This chapter covers mechanical properties, microstructures, chemical compositions, manufacturing processes, and engineering of gating practices for several applications of gray, white, and alloyed cast irons. It begins with a description of material standards, followed by a section providing information on the practice of stress relieving. Next, the chapter details various ways of eliminating slag entrainment while designing gating and venting systems. Several factors related to the establishment of the optimum pouring rate and time are then covered. Further, the chapter discusses the technology of unalloyed or low-alloyed gray iron castings and white iron and high-alloyed cast irons. Finally, it describes the casting defects that are associated with cast iron and the processes involved in solving these defects. The article includes a number of figures illustrating the topics discussed.

Cast irons, like steels, are iron-carbon alloys but with higher carbon levels than steels to take advantage of eutectic solidification in the binary iron-carbon system. Like steel, heat treatment of cast iron includes stress relieving, annealing, normalizing, through hardening, and surface hardening. This chapter introduces solid-state heat treatment of iron castings, covering general considerations for heat treatment and discussing the processes, advantages, and disadvantages of heat treatment of cast iron.

This chapter discusses different thermal processes applicable to the various alloy groups of stainless steels, namely austenitic, ferritic, martensitic, precipitation hardening, and duplex stainless steels. The processes discussed include soaking, annealing, stress relieving, austenitizing, tempering, aging, and conditioning.

One of the primary advantages of steels is their ability to attain high strengths through heat treatment while still retaining some degree of ductility. Heat treatments can be used to not only harden steels but also to provide other useful combinations of properties, such as ductility, formability, and machinability. This chapter discusses various heat treatment processes, namely annealing, stress relieving, normalizing, spheroidizing, and hardening by austenitizing, quenching and tempering. It also discusses two types of interrupted quenching processes: martempering and austempering. The chapter concludes with a brief section on temper embrittlement.

This chapter introduces the principal heat treating processes, namely normalizing, annealing, stress relieving, surface hardening, quenching, and tempering. An overview of four of the more popular surface hardening treatments, namely carburizing, carbonitriding, nitriding, and nitrocarburizing, is provided.

This chapter is a detailed account of heat treating techniques for cast irons (gray and ductile), providing the reader with a basic understanding of the differences among various types of cast irons and the concept of carbon equivalent. The types of heat treatments discussed are stress relieving, annealing, normalizing, surface hardening, quenching, martempering, austempering, and flame and induction hardening.

All superalloys, whether precipitation hardened or not, are heated at some point in their production for a subsequent processing step or, as needed, to alter their microstructure. This chapter discusses the changes that occur in superalloys during heat treatment and the many reasons such changes are required. It describes several types of treatments, including stress relieving, in-process annealing, full annealing, solution annealing, coating diffusion, and precipitation hardening. It discusses the temperatures, holding times, and heating and cooling rates necessary to achieve the desired objectives of quenching, annealing, and aging along with the associated risks of surface damage caused by oxidation, carbon pickup, alloy depletion, intergranular attack, and environmental contaminants. It also discusses heat treatment atmospheres, furnace and fixturing requirements, and practical considerations, including heating and cooling rates for wrought and cast superalloys and combined treatments such as solution annealing and vacuum brazing.

This article covers the metallurgy and properties of gray irons. It describes the classes or grades of gray iron, the types of applications for which they are suited, and the corresponding compositional ranges. It discusses the role of major, minor, and trace elements, how they are added, and how they affect various properties, behaviors, and processing characteristics. It explains how silicon, chromium, and nickel, in particular, improve high-temperature, corrosion, and wear performance.

This chapter discusses the effect of heat treating on titanium alloys and the influence of time and temperature on critical properties and behaviors. It explains how heat treatments are used to make titanium stronger, tougher, more ductile, and easier to machine as well as more resistant to the effects of corrosion and thermal and mechanical fatigue. It describes accepted practices for stress relieving, aging, annealing, and post-treatment processing along with associated challenges and concerns.

Mold steels are used for plastic molding and certain die-casting applications and are designated as group P steels in the AISI classification system. The fabrication and performance requirements that differentiate them from other types of tool steels are described in this chapter. It provides information on hubbing and machined cavity grades of mold steels and describes the performance of the corrosion-resistant mold steels. The chapter discusses the processes involved in forging, annealing, stress relieving, carburizing, hardening, and tempering of mold steels. It presents the selection criteria and applications of mold steels.