Martensitic steels must be tempered to increase their toughness and ductility. The tempering process requires heating from room temperature to the desired tempering temperature. In this paper, the effects of heating rates on carbide precipitate size distribution, chemistry, and precipitate density will be discussed. As-quenched martensite in AISI 4140 steel was heated to selected tempering temperatures in air furnaces as well as by induction. The heating rates for tempering vary from 30 seconds to 20 minutes. The experimental results are presented, and carbides were characterized using an extraction technique.