NiCoCrAlY coatings are widely used as bond coats for ceramic thermal barrier coatings (TBCs) and oxidation and corrosion protective overlay coatings in industrial gas turbines. High temperature oxidation behaviour of NiCoCrAlYs has a great influence on the coating performance and lifetime of TBCs. A promising route to decrease the oxidation rate of such coatings is post-coating surface modification which can facilitate formation of a uniform alumina scale with a considerably slower growth rate compared to the as-sprayed coatings. In this work, the effect of surface treatment by means of shot peening and laser surface melting (LSM) on the oxidation resistance of high velocity air-fuel (HVAF) sprayed NiCoCrAlY coatings was studied. Isothermal oxidation was carried out at 1000 °C for 1000h. Results showed that the rough surface of as-sprayed HVAF sprayed coatings was significantly changed after shot peening and LSM treatment, with a compact and smooth appearance. After the exposure, the oxide scales formed on surface-treated NiCoCrAlY coatings showed different morphology and growth rate compared to those formed on as-sprayed coating surface. The oxidation behaviour of surface treated HVAF-sprayed NiCoCrAlY coatings were revealed and discussed.

This study evaluates the effect of Ru and Ce on the oxidation behavior of NiCoCrAl coatings deposited by HVOF spraying. Isothermal oxidation tests were conducted at 900, 1000, and 1100 °C. Test samples were also cycled between 100 °C and 1100 °C, with a dwell time of 1 h at 1100 °C. In both cases, coatings with Ru had a lower oxidation rate than those with Ce additions. β-depletion due to interdiffusion was also found to be lower when Ru was present. To help explain the findings, simulation results are presented and discussed along with observations on the influence of oxidation time on microstructure evolution.