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H. Hawthorne
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Proceedings Papers
ITSC 2003, Thermal Spray 2003: Proceedings from the International Thermal Spray Conference, 405-410, May 5–8, 2003,
Abstract
View Papertitled, Erosion Behavior of WC-10Co-4Cr HVOF Coatings
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for content titled, Erosion Behavior of WC-10Co-4Cr HVOF Coatings
Among the WC based cermets coating materials, those using the 10%Co-4%Cr matrix demonstrate excellent wear and corrosion properties. In this paper the erosion behaviors of WC-10%Co-4%Cr HVOF coatings was evaluated under different erosion conditions. The coatings were obtained from the JP-5000 gun using kerosene as fuel and the Diamond Jet gun using propylene and hydrogen. Two types of powder morphology were used: the first type was coarse and angular while the second was smaller, porous and spherical. The coatings were submitted to dry and slurry erosion. Erosion tests were performed at room temperature for both dry and slurry erosion. Dry erosion was evaluated by jet erosion while for slurry erosion, two different tests were performed: Coriolis and jet impingement erosion. Experimental results show that for the same powder, the erosion resistance measured by the Coriolis test exhibits 100% variation while for jet impingement it varies only by 20% depending on gun and spray conditions. The results also show that the powder selection is one of the key factors controlling the coating performance. The selection of powder can affect the Coriolis erosion resistance by more than 300% and the dry and slurry erosion resistance by 75%. The results are analyzed as a function of the processing and coating microstructure.
Proceedings Papers
ITSC 2001, Thermal Spray 2001: Proceedings from the International Thermal Spray Conference, 1051-1060, May 28–30, 2001,
Abstract
View Papertitled, HVOF Process Optimization for the Erosion Resistance of WC-12Co and WC-10Co-4Cr Coatings
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for content titled, HVOF Process Optimization for the Erosion Resistance of WC-12Co and WC-10Co-4Cr Coatings
Recent studies have demonstrated that WC-12Co and WC- 10Co-4Cr coatings were the best performing HVOF coatings against erosion. This paper looks at the influences of the HVOF process parameters for WC-12Co and WC-10Co-4Cr materials on the erosion resistance of the coatings. The effect of powder morphology, matrix chemistry and HVOF process parameters with respect to both silica slurry erosion and alumina dry erosion has been studied. All coatings were produced using the HVOF JP-5000 system with kerosene-oxygen flame. The spraying parameters were analyzed in term of sprayed particle velocity and temperature as measured with the DFV2000 optical diagnostic system. Simultaneously with in-flight particle measurements, the substrate-coating temperature was monitored by infrared pyrometry during coating deposition. The resulting coating microstructure was evaluated in terms of microhardness, porosity type and extent of wear damage after dry and slurry erosion. The material volume loss under various erosion conditions was related to the coating properties and microstructure. According to the experimental results, the following conclusions are drawn: 1) the kerosene flow rate affects the inflight particle state (velocity and temperature) and the coating porosity. 2) Cobalt-chrome matrix cermet performs better in slurry erosion while denser and harder cobalt matrix cermet performs better in dry erosion. 3) The use of kerosene-rich flame with lower oxygen stoichiometry reduces the carbide degradation and optimizes the wear performance of WC-12Co coatings in both dry and slurry erosion.
Proceedings Papers
ITSC1999, Thermal Spray 1999: Proceedings from the United Thermal Spray Conference, 422-427, March 17–19, 1999,
Abstract
View Papertitled, Slurry and Dry Erosion of Arc-Sprayed Metal and Composite Coatings
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for content titled, Slurry and Dry Erosion of Arc-Sprayed Metal and Composite Coatings
Arc spraying can be used to produce coatings to protect against wear and tear against erosion. This paper presents some results obtained within the core research program of the NRC Technology Group in Surface Engineering on the development of erosion-resistant coatings. A relationship is established between the volume loss of the material (performance) under different erosion conditions and the coating properties or the microstructure. The results show that the wear behavior of the arc-sprayed materials depends on the type, size and impact strength of the impacting eroding particles. It is observed that for soft materials, even if ductile tearing is an active mode of degradation, the brittle behavior of intersplat oxides also plays an important role. For harder materials, this brittle delamination of splats becomes the dominant erosive mechanism, as can be observed on the worn surfaces. Paper includes a German-language abstract.
