A working knowledge of diffusion is necessary to understand and predict the behavior of metals and alloys during manufacturing and in certain types of service. This chapter covers the fundamentals of diffusion in solids and some of the applications in which diffusion plays a role. It discusses the mechanisms behind interstitial, substitutional, grain boundary, and surface diffusion, the derivation and use of Fick’s laws, and the basic principles of diffusion coating processes, including carburizing, nitriding, nitrocarburizing, cyaniding, carbonitriding, boriding, aluminizing, siliconizing, chromizing, vanadizing, and titanizing. It also discusses diffusion bonding and presents several approaches for dealing with oxide barrier problems.

This chapter discusses the basic principles of precipitation hardening, an important strengthening mechanism in nonferrous alloys as well as stainless steel. It begins with a detailed review of the theory of precipitation hardening, then describes its application to aluminum alloys and nickel-base superalloys.

Precipitation hardening is used extensively to strengthen aluminum alloys, magnesium alloys, nickel-base superalloys, beryllium-copper alloys, and precipitation-hardening stainless steels. This chapter discusses two types of particle strengthening: precipitation hardening, which takes place during heat treatment; and true dispersion hardening, which can be achieved by mechanical alloying and powder metallurgy consolidation. It provides information on the three steps of precipitation hardening of aluminum alloys: solution heat treating, rapid quenching, and aging.

This chapter presents an overview of heat treating of nonferrous alloys. First, a brief discussion on the effects of cold work and annealing on nonferrous alloys is presented. This is followed by a discussion on the mechanisms involved in the more commonly used heat treating procedures for hardening or strengthening, namely solution treating and aging. Examples are presented for heat treating of two commercially important nonferrous alloys, one from the aluminum-copper system and one from the copper-beryllium system.

This appendix provides supplemental information on the metallurgical aspects of atomic structure, the use of dislocation theory, heat treatment processes and procedures, important engineering materials and strengthening mechanisms, and the nature of elastic, plastic, and creep strain components. It also provides information on mechanical property and fatigue testing, the use of hysteresis energy to analyze fatigue, a procedure for inverting equations to solve for dependent variables, and a method for dealing with the statistical nature of failure.

This appendix contains abbreviations and symbols related to aluminum alloy castings.

In castings, microstructural features are products of metal chemistry and solidification conditions. The microstructural features, excluding defects, that most strongly affect the mechanical properties or aluminum castings are size, form, and distribution of intermetallic phases; dendrite arm spacing; grain size and shape; and eutectic modification and primary phase refinement. This chapter discusses the effects of these microstructural features on properties and methods for controlling them. The chapter concludes with a detailed examination of the refinement of hypereutectic aluminum-silicon alloys.

Porosity in aluminum is caused by the precipitation of hydrogen from liquid solution or by shrinkage during solidification, and more usually by a combination of these effects. Nonmetallic inclusions entrained before solidification influence porosity formation and mechanical properties. This chapter describes the causes and control of porosity and inclusions in aluminum castings as well as the combined effects of hydrogen, shrinkage, and inclusions on the properties of aluminum alloys. In addition, it discusses the applications of radiography to reveal internal discontinuities in aluminum.

Hot isostatic pressing (HIP) is a process refinement available to address internal porosity in castings. The HIP process may be used, in particular, for applications requiring very high quality and performance. This chapter discusses the principles, advantages, and disadvantages of HIP. It describes the effect of HIP on tensile properties and on the fatigue performance of aluminum alloy castings. In addition, the chapter discusses the processes involved in radiographic inspection of HIP-processed castings.

The metallurgy of aluminum and its alloys offers a range of opportunities for employing heat treatments to obtain desirable combinations of mechanical and physical properties such that castings meet defined temper requirements. This chapter discusses the processes involved in solution heat treatment, quenching, precipitation hardening, and annealing of aluminum alloys. The effects of these processes on dimensional stability and residual stresses are also discussed. Troubleshooting and diagnosis of heat treating problems are covered in the concluding section of the chapter.

This chapter reviews and provides data tables for the wide range of properties and performance characteristics that are possible with specific aluminum casting alloys and tempers. Properties and performance attributes addressed include casting and finishing characteristics; typical physical properties; typical and minimum (design) mechanical properties; fatigue strength; fracture resistance, including subcritical crack growth; and resistance to general corrosion and to stress-corrosion cracking. The chapter concludes with information on the properties of cast aluminum matrix composites.

This data set presents aging response curves for a wide range of aluminum casting alloys. The aging response curves are of two types: room-temperature, or "natural," curves and artificial, or "high-temperature," curves. The curves in each group are presented in the numeric sequence of the casting alloy designation. The curves included are the results of measurements on individual lots considered representative of the respective alloys and tempers. The properties considered are yield strength, ultimate tensile strength, elongation, and Brinell hardness.

This data set contains approximately 50 growth curves for a wide range of aluminum casting alloys at various temperatures. Growth curves are used to determine the dimensional changes that must be anticipated during service in applications where close dimensional tolerances are required. Hardness curves are provided for many of the alloys. The hardness values are from corresponding aging response studies in which measurements were made on individual lots considered representative of the respective alloys and tempers.

The stress-strain curves in this data set are representative examples of the behavior of several cast alloys under tensile or compressive loads. The curves are arranged by alloy designation. Each figure cites the original source of the curve and provides pertinent background information as available. Compressive tangent modulus curves are presented for certain alloys. The effects of cyclic loading are given on several curves.

This data set contains the results of uniaxial tensile tests of a wide range of aluminum casting alloys conducted at high temperatures from 100 to 370 deg C, subzero temperatures from -269 to -28 deg C, and room temperature after holding at high temperatures from 100 to 370 deg C. In most cases, tests were made of several lots of material of each alloy and temper. The results for the several lots were then analyzed together graphically and statistically, and the averages were normalized to the room-temperature typical values. For some alloys, "representative" values (raw data) rather than typical values are provided.

This data set contains the results of uniaxial creep rupture tests for a wide range of aluminum casting alloys conducted at temperatures from 100 to 315 deg C. In most cases, tests were made of several lots of material of each alloy and temper, the results were analyzed, and the averages were normalized to the room-temperature typical values. For some alloys, "representative" values (raw data) rather than typical values are provided.

This data set contains the results of rotating-beam reversed-bending fatigue tests for a wide range of aluminum casting alloys. These fatigue curves are the results of tests on individual lots of material considered representative of the respective alloys and tempers.

This appendix is a compilation of terms and definitions related to cast aluminum products, their production, and their properties.

This appendix contains drawings that illustrate the test specimens used in generating the data related to aluminum alloy castings.

This chapter first introduces the various factors that may alter the physical and mechanical properties of aluminum castings that are addressed in the other chapters in the book. Then, it presents the historical development of aluminum castings, followed by a discussion on the advantages and limitations of aluminum castings. Next, the chapter describes the major trends that are influencing the increased use of aluminum castings. Finally, it introduces the considerations involved in the selection of an appropriate aluminum alloy and casting process for a given application.