This chapter presents an overview on the twins and stacking faults. It then provides an overview of the compositions, microstructures, thermodynamics, processing, deformation mechanism, mechanical properties, formability, and special attributes of twinning-induced plasticity steels.

This chapter presents a discussion on the grain sizes and boundaries in nanocrystals. It discusses the third-generation nanotechnology in advanced high-strength steels.

This chapter examines the microstructure of metallic components produced by casting and compares them with microstructures achieved by means of powder metallurgy. It shows how metals and alloys obtained by various processing routes differ in terms of grain size, secondary phases, oxide and carbide dispersions, porosity, dendritic formation, and properties such as hardness, toughness, tensile strength, and yield strength.

The appendix contains detailed simulation examples through which readers learn how to format and analyze problems using the LAMMPS molecular dynamics simulator. By means of simulation, readers will determine the thermal expansion coefficient of copper, generate stress-strain plots for aluminum at different temperatures, calculate the surface energy of copper for different crystal orientations, investigate diffusion effects in BCC iron, estimate the sliding friction between graphene layers, compare the stacking fault energy of silver and aluminum, and analyze the properties and behaviors of liquids and gases. All examples employ a systematic problem-solving approach and include necessary input code.

A working knowledge of diffusion is necessary to understand and predict the behavior of metals and alloys during manufacturing and in certain types of service. This chapter covers the fundamentals of diffusion in solids and some of the applications in which diffusion plays a role. It discusses the mechanisms behind interstitial, substitutional, grain boundary, and surface diffusion, the derivation and use of Fick’s laws, and the basic principles of diffusion coating processes, including carburizing, nitriding, nitrocarburizing, cyaniding, carbonitriding, boriding, aluminizing, siliconizing, chromizing, vanadizing, and titanizing. It also discusses diffusion bonding and presents several approaches for dealing with oxide barrier problems.

This chapter provides readers with worked solutions to more than 25 problems related to compositional impurities and structural defects. The problems deal with important issues and challenges such as the design of low-density steels, the causes and effects of distortion in different crystal structures, the ability to predict the movement of dislocations, the influence of impurities on defects, the relationship between gain size and material properties, the identification of specific types of defects, the selection of compatible metals for vacuum environments, and the effect of twinning planes on stacking sequences. The chapter also includes problems on how the formation of precipitates can produce slip planes and how grain boundaries can act as obstacles to dislocation motion.

The building block of all matter, including metals, is the atom. This chapter initially provides information on atomic bonding and the crystal structure of metals and alloys, followed by a description of three crystal lattice structures of metals: face-centered cubic, hexagonal close-packed, and body-centered cubic. It then describes the four main divisions of crystal defects, namely point defects, line defects, planar defects, and volume defects. The chapter provides information on grain boundaries of metals, processes involved in atomic diffusion, and key properties of a solid solution. It also explains the aspects of a phase diagram that shows what phase or phases are present in the alloy under conditions of thermal equilibrium. Finally, a discussion on the applications of equilibrium phase diagrams is presented.

This chapter explains how the presence of intermediate phases affects the melting behavior of binary alloys and the transformations that occur under different rates of cooling. It begins by examining the phase diagrams of magnesium-lead and copper-zinc, noting some of the complexities associated with intermediate phases. It then discusses the difference between ordered and disordered phases and how they are accounted for on phase diagrams. It describes how the atoms in a disordered solution may arrange themselves into an ordered array, forming a superlattice in the process of cooling, and goes on to identify the most common superlattice structures and their corresponding alloy phases. It also discusses the factors that limit the formation of superlattices along with the kinetics of spinodal decomposition and its effect on microstructure development.

This appendix provides a detailed overview of the crystal structure of metals. It describes primary bonding mechanisms, space lattices and crystal systems, unit cell parameters, slip systems, and crystallographic planes and directions as well as plastic deformation mechanisms, crystalline imperfections, and the formation of surface or planar defects. It also discusses the use of X-ray diffraction for determining crystal structure.

This chapter discusses the typical compositional ranges of superalloys, the role of major base metals (iron, cobalt, and nickel), and the effects of common alloying additions. It describes how chromium, aluminum, and titanium as well as refractory elements, grain-boundary elements, reactive elements, and oxides influence mechanical properties and behaviors. It also discusses the effect of trace elements.

This chapter familiarizes readers with the mechanisms involved in creep and how they are related to fatigue behavior. It explains that what we observe as creep deformation is the gradual displacement of atoms in the direction of an applied stress aided by diffusion, dislocation movement, and grain boundary sliding. It describes these mechanisms in qualitative terms, explaining how they are driven by thermal energy and how they can be analyzed using creep curves and deformation maps. In addition, it examines the types of damage associated with creep, presents a number of creep strain and strain rate equations, explains how to determine creep constants, and reviews the findings of several studies on cyclic loading. It also discusses the development of a novel test that measures the cyclic creep-rupture resistance of materials in tension and compression.

Strain-range partitioning is a method for assessing the effects of creep fatigue based on inelastic strain paths or strain reversals. The first part of the chapter defines four distinct strain paths that can be used to model any cyclic loading pattern and describes the microstructural damages associated with each of the four basic loading cycles. The discussion then turns to fatigue life prediction for different types of materials and more realistic loading conditions, particularly those in which hysteresis loops have more than one strain-range component. To that end, the chapter considers two cases. In one, the relationship between strain range and cyclic life is established from test data. In the other, a rule is required to determine the damage of each concurrent strain and the total damage of the cycle is used to predict creep-fatigue life. The chapter presents several such damage rules and discusses their applicability in different situations.

This chapter considers various behaviors of microstructural interfaces from a thermodynamics viewpoint. It discusses energy of surface and interface, the Gibbs-Thomson Effect, grain-boundary segregation, smooth and rough interfaces, and grain growth.

In a perfect crystalline structure, there is an orderly repetition of the lattice in every direction in space. Real crystals contain a considerable number of imperfections, or defects, that affect their physical, chemical, mechanical, and electronic properties. Defects play an important role in processes such as deformation, annealing, precipitation, diffusion, and sintering. All defects and imperfections can be conveniently classified under four main divisions: point defects, line defects, planar defects, and volume defects. This chapter provides a detailed discussion on the causes, nature, and impact of these defects in metals. It also describes the mechanisms that cause plastic deformation in metals.

This chapter focuses on the processes and mechanisms involved in fatigue. It begins with a review of some of the early theories of fatigue and the tools subsequently used to obtain a better understanding of the fatigue process. It then explains how plasticity plays a major role in creating dislocations, breaking up grains into subgrains, and causing microscopic imperfections to coalesce into larger flaws. It also discusses the factors that contribute to the development and propagation of fatigue cracks, including surface deterioration, volumetric and environmental effects, foreign particles, and stresses generated by rolling contact.

This chapter examines the structural changes that occur in high-carbon steels during austenitization. It describes the effect of heating time and temperature on the production of austenite and the associated transformation of ferrite and cementite in eutectoid, hypoeutectoid, and hypereutectoid steels. It discusses the factors that influence the kinetics of the process, including carbon diffusion and the morphology of the original structure. It describes the nucleation and growth of austenite grains, the effect of grain size on mechanical properties, and the difference between coarse- and fine-grained steels. The chapter also discusses grain-refinement processes and some of the effects of overheating, including sulfide spheroidization, grain-boundary sulfide precipitation, and grain-boundary liquation.