Proceedings Papers
ITSC1998, Thermal Spray 1998: Proceedings from the International Thermal Spray Conference, 231-236, May 25–29, 1998,
Abstract
View Papertitled, Slurry and Dry Erosion of High Velocity Oxy-Fuel Thermal Sprayed Coatings
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for content titled, Slurry and Dry Erosion of High Velocity Oxy-Fuel Thermal Sprayed Coatings
Improvement of the high velocity oxy-fuel deposition (HVOF) process in the last decade has led to coatings with significant improved microstructures for better protection against wear and corrosion. HVOF coatings of cermet and metallic materials provide protection against erosion and are therefore good alternatives to the use of high-priced material. This paper presents the results of a study undertaken within the core research program of the National Research Council of Canada technology group in surface engineering, "SURFTEC", in which the performance of ten HVOF erosion-resistant coatings were evaluated under both dry and slurry erosion. Ten different types of HVOF coatings were studied including: six grades of WC with either Co or a Ni based matrix, one grade of Cr3C2 in a Ni-Cr matrix, and three grades of metallic alloy: Ni alloy, Co alloy and a SS 316-L. Coatings performance was evaluated with respect to the volume ratio and composition of metallic binder in carbide coatings, type of carbide, coating microstructure, impinging angle and the size of the erodent particles. All coatings were produced using the HVOF IP5000 system controlled by the Hawcs-II controller. Slurry jet erosion tests were conducted using a 10 %w/w alumina particle/water slurry. Two alumina particle sizes, 320 and 80 grit (nominal grain diameters 35 μm and 200 μm, respectively) were used. The nominal impact velocity of the slurry was 15 m/s and the nozzle-specimen distance 100 mm. Dry erosion tests were conducted using 50 μm diameter alumina particles projected onto coated flat test coupons through a carbide nozzle of diameter 1.14mm with a particle velocity of 84 m/s at a feed rate of 2 ±1 g/min. let impingement angles of 90° and 20° were used for both dry and slurry erosion tests. The volume loss of material under various erosion conditions was related to the coating properties and microstructure. Results indicate that the coating behavior is dependent on the erodent particle size, the erosion impinging angle to some extent and for slurry erosion, to the corrosion resistance of the cermet matrix.
Proceedings Papers
ITSC1997, Thermal Spray 1997: Proceedings from the United Thermal Spray Conference, 97-106, September 15–18, 1997,
Abstract
View Papertitled, Slurry Erosion of High Velocity Oxy-fuel Thermal Sprayed Coatings
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for content titled, Slurry Erosion of High Velocity Oxy-fuel Thermal Sprayed Coatings
Improvement of the high velocity oxy-fuel deposition (HVOF) process in the last decade has enhanced the microstructure of coatings in order to better perform against wear and corrosion. Indeed cermet and metal HVOF coatings are reliable and have excellent performance under slurry erosion and provide therefore an alternative to the use of high-priced material. This paper presents the results of a study undertaken within the core research program of the National Research Council of Canada technology group in surface engineering, "SURFTEC", in which the performance of ten HVOF erosion-resistant coatings was evaluated. Ten different types of HVOF coatings were studied including: six grades of WC with either Co or a Ni based matrix, one grade of Cr 3 C 2 in a Ni-Cr matrix, and three grade of metallic alloy: Ni alloy, Co alloy and a SS 316- L. The performance of coatings was evaluated with respect to: the volume ratio and composition of metallic binder in carbide coatings, type of carbide, coating microstructure, impinging angle and the size of the erodent particles. All coatings were produced using the HVOF JP-5000 system controlled by the Hawcs-ll controller. Slurry erosion tests were conducted with a jet impingement rig with a 10 %w/w alumina particle/water slurry. The volume loss of material under various slurry erosion conditions was related to the coating properties and microstructure. Results indicate that the behavior of HVOF sprayed materials is dependent on the erodent particle size, to the erosion impinging angle to some extent and to the corrosion resistance of the cermet matrix.
Proceedings Papers
ITSC1997, Thermal Spray 1997: Proceedings from the United Thermal Spray Conference, 107-112, September 15–18, 1997,
Abstract
View Papertitled, Slurry Erosion of Arc-Sprayed Metal and Composite Coatings
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for content titled, Slurry Erosion of Arc-Sprayed Metal and Composite Coatings
Two grades of stainless steel, 316 and 440-C, in the form of solid wire, and two cored wires, Duocor and 95-MXC, were used. Coatings were made using the Miller BP-400 and TAFA 9000 systems. Slurry jet erosion tests were conducted using a 10 %w/w alumina particle/water slurry. Two alumina particle sizes, 320 and 80 grit (nominal grain diameters 35 μm and 200 μm, respectively) were used at impinging angles of 90° and 20°. The nominal impact velocity of the slurry was 15 m/s and the nozzle-specimen distance 100 mm. The volume loss of material under various slurry erosion conditions was related to the coating properties and microstructure. Results indicate that the wear behavior of arc sprayed materials is dependent on the erodent particle size; for large erodent particle size, the relative erosion is almost independent of the impinging angle, while for the smaller particle size the angle effect is the dominant factor. This behavior can be related to the lamella structure and the relative toughness of the different phases of the coatings.