This chapter covers the friction and wear behaviors of plastics and elastomers. It begins by describing the molecular differences between the two types of polymers and their typical uses. It then discusses the important attributes of engineering plastics and their suitability for applications involving friction, erosion, and adhesive and abrasive wear. It also discusses the tribology of elastomers and rubber along with their basic differences and the conditions under which they produce Schallamach waves. It includes information on polymer composites as well.

This chapter reviews the tests and procedures used for measuring hardness of plastics and elastomers. The conventional testing methods (Rockwell, Vickers, Brinell, and Knoop) used for testing of metals are based on the idea that hardness represents the resistance against permanent plastic deformation of the material to be tested. However, elastic deformation must be considered in hardness measurement of elastomers. This chapter discusses the equipment and processes involved in the durometer (Shore) test, the International Rubber Hardness Degree test, and other specialized tests. It presents the criteria that can be used to select a suitable hardness testing method for elastomers or plastics and describes processes involved in specimen preparation and equipment calibration.

Elastomers comprise a subclass of polymers that display the ability to stretch and recover that is typical of a rubber band. This chapter describes the properties determined by tensile testing of elastomers and the factors influencing them, namely, structuring of the molecular matrix, compounding, specimen preparation, specimen type, vulcanization parameters, and temperature. The chapter also provides information on ASTM D 412, the most widely referenced standard for determining the tensile properties of elastomers.

This article briefly introduces some commonly used methods of mechanical testing of plastics for determining mechanical properties, also describing the test methods and providing comparative data for the mechanical property tests. In addition, creep testing and dynamic mechanical analyses of viscoelastic plastics are briefly described. The discussion covers the most commonly used tests for impact performance, various types of hardness test for plastics, the fatigue strength of viscoelastic materials, and the tension testing of elastomers and fibers.

This article provides details on several of the classifications of polymer wear mechanisms, using wear data and micrographs from published works. The primary goals are to present the mechanisms of polymer wear and to quantify wear in terms of wear rate. The discussion begins by providing information on the processes involved in interfacial and cohesive wear. This is followed by sections describing the wear process and applications of elastomers, thermosets, glassy thermoplastics, and semicrystalline thermoplastics. The effects of environmental and lubricant on the wear failures of polymers are then discussed. The article further includes a case study describing the tribological performance of nylon. It ends by presenting some examples of wear failures of plastics.

This article discusses the molecular mechanism, environmental criteria, and material optimization of environmental stress crazing (ESC) in glassy thermoplastics, polyethylenes, and nylons. In addition, it provides information on various tests used to determine relative susceptibility to ESC, namely constant tensile load testing and constant-strain testing.

All materials are susceptible to corrosion or some form of environmental degradation. Although no single material is suitable for all applications, usually there are a variety of materials that will perform satisfactorily in a given environment. The intent of this chapter is to review the corrosion behavior of the major classes of metals and alloys as well as some nonmetallic materials, describe typical corrosion applications, and present some unique weaknesses of various types of materials. It also aims to point out some unique material characteristics that may be important in material selection, and discuss, where appropriate, the characteristic forms of corrosion that attack specific materials. The materials addressed in this chapter include carbon steels, weathering steels, and alloy steels; nickel, copper, aluminum, titanium, lead, magnesium, tin, zirconium, tantalum, niobium, and cobalt and their alloys; polymers; and other nonmetallic materials, including rubber, carbon and graphite, and woods.