This appendix is a collection of isothermal diagrams for carbon steels, chromium-molybdenum steels, nickel-chromium-molybdenum steels, nickel-molybdenum steels, and chromium steels.

This appendix is a collection of selected continuous cooling transformation diagrams for carbon steels; Mn steels; Mn-Mo, Mn-Ce, Mn-Ni-Mo, and Mn-Ni-CrMo steels; silicon steels; nickel steels; Ni-Cr-Mo steels; and chromium steels.

Many metallic components, such as retorts in heat treat furnaces, furnace heater tubes and coils in chemical and petrochemical plants, waterwalls and reheater tubes in boilers, and combustors and transition ducts in gas turbines, are subject to oxidation. This chapter explains how oxidation affects a wide range of engineering alloys from carbon and Cr-Mo steels to superalloys. It discusses the kinetics and thermodynamics involved in the formation of oxides and the effect of surface and bulk chemistry. It provides oxidation data for numerous alloys and intermetallics in terms of weight gain, metal loss, depth of attack, and oxidation rate. It also discusses the effect of metallurgical and environmental factors such as oxygen concentration, high-velocity combustion gas streams, chromium depletion and breakaway, component thickness, and water vapor.

This chapter describes the phenomenological aspects of fatigue and how to assess its effect on the life of components operating in high-temperature environments. It explains how fatigue is measured and expressed and how it is affected by loading conditions (stress cycles, amplitude, and frequency) and factors such as temperature, material defects, component geometry, and processing history. It provides a detailed overview of the damage mechanisms associated with high-cycle and low-cycle fatigue as well as thermal fatigue, creep-fatigue, and fatigue-crack growth. It also demonstrates the use of tools and techniques that have been developed to quantify fatigue-related damage and its effect on the remaining life of components.

This chapter covers the failure modes and mechanisms associated with boiler components and the tools and techniques used to assess damages and predict remaining component life. It begins with a review of the design and operation of a utility boiler and the materials used in construction. It then describes the various causes of failure in boiler tubes, headers, and steam pipes, explaining how and why they occur, how they are diagnosed, and how to mitigate their effects. The final and by far largest section in the chapter is a tutorial on damage and life assessment techniques for boiler components and assemblies. It demonstrates the use of various methods, including analytical techniques that estimate life expenditure based on operating history, component geometry, and material properties; predictive methods based on the extrapolation of failure statistics; methods that predict life based on dimensional measurements; methods based on metallographic studies; methods based on temperature estimates; and a method for estimating remaining life under creep conditions based on stress-rupture testing of service-exposed material samples. The chapter also discusses the use of fracture mechanics and presents a number of cases in which life assessments are made based on the integration of several methods.