Hardfacing alloys are commonly used for wear- and galling-resistant surfaces for mechanical parts under high loads, such as valve seats. Cobalt-based Stellite, as well as, stainless-steel-based Norem02 and Tristelle 5183 alloys show similar microstructural features that correlate with good galling resistance. These microstructures contain hard carbides surrounded by a metastable austenite (fcc) phase that transform displacively to martensite (hcp or bcc or bct) under deformation. As a result, the transformed wear surface forms a hard layer that resists transition to a galling wear mechanism. However, at elevated temperature (350°C), the stainless steel hardfacing alloys do not show acceptable galling behavior, unlike Stellite. This effect is consistent with the loss of fcc to bcc/bct phase transformation and the increase in depth of the heavily deformed surface layer. Retention of high hardness and low depth of plastic strain in the surface tribolayer is critical for retaining galling resistance at high temperature.

Ultrasupercritical (USC) steam boiler and heat recovery steam generator (HRSG) technology is constantly evolving to improve efficiency and reduce emissions. Currently, temperatures are pushing beyond the capabilities of even the most advanced ferritic steels with some applications requiring nickel-based superalloys. Cost-effective design of these systems requires the application of a variety of alloys representing a range of cost/property trade-offs. CF8C-Plus is a cast austenitic stainless steel recently developed for application in high temperatures similar to those in power plants (600 - 900 °C) with creep strength comparable to several superalloys. This makes it an attractive alternative for those expensive alloys. EPRI, with assistance from PCC subsidiaries Special Metals and Wyman Gordon Pipes and Fittings, has produced and characterized two pipe extrusions nominally 5.25 inch OD x 0.5 inch wall thickness and 6 inch OD x 0.75 inch wall (13.3 x 1.3 cm and 15.2 x 1.9 cm), each about 1000 lbs, to continue to assess the feasibility of using a wrought version of the alloy in power piping and tubing applications. The mechanical properties from these extrusions show performance in the same population as earlier forging trials demonstrating capability exceeding several austenitic stainless steels common to the industry. Creep-rupture performance in these extrusions continues to be competitive with nickel-based superalloys.

For four decades, the Electric Power Research Institute (EPRI) has led groundbreaking materials research in the power industry, yielding significant cost savings across fossil, nuclear, and power delivery sectors. This paper outlines EPRI's fossil-related research, conducted through three major programs: Fossil Materials&Repair (P87 Base program), Materials-Fossil&Nuclear strategic program, and a supplemental program addressing key industry initiatives. EPRI's research focuses on understanding damage mechanisms, developing improved materials, enhancing life prediction methodologies, and advancing component degradation assessment. The paper highlights the synergy between EPRI's short- and long-term research initiatives, referencing several presentations from the 6th International Conference on Advances in Materials Technology for Fossil Power Plants. By showcasing EPRI's comprehensive approach to materials research, this overview demonstrates the institute's ongoing commitment to advancing power generation technology and efficiency.

The manufacture of large, complex components for ultra-supercritical and oxy-combustion applications will be extremely costly for industry over the next few decades as many of these components will be manufactured from expensive, high strength, nickel-based alloys casting and forgings. The current feasibility study investigates the use of an alternative manufacturing method, powder metallurgy and hot isostatic processing (PM/HIP), to produce high quality, and potentially less expensive components for power generation applications. Benefits of the process include manufacture of components to near-net shapes, precise chemistry control, a homogeneous microstructure, increased material utilization, good weldability, and improved inspectability.

A research program has been initiated to develop the first predictive methodology for corrosion fatigue life in steam turbine blades, addressing a critical gap in current understanding despite extensive research into corrosion pitting and fatigue failure. The study focuses initially on dual-certified 403/410 12% Cr stainless steel, utilizing a newly developed test facility capable of conducting high-cycle fatigue tests in simulated steam environments at 90°C with controlled corrosive conditions. This testing platform enables the investigation of various steady and cyclic stress conditions, establishing a foundation for future testing of other blade steels and the development of comprehensive blade life estimation techniques.

Grade 92 steel, a creep strength-enhanced ferritic (CSEF) steel, is used in supercritical steam fossil power plants for boilers and piping systems. While its creep strength is crucial, understanding the interaction between creep and fatigue damage is also vital for assessing component integrity under cyclic loading. Despite existing studies on its creep-fatigue behavior, additional data under creep-dominant conditions relevant to plant evaluations are needed. Girth welds, critical to piping system integrity, are particularly important in this context. EPRI and CRIEPI initiated a project to develop a comprehensive database on the creep-fatigue behavior of Grade 92 steel's base metal and welded joints and to establish a suitable life estimation procedure. Key findings include: (i) a thick pipe with submerged arc welding (SAW) was manufactured for testing; (ii) base metal and cross-weld specimens showed similar behavior under short-term creep and cyclic loading; (iii) these specimens had lower creep strengths than average literature values for this steel class in the short time regime, with differences decreasing as stress decreased; and (iv) the fatigue and creep-fatigue behavior of these specimens were similar to those of Grade 91 and 122 steels, with common characteristics in creep-fatigue failure prediction models across the three CSEF steels.

Advanced Ultra-supercritical (A-USC) steam power-plant technology is being developed for better efficiency and lower emissions at 700°C and above, but is based mainly on Ni-based alloys. The ability to include lower-cost alloys with appropriate high-temperature performance should have substantial technological and economic benefits. CF8C-Plus is a cast austenitic stainless steel recently developed for other applications at 600-900°C, which has creep-strength comparable to many solid-solution Ni-based alloys. EPRI and Carpenter Technology produced a 400 lb heat of CF8C-Plus steel and hot-forged it at 5:1 and 12:1 reductions, to assess feasibility of the alloy as a wrought advanced stainless steel for potential use as steam headers and piping for A-USC power plant applications. The hot-forged alloy has a recrystallized grain structure 6-9 times finer than the as-cast dendritic structure, resulting in better strength and impact resistance at room-temperature, and about 20% higher yield-strength (YS) at 760°C, and similar or better ductility compared to the as-cast material. The initial creep-rupture testing at 700-800°C for up to 2000h also indicates similar or better rupture resistance and better creep-ductility for wrought compared to cast material. The next steps needed to test performance of the wrought austenitic stainless steel for extruded headers and piping are discussed.

In the late 1980s, the domestic utility industry experienced failures in dissimilar metal welds (DMWs) between low-alloy ferritic tubing and austenitic tubing in superheaters and reheaters. Extensive research by EPRI found that nickel-based filler metals provided significant service life improvements over 309 stainless steel filler metals. Improved joint geometries and additional weld metal reinforcement were determined to extend service life further. A new nickel-based filler metal was also developed, exhibiting thermal expansion properties similar to the low-alloy base metal and a low chromium content that would result in a smaller carbon-depleted zone than currently available fillers. However, this new filler metal was never commercialized due to a tendency for microfissuring, resulting in less than desired service life. This paper discusses further investigation into the filler metal microfissuring issue and examines long-term testing to determine the filler's suitability for high-temperature applications.