-temperature fracture. It also discusses creep-life prediction and related design methods and some of the factors involved in high-temperature fatigue, including creep-fatigue interaction and thermomechanical damage.

This chapter discusses the causes and effects of wear along with prevention methods. It covers abrasive, erosive, erosion-corrosion, grinding, gouging, adhesive, and fretting wear. It also discusses various forms of contact-stress fatigue, including subsurface-origin fatigue, surface-origin fatigue, subcase-origin fatigue (spalling fatigue), and cavitation fatigue.