In this work, tunnel plasma spraying is used to produce Cu 36 Zr 48 Al 8 Ag 8 metallic glass coatings on stainless steel. The results show that cooling gas flow rates play a vital role in oxidation and the formation of intermetallic phases in coating microstructures. Phase formation and microstructural features were evaluated by XRD and SEM-EDX analysis. Coating properties including hardness, sliding wear, and corrosion resistance were measured and the results are compared with the presence of secondary phases. It is shown that an increase in secondary phases improves sliding wear resistance but reduces resistance to corrosion.