Alloying, heat treating, and work hardening are widely used to control material properties, and though they take different approaches, they all focus on imperfections of one type or other. This chapter provides readers with essential background on these material imperfections and their relevance in design and manufacturing. It begins with a review of compositional impurities, the physical arrangement of atoms in solid solution, and the factors that determine maximum solubility. It then describes different types of structural imperfections, including point, line, and planar defects, and how they respond to applied stresses and strains. The chapter makes extensive use of graphics to illustrate crystal lattice structures and related concepts such as vacancies and interstitial sites, ion migration, volume expansion, antisite defects, edge and screw dislocations, slip planes, twinning planes, and dislocation passage through precipitates. It also points out important structure-property correlations.

This chapter describes some of the most effective tools for investigating boiler tube failures, including scanning electron microscopy, optical emission spectroscopy, atomic absorption spectroscopy, x-ray fluorescence spectroscopy, x-ray diffraction, and x-ray photoelectron spectroscopy. It explains how the tools work and what they reveal. It also covers the topic of image analysis and its application in the measurement of grain size, phase/volume fraction, delta ferrite and retained austenite, inclusion rating, depth of carburization/decarburization, scale thickness, pearlite banding, microhardness, and hardness profiles. The chapter concludes with a brief discussion on the effect of scaling and deposition and how to measure it.

This chapter serves as a study and guide on the main phase constituents of cast aluminum-silicon alloys, alpha-Al solid solution and Si crystals. The first section focuses on the structure of Al-Si castings in the as-cast state, covering the morphology of the alpha-Al solid solution grains and the process by which they form. It describes how cooling rates, temperature gradients, and local concentrations influence the topology of the crystallization front, and how they play a role in determining the morphology and dispersion degree of the grains observed in cross sections of cast parts. It also describes the mechanism behind dendritic grain crystallization and how factors such as surface tension, capillary length, and lattice symmetry affect dendritic arm size and spacing. The section that follows examines the morphology of the silicon crystals that form in aluminum-silicon castings and its effect on properties and processing characteristics. It discusses the faceted nature of primary Si crystals and the modification techniques used to optimize their shape. It also describes the morphology of the (alpha-Al + Si) eutectic, which can be lamellar or rodlike in shape, and explains how it can be modified through temperature control or alloy additions to improve properties such as tensile strength and plasticity and reduce shrinkage.

The practical application of metals and alloys is guided largely by information obtained through the study of their microstructure. This chapter examines a wide range of titanium microstructures, identifying characteristic features and explaining what they reveal about processing, properties, and performance. It includes images of elongated and equiaxed structures, primary alpha, transformed beta, and metastable phases as well as spheroidal and intergranular beta, alpha case, and intermetallic compounds. It also defines important terms and provides step-by-step procedures for preparing titanium for metallographic analysis.

The solidification process has a major influence on the microstructure and mechanical properties of metal casting as well as wrought products. This appendix covers the fundamentals of solidification. It discusses the formation of solidification structures, the characteristics of planar, cellular, and dendritic growth, the basic freezing sequence for an alloy casting, and the variations in cooling rate, heat flow, and grain morphology in different areas of the mold. It also describes the types of segregation that occur during freezing, the effect of solidification rate on secondary dendrite arm spacing, and the factors that contribute to porosity and shrinkage.

This chapter provides an overview of beryllium casting practices and the challenges involved. It discusses the stages of solidification, the effect of cooling rate, the difficulty of heat removal, and the potential for hot cracking. It describes common melting techniques, including vacuum induction melting, vacuum arc melting, and electron beam melting, and some of the ways they have been used to cast beryllium alloys. The chapter also includes information on metal purification and grain refinement procedures.

Bonding in solids may be classified as either primary or secondary bonding. Methods of primary bonding include the metallic, ionic, and covalent bonds. This chapter discusses and provides a comparison of the properties of these bonds. This is followed by a discussion on crystalline structure, providing information on space lattices and crystal systems, hexagonal close-packed systems, and face-centered and body-centered cubic systems. The chapter then covers slip systems and closes with a brief section on allotropic transformations that occur at a constant temperature during either heating or cooling.

In a perfect crystalline structure, there is an orderly repetition of the lattice in every direction in space. Real crystals contain a considerable number of imperfections, or defects, that affect their physical, chemical, mechanical, and electronic properties. Defects play an important role in processes such as deformation, annealing, precipitation, diffusion, and sintering. All defects and imperfections can be conveniently classified under four main divisions: point defects, line defects, planar defects, and volume defects. This chapter provides a detailed discussion on the causes, nature, and impact of these defects in metals. It also describes the mechanisms that cause plastic deformation in metals.

When a metal is alloyed with another metal, either substitutional or interstitial solid solutions are usually formed. This chapter discusses the general characteristics of these solutions and the effects of several alloying elements on the yield strength of pure metals. It presents four rules that give a qualitative estimate of the ability of two metals to form substitutional solid solutions: relative size factor, chemical affinity factor, relative valency factor, and lattice type factor. The chapter provides information on alloys that form an ordered structure during heating. It describes the intermediate phases that are formed during solidification between the two extremes of substitutional solid solution on the one hand and intermetallic compound on the other. The chapter concludes with a section on strain aging in low-carbon steels that allows the interstitial atoms to diffuse to the dislocations and again form atmospheres that pin dislocation movement.

This chapter provides a short introduction to phase transformations, namely, the liquid-to-solid phase transformations that occur during solidification and the solid-to-solid transformations that are important in processing, such as heat treatment. It also introduces the concept of free energy that governs whether or not a phase transformation is possible, and then the kinetic considerations that determine the rate at which transformations take place. The chapter also describes important solid-state transformations such as spinodal decomposition and martensitic transformation.

