The present work evaluates the oxidation and hot corrosion resistance of high velocity oxy-fuel (HVOF) sprayed WC-NiCrFeSiB coating deposited on Ni-based superalloy (Superni 75) and Fe-based superalloy (Superfer 800H). The coated as well as uncoated specimens were exposed to air and molten salt (Na 2 SO 4 -25%NaCl) environment at 800 °C under cyclic conditions. The thermogravimetric technique was used to establish the kinetics of corrosion. The corrosion products were characterized using the combined techniques of X-ray diffraction (XRD), scanning electron microscopy (SEM) and electron probe micro analyser (EPMA). The WC-NiCrFeSiB coating provides necessary resistance against oxidation and hot corrosion to both the nickel and iron based superalloys in the given environmental conditions at 800 °C. The oxides of active elements of the coatings, formed in the surface scale as well as at the boundaries of nickel and tungsten rich splats, have contributed for the oxidation and hot corrosion resistance of WC-NiCrFeSiB coatings, as these oxides act as barriers for the diffusion/penetration of the corrosive species through the coatings.

In this study, high velocity-oxy fuel (HVOF) technique was used to deposit Cr 3 C 2 -NiCr coating on the Ni-base superalloys for their hot corrosion applications. The coatings were characterised with regard to coating thickness, porosity, microhardness and microstructure. The hot corrosion behaviours of the bare and Cr 3 C 2 -NiCr coated superalloys were studied after exposure to molten salt (Na 2 SO 4 -60%V 2 O 5 ) at 900°C under cyclic conditions. Optical microscopy, XRD, SEM/EDAX and EPMA techniques were used to characterise the coatings. The thermogravimetric technique was used to establish kinetics of corrosion. The structure of the as sprayed Cr 3 C 2 -NiCr coating mainly consisted of γ-nickel solid solution with very low intensity peaks of Cr 7 C 3 and Cr 2 O 3 phases. Some porosity (less than 1.5%), inclusions, unmelted and semi-melted powder particles were observed in the structure of the coatings. Coating microhardness values were found to be in the range of 850-900 Hv (Vickers hardness). The Cr 3 C 2 - NiCr coating was resistant to hot corrosion in the given molten salt environment at 900°C. The hot corrosion resistance imparted by Cr 3 C 2 -NiCr coatings may be attributed to the formation of oxides of nickel, chromium, and spinels of nickel and chromium.