In cold spraying, oxide-free interface is an important factor for fresh metal bonding between particles and substrate, which determines the bonding strength and final coating quality. In this study, a well-designed experiment was performed to examine the deformation behaviour of the oxide film on copper alloy particle surface after deposition. The experiment results show that partial oxide film could be disrupted during the high-speed impact. However, most of the oxide films were found to remain intact after particle deposition, which limited the exposure of oxide free interface. The presence of oxide film at the interfaces between deposited particles and substrate seriously affected the metallurgical bonding. Besides, substrate material is found to have a strong influence on the deformation behaviour and final state of the oxide film. The study also demonstrated that the bonding mode between deposited particle and substrate strongly depends on the type of substrate.

An innovative hybrid process which combines the two very effective solid-state techniques of cold spraying (CS) and friction stir processing (FSP), was proposed to fabricate a high-strength ultrafine-grained Cu-Zn coating. Results show that the CS coating had an elongated microstructure with 78.42% of low-angle grain boundaries. Following FSP, there appear ultrafine grains with 90.47% of high-angle grain boundaries and a composition of α, β' and γ phases while the CS coatings was mainly α. Significant mechanical properties enhancement is achieved, i.e. with the ultimate tensile strength increasing from 87.2 MPa to 257.5 MPa and fracture elongation increasing from 0.17% to 0.81%. The precipitates have a significant effect on the fracture behavior of FSP coatings.

ZnO nanostructured coatings have been prepared on Al 2 O 3 substrates fitted with Au electrodes on one side and a Pt heater on the other, forming a solid-state gas sensor. The coatings were deposited by solution precursor plasma spraying (SPPS) using aqueous zinc acetate as the precursor solution. FE-SEM images show that the coatings are nanostructured with grain sizes of 50-100 nm. Surface morphology and grain size were found to be influenced by the flow rate of H 2 in the plasma forming gas. The gas sensing function was characterized by measuring the electrical resistance of the coating in the presence of NO 2 gas, showing good sensitivity down to the sub-ppm range.

Gas permeation behaviour through atmospheric plasma-sprayed 8 mol% yttria stabilized zirconia (YSZ) electrolyte coating was studied experimentally. YSZ coatings were fabricated using different powder feedstock. The temperature and velocity of in-flight particles during spraying were measured with a diagnostic system. The results showed that particle temperature and velocity were significantly influenced by the size of powders. The gas permeability of these coatings was estimated by a specific instrument with pure O 2 , N 2 and H 2 . It was found that the gas permeability was reduced by decreasing the size of powder. Gas permeation behaviour through plasma-sprayed YSZ coating was studied. Transition flow was compatible to gas permeation behaviour for all three plasma-sprayed YSZ coatings. The relationship between gas permeation behaviour and coating microstructure is discussed in this article.

In this paper, the effect of velocity on the characteristics of atmospheric plasma sprayed yttria stabilized zirconia was investigated through adjusting auxiliary helium flow. The temperature and velocity of in-flight particles were measured with DPV2000 analyzer. The results showed that helium flow significantly influenced particle velocity and less distinctly influenced particle temperature. The microstructure of the coatings was characterized by scanning electron microscopy and X-ray diffraction analyzer. The ionic conductivity of the deposits through thickness direction was measured by a potentiostat/galvanostat based on three-electrode assembly approach in a temperature range of 500-1000 °C. The specific gas permeability was estimated. The results showed that the gas permeability was improved by increasing the in-flight particle velocity. However, the in-flight particle velocity has little effect on the ionic conductivity of specimens.