This chapter describes surface modification processes that go beyond conventional heat treatments, including plasma nitriding, plasma carburizing, low-pressure carburizing, ion implantation, physical and chemical vapor deposition, salt bath coating, and transformation hardening via high-energy laser and electron beams. The chapter compares methods and includes several example applications.

Ion nitriding equipment can be categorized into two groups: cold-wall continuous direct current (dc) equipment and hot-wall pulsed dc equipment. This chapter focuses on these two categories along with other important considerations for ion (plasma) nitriding equipment and processing. Other important considerations discussed include the hollow cathode effect, sputter cleaning, furnace loading, pressure/voltage relationships, workpiece masking, and furnace configuration options. The chapter describes five methods of cooling parts from the process temperature to an acceptable exposure temperature after plasma nitriding. The chapter also presents some of the advantages of the pulsed plasma process.

This chapter first lists the compositions of typical steels that are suitable for nitriding. It then presents considerations for steel selection. The chapter also shows the influence of alloying elements on hardness after nitriding and the depth of nitriding. It provides a detailed discussion on plasma nitriding of type 422 stainless steel, nitriding of type 440A and type 630 (17-4 PH) stainless steel. The chapter also discusses plasma nitride case depths.

Process gas control for plasma (ion) nitriding is a matter of estimating the flows necessary to accomplish the required surface metallurgy. This chapter reviews several studies aimed at better understanding process gas control in plasma nitriding and its influence on compound zone formation. Emphasis is placed on the effect of sputtering on the kinetics of compound zone formation. The discussion covers the processes involved in process gas control analysis by photo spectrometry and mass spectrometry and the difficulties associated with gas analysis.

Several limitations in achieving optimal gear performance with conventional nitriding have led researchers to work on a variety of novel and improved nitriding processes. Of these, ion/plasma nitriding offers some promising results, which are reviewed in this chapter. The chapter concludes with a case history describing the application of ion nitriding to an internal ring gear of an epicyclic gearbox.