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J.A. Calero
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Proceedings Papers
ITSC1998, Thermal Spray 1998: Proceedings from the International Thermal Spray Conference, 741-746, May 25–29, 1998,
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The ball-on-disk wear test is widely used in order to determine the sliding wear resistance behaviour of the samples. Although a great number of authors consider the ball-on-disk test to be far from the real situation, the results obtained permit to develop a preliminary idea about the wear behaviour of the tested samples. During the development of the ball-on-disk test a wear track is formed on the test specimen. Scanning white light interferometry can be used to determine the surface damage in the wear track by obtaining images which relate to the surface profile and general morphology. From measurements on interferometric profiles it is possible to determine accurately the track depth and width and hence the volume of the coating removed by wear. It is also possible to determine by optical microscopy the volume of metal lost from the ball. The results obtained have improved the general understanding of the energy absorption during wear and of the observed changes in the coefficient of friction. The results obtained have shown that with the coatings of WC-Co deposited by the HVOF process no volumetric changes occur when using a WC-6%Co sintered ball. Tests on coatings containing TiC or Cr3CZ as the carbide phase or stainless steel coatings show significant losses of material.
Proceedings Papers
ITSC1997, Thermal Spray 1997: Proceedings from the United Thermal Spray Conference, 717-721, September 15–18, 1997,
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Chromium carbide-nickel chromium coatings produced by HVOF spraying are widely used for high temperature wear and erosion resistant applications. Examination of the literature shows that whilst the mechanical properties of these coatings have been widely investigated, there has been little research into the physical processes occurring during HVOF spraying of this system, such as carbide dissolution, liquid-metallic phase oxidation, decarburisation and rapid solidification. The purpose of the present work has been to perform a systematic characterisation of the chromium carbide-nickel chromium system in both the initial powder and as-sprayed states with a variety of spraying conditions using optical, scanning and transmission electron microscopy, electron microprobe and X-ray diffraction. The presence of amorphous and nanocrystalline phases has been demonstrated. The nanocrystalline structures tend to be Ni rich, with the amorphous phases rich in Cr. Carbides of the form Cr 3 C 2 were found to be dissolved slightly during spraying, increasing the Cr and C contents of the liquid metallic phase. There was no evidence of chromium carbide oxidation.
Proceedings Papers
ITSC1997, Thermal Spray 1997: Proceedings from the United Thermal Spray Conference, 943-948, September 15–18, 1997,
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Mathematical modelling of the formation of the WC-Co coating structure and adhesion on copper substrate during high velocity oxygen-fuel (HVOF) spraying is provided. Smooth (polished) and rough (grit blasted) substrates are considered. Variations of solidification time, solidification velocity, thermal gradient, and cooling velocity in the coating and substrate interfacial region are studied. Formation of the amorphous and crystalline structures in the coating and of the crystalline structure in the substrate interfacial region is investigated. Behaviour of the crystal size and intercrystalline distance with respect to the thermal spray parameters and morphology of the substrate surface is analysed. Optimal conditions for the development of fine and dense crystalline structure are determined. Mechanical and thermal mechanisms of development of the substrate-coating adhesion are discussed. Results obtained agree well with experimental data.