This chapter familiarizes readers with the use of Fick’s laws of diffusion in heat treating, coating, and other metallurgical processes. It contains worked solutions to nearly 30 problems requiring the calculation of activation energy, diffusion coefficient, concentration level, surface layer thickness, case depth, and processing time and temperature. The selected problems deal with various types of iron, steel, and nonferrous alloys and processes ranging from aluminizing, chromizing, carburizing, and plasma nitriding to hydrogen dissipation, decarburizing, and oxidation. A few diffusion problems involving single-crystal silicon are also included.

Steel is an important material because of its tremendous flexibility in metal working and heat treating to produce a variety of mechanical, physical, and chemical properties. The purpose of this chapter is to present the metallurgical principles of heat treatment of steel in a generalized manner. The chapter provides a discussion on the constitution of commercially pure iron, subsequently leading to discussion on the iron-carbon alloy system. The chapter also describes the effect of carbon on the constitution of iron and of the solubility of carbon in iron. It provides information on transformations and on the classification of steels by carbon content. The chapter ends with a discussion on the effect of time on transformation and on the use of time-temperature-transformation diagrams.

As the carburizing process has become more sophisticated and controllable, it also has become easy to change the carbon potential during the carburizing process. It is important that the change in the carbon potential be made at the right time in the overall cycle. This appendix discusses the advantages of boost/diffuse carburizing cycles. A table lists typical carburizing constants and boost/diffusion ratios needed to obtain a 0.80 to 0.90% surface carbon content in a low-alloy, low-carbon steel. A figure illustrates possible carbon penetration profiles from boost/diffuse cycles.

Gas (atmosphere) carburizing is the de facto standard by which all other surface hardening techniques are measured and is the emphasis of this chapter. Initially, the chapter describes the process and equipment for gas carburizing. This is followed by sections discussing the processes involved in quenching, hardening, tempering, recarburizing, and cold treatment of carburized and quenched gears. Next, the chapter reviews the selection process of materials for carburized gears and provides information on carbon content, properties, and core hardness of gear teeth. The problems associated with carburizing are then covered, followed by the processes involved in heat treat distortion and shot peening of carburized and hardened gears. Information on grinding stock allowance on tooth flanks to compensate for distortion is also provided. The chapter further discusses the applications of carburized and hardened gears. Finally, it reviews vacuum carburizing and compares the attributes of conventional gas carburizing and vacuum carburizing.

This chapter provides a brief but practical overview of the case carburizing process. It discusses the benefits and challenges of the process and compares and contrasts it with other hardening methods. It explains how design allowables and safety factors compensate for unknowns and familiarizes readers with the steps involved in determining case depth and verifying that case carbon requirements have been met.

This chapter explains how decarburization can occur during carburizing processes and how to limit the severity of its effects. It describes the reactions and conditions that result in a loss of carbon atoms and how they vary with changes in the physical metallurgy of the affected material and the processing environment. It examines the characteristic features of decarburized microstructures and assesses their influence on hardness, residual stresses, and fatigue and fracture behaviors. It also discusses corrective measures and practical considerations regarding their use.

This chapter discusses the formation of free carbides and their effect on case-carburized components. It explains how alloying elements influence the composition and structure of carbide phases produced at cooling rates typical of carburizing process. It describes the morphology and distribution of the various types of carbides formed and explains how they affect mechanical properties such as hardness, residual stresses, fatigue and fracture behaviors, and wear resistance. It also provides guidance for determining what processing conditions to avoid and when and why parts should be rejected.

This chapter addresses the issue of retained austenite in quenched carburized steels. It explains why retained austenite can be expected at the surface of case-hardened components, how to estimate the amount that will be present, and how to effectively stabilize or otherwise control it. It presents detailed images and data plots showing how retained austenite appears and how it influences hardness, tensile properties, residual stresses, fatigue and fracture behaviors, and wear resistance.

This chapter is a study of the microstructure of case-hardened steels. It explains what can be learned by examining grain size, microcracking, nonmetallic inclusions, and the effects of microsegregation. It identifies information-rich features, describing their ideal characteristics, the likely cause of variations observed, and their effect on mechanical properties and behaviors. The discussions throughout the chapter are aided by the use of images, diagrams, data plots, and tables.

The design of case-hardened components is an iterative process, requiring the consideration of multiple interrelated factors. This chapter walks readers through the steps involved in selecting an appropriate material and assessing the influence of alloy composition and cooling rate on core properties including hardenability, microstructure, tensile and yield strength, ductility, toughness, and fatigue resistance. It likewise explains how carbon affects case hardenability, surface hardness, and case toughness and how case depth influences residual stresses and bending and contact fatigue. It also discusses the effect of quenching methods and addresses the issue of distortion.

This chapter familiarizes readers with tempering and refrigeration treatments and their effect on case-carburized parts. It explains how tempering makes such parts easier to machine, more structurally and dimensionally stable, and more durable in certain applications. It identifies key process parameters and provides test data showing how they affect hardness, yield strength, bending and contact fatigue, and fracture toughness. It also addresses potential problems stemming from process-related factors such as the presence of hydrogen and the effects of aging and grinding. In regard to refrigeration, the chapter explains that it is not uncommon for subzero treatments to be included in the production of carburized parts whether as a standard procedure or optional step. Subzero cooling promotes the transformation of retained austenite to martensite, thereby increasing surface hardness and reducing the propensity of quenched carburized steels to burn and crack during surface grinding. The chapter includes numerous data plots and tables showing how the various treatments influence hardness, wear resistance, tensile properties, and fatigue and fracture behaviors.

This chapter examines the microstructure and properties of annealed and normalized steels containing more than 0.25% carbon. It shows, using detailed micrographs, how incrementally higher levels of carbon affect the structure and distribution of pearlite and how it intermingles with proeutectoid ferrite and cementite. It explains how ferrite and pearlite respond to deformation and how related features such as slip lines, dislocations, shear bands, and kinking can be detected as well as what they reveal. It also describes the structure of patented wires, cast steels, and sintered steels and the morphology of manganese sulfide inclusions in castings.

High-speed tool steels have in common the ability to maintain high hardness at elevated temperatures. High speed steels are primarily used for cutting tools that generate heat during high-speed machining. They are designated as group M or group T steels in the AISI classification system, depending on whether the major alloying approach is based on molybdenum or tungsten. This chapter describes the effects of each of the alloying elements and carbon content on the processing, microstructures, and properties of high-speed steels. It discusses the processes involved in the solidification, hot work, annealing, austenitizing for hardening, and tempering of high-speed steels. It also discusses the processes involved in controlling grain size during austenitizing and reviews the characteristics of cooling transformations and other property changes in tempered high-speed steels. Information on multipoint cutting tools is provided. The chapter discusses the applications of high-speed tool steel and factors in selecting high-speed tool steels.

This chapter contains problems that illustrate the calculation or determination of such items as ideal critical diameter, the Jominy curve, and the severity of quench by methods. It presents solutions for the calculation of the effect of prior austenite grain size, carbon content, chromium content, and molybdenum content on ideal critical diameter. The chapter also contains solutions for calculation of Jominy curves and determination of minimum hardness of quenched steels, tempered hardness, ideal critical diameter, severity of quench, heat treatment, and effect of tempering during heat-up to tempering temperature.

This chapter discusses the method for calculating hardenability from composition. It contains tables listing multiplying factors, carbon content, initial hardness, and 50% martensite hardness. The tables also list Jominy distance for 50% martensite vs. DI (in. and mm), boron factors vs. % carbon and alloy factor, and distance hardness dividing factors for non-boron and boron steels (in. and mm).