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Abstract

This chapter lays the groundwork for understanding electrode kinetics associated with corrosion. It presents a simple but useful theory relating kinetics to the polarization behavior of half-cell reactions. The theory is based on the observation that electrode potentials vary as a function of current density or charge transfer in a given area. The chapter explains how to measure and plot electrode potentials and currents and how to interpret the resulting polarization curves. It also discusses the effects of concentration gradients, explaining how they cause diffusion and, in some cases, produce changes in electrode potential.

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Kinetics of Single Half-Cell Reactions, Fundamentals of Electrochemical Corrosion, By E.E. Stansbury, R.A. Buchanan, ASM International, 2000, p 87–125, https://doi.org/10.31399/asm.tb.fec.t65940087

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