Diffusion is the movement of atoms through the crystalline lattice. This chapter discusses the two main types of diffusion that can occur in solids: interstitial diffusion and substitutional diffusion. It describes Fick's first and second laws of diffusion, with emphasis on several applications of the latter. The chapter also provides information on the temperature dependence of diffusion, intrinsic diffusion coefficients (Kirkendall effect), and high diffusion paths.

Phase diagrams are graphical representations that show the phases present in the material at various compositions, temperatures, and pressures. This chapter begins with a section describing the construction of phase diagrams for the simple binary isomorphous system. A binary phase diagram can be used to determine three important types of information: the phases that are present, the composition of the phases, and the percentages or fractions of the phases. The chapter then describes the construction of one common type of binary phase diagram i.e., the eutectic alloy system. The major eutectic systems include the aluminum-silicon eutectic system and the lead-tin eutectic system. The chapter discusses the construction of eutectic phase diagrams from free energy curves. It also provides information on peritectic, monotectic, and solid-state reactions in alloy systems. The presence of intermediate phases is also described. Finally, a brief section provides some information on ternary phase diagrams.

Almost all metals and alloys are produced from liquids by solidification. For both castings and wrought products, the solidification process has a major influence on both the microstructure and mechanical properties of the final product. This chapter discusses the three zones that a metal cast into a mold can have: a chill zone, a zone containing columnar grains, and a center-equiaxed grain zone. Since the way in which alloys partition on freezing, it follows that all castings are segregated to different categories. The different types of segregation discussed include normal, gravity, micro, and inverse. The chapter also provides information on grain refinement and secondary dendrite arm spacing and porosity and shrinkage in castings. It concludes with a brief overview of six of the most important casting processes in industries: sand casting, plaster mold casting, evaporative pattern casting, investment casting, permanent mold casting, and die casting.

Annealing, a heat treatment process, is used to soften metals that have been hardened by cold working. This chapter discusses the following three distinct processes that can occur during annealing: recovery, recrystallization, and grain growth. The types of processes that occur during recovery are the annihilation of excess point defects, the rearrangement of dislocations into lower-energy configurations, and the formation of subgrains that grow and interlock into sub-boundaries. The article also discusses the main factors that affect recrystallization. They are temperature and time; degree of cold work; purity of the metal; original grain size; and temperature of deformation. The types of grain growth discussed include normal or continuous grain growth and abnormal or discontinuous grain growth.

Precipitation hardening is used extensively to strengthen aluminum alloys, magnesium alloys, nickel-base superalloys, beryllium-copper alloys, and precipitation-hardening stainless steels. This chapter discusses two types of particle strengthening: precipitation hardening, which takes place during heat treatment; and true dispersion hardening, which can be achieved by mechanical alloying and powder metallurgy consolidation. It provides information on the three steps of precipitation hardening of aluminum alloys: solution heat treating, rapid quenching, and aging.

This chapter examines the isothermal phase transformations of the iron-carbide system. The discussion includes the formation of ferritic, eutectoid, hypoeutectoid, hypereutectoid, bainitic, and martensitic microstructures as well as their properties, composition, and metallurgy. The use of time-temperature-transformation (TTT) diagrams in understanding the phase transformations and the changes in the isothermal transformation curves due to the addition of carbon and other alloying elements are also discussed.

One of the primary advantages of steels is their ability to attain high strengths through heat treatment while still retaining some degree of ductility. Heat treatments can be used to not only harden steels but also to provide other useful combinations of properties, such as ductility, formability, and machinability. This chapter discusses various heat treatment processes, namely annealing, stress relieving, normalizing, spheroidizing, and hardening by austenitizing, quenching and tempering. It also discusses two types of interrupted quenching processes: martempering and austempering. The chapter concludes with a brief section on temper embrittlement.

The mechanical behavior of a material is its response to an applied load or force. Important mechanical properties are strength, hardness, stiffness, and ductility. This chapter discusses three principal ways in which these properties are tested: tension, compression, and shear. Important tensile properties that can be determined by the tensile test include yield strength, ultimate tensile strength, ductility, resilience, and toughness. The chapter describes the effects of stress concentrations on ductile metals under cyclic loads. Other topics covered include combined stresses, yield criteria, and residual stresses of metals.

Fracture is the separation of a solid body into two or more pieces under the action of stress. Fracture can be classified into two broad categories: ductile fracture and brittle fracture. Beginning with a comparison of these two categories, this chapter discusses the nature and causes of these failure modes. Some body-centered cubic and hexagonal close-packed metals, and steels in particular, exhibit a ductile-to-brittle transition when loaded under impact and the chapter describes the use of notched bar impact testing to determine the temperature at which a normally ductile failure transitions to a brittle failure. The discussion then covers the Griffith theory of brittle fracture and the formulation of fracture mechanics. Procedures for determination of the plane-strain fracture toughness are subsequently covered. Finally, the chapter describes the effects of microstructural variables on fracture toughness of steels, aluminum alloys, and titanium alloys.

Fatigue failures occur due to the application of fluctuating stresses that are much lower than the stress required to cause failure during a single application of stress. This chapter describes three basic factors that cause fatigue: a maximum tensile stress of sufficiently high value, a large enough variation or fluctuation in the applied stress, and a sufficiently large number of cycles of the applied stress. The discussion covers high-cycle fatigue, low-cycle fatigue, and fatigue crack propagation. The chapter then discusses the stages where fatigue crack nucleation and growth occurs. It describes the most effective methods of improving fatigue life. The chapter also explains the effect of geometrical stress concentrations on fatigue. In addition, it explores the environmental effects of corrosion fatigue, low-temperature fatigue, high-temperature fatigue, and thermal fatigue. Finally, the chapter discusses a number of design philosophies or methodologies to deal with design against fatigue failures.