The blast erosion-resistance properties of HVOF thermal spray Cr 3 C 2 type coating system and aluminized material were examined to improve erosion-resistance of turbine housings of compressors used in turbochargers for marine diesel engines. As a result, the erosion life of aluminized material is as same as that of the substrate, on the other hand the erosion life of thermal sprayed coating is ten times of that of the substrate. Therefore, erosion life of turbine housing can be extended by the surface treatment procedure. This technology is applicable to actual products.

The degradation mechanisms of machine parts are well-known facts, usually resulting in replacement of components. However, in some cases, for instance, parts for large ship engines, repair will often seem more attractive. Time-wise, the vessel’s down-time will be reduced and the investment will be lower. This paper describes repair work performed on valve stems from a 52-year-old ship engine. Due to this long time in operation, the stems were damaged by wear and were no longer functional. The requirements for the stems were scarcely documented stating only a few specific requirements; therefore a short study of the possibilities concerning rebuild material and application method was initiated. This paper illuminates the manufacturing process used; twin wire arc spraying with Monel as the rebuild material. Monel is chosen to meet the requirements for hardness and the subsequent high precision machining. In addition, the mechanical and metallurgical properties of the rebuild coating are examined in regard to adhesion, microstructure and hardness to interpret and support the functionality.

Due to its low processing temperature, cold-sprayed coatings tend to exhibit many advantages over traditional thermal sprayed coatings, such as, lower porosity, oxidation and residual stress levels. These characteristics impart the improved anti-corrosion performance of the cold-sprayed coatings. However, it is not known how much these factors influence the corrosion performance of them. In addition, there are few results on the electrochemical behavior difference between cold and thermally sprayed coatings. In this article, as-deposited cold-sprayed copper, aluminum bulk material, arc-sprayed copper and pure copper are tested with electrochemical methods to compare their electrochemical behaviors in natural seawater. The electrochemical methods included the potential-dynamic polarization curve and electrochemical impedance spectrum. The results indicated that there is no significant difference in the corrosion potential between cold-sprayed and bulk copper materials. The potential of cold-sprayed copper is much different from that of the arc-sprayed one. Polarization curves indicated that the corrosion rate is significantly higher for arc-sprayed copper. The electrochemical impedance spectrum shows that there is no difference in electrode interface structure between cold-sprayed and bulk copper materials. Based on these results it is inferred that the higher corrosion rate for arc-sprayed copper was caused by its high porosity level and oxidation degree.

The present study compares needed prerequisites for the application of cavitation resistant bronzes by applying different coating techniques, such as cold spraying, HVOF spraying, warm spraying and arc spraying. By optimization to optimum cavitation resistance, the deposited coatings can increase the service life of ship rudders significantly and even serve as repair processes for ship propellers. The given overview aims to support the selection of processes when specifying the target properties to be set with regard to cavitation protection. By using high-pressure warm spraying and cold spraying, properties similar to those of cast nickel aluminum bronze were achieved, however at relatively high costs. In contrast, coatings produced by using HVOF and arc spraying have erosion rates that are only about four respectively three times higher as compared to cast nickel aluminum bronze, while far outperforming bulk shipbuilding steel. Hence, their properties should be sufficient for acceptable service life or docking intervals for ship rudder applications. Propeller repair might demand for better coating properties as obtained by cold spraying. With respect to costs, HVOF and arc spraying in summary might represent a good compromise to reach coating properties needed in application.

The present study investigates the microstructure and properties of cold spray coatings produced from gas-atomized CuAl10Fe5Ni5 powders. To obtain information relevant to ship rudder cavitation-erosion performance, GL-A shipbuilding steel, equivalent to S235, was chosen as the substrate material. Thick Cu-Al-bronze coatings were deposited on grit-blasted plates using a wide range of parameter sets with different powder treatments, nozzle geometries, gas and substrate temperatures, and particle impact conditions. Coating samples were examined via SEM and XRD analysis, cavitation tests were performed, and bond strengths were measured. Powder and single impact morphologies were also investigated and, along with coating properties and structures, are correlated with spraying conditions. The results indicate that cold sprayed bronze coatings have good potential for ship rudder protection.

Fast streaming fluid media causes cavitation-erosion in pumps, ship-propellers and rudders. To avoid severe damage, materials with high resistance against plastic deformation and a high fatigue strength should be used. Bronzes fulfill these criteria, but as-cast bulk parts are rather costly. A promising alternative is cold-spray deposition of dense and oxide-free coatings onto exposed surfaces. To achieve high quality bronze coatings by cold-spraying, parameter optimization has to tackle the high hardness of the feedstock powder materials. Additionally, practical limits due to nozzle clogging have to be considered, which may occur at gas temperatures above 700 °C. The present study investigates possible solutions by systematic process parameter and feedstock material optimization, including variation of bronze compositions. Thus, dense coating microstructures and - in consequence - high hardness and good cavitation resistance were obtained. Cold-spray coatings reach up to 8 times better cavitation resistance as compared to conventional ship-building steel (GL-A).

This paper evaluates the cavitation erosion wear rate and failure modes of WC-10Co-4Cr coatings. These coatings are used in various industrial applications to protect against erosive, abrasive, sliding and cavitation wear in corrosive environments. Cavitation erosion tests were performed using a modified ASTM G-32 cavitation test rig. Thermally sprayed High Velocity Oxy-Fuel (HVOF) WC-Co-Cr coatings were deposited using industrially optimised coating process parameters on carbon steel and stainless-steel substrate coupons. Coatings were tested to simulate the cavitation bubbles occurring in valves, pumps, and ship propellers. Indirect cavitation was used to impact the cavitation bubbles on the test specimen at a fixed offset distance from the vibrator end. Test specimens were immersed in natural seawater. A water circulation cooling system was used to control the temperature of the water. The cumulative mass cavitation erosion and erosion rate results were evaluated. The coating microstructure was analysed using Scanning Electron Microscopy (SEM) and x-ray diffraction. Post-test evaluations included SEM observation in combination with energy dispersive x-ray analysis (EDX) to understand the failure modes. Results are discussed in terms of the factors controlling the cavitation erosion rate.

For very large structures and parts in critical environments, a materials solution often cannot be found by using one material. The specific desired properties for those structures, like stiffness, ductility, high temperature stability, corrosion resistance, etc. are difficult to fulfill with only one material. In this case a solution may be found by using coatings and design their specific properties to replenish each other by their combination. The Thermal Spraying processes offer the necessary flexibility of producing thin to thick, ductile, soft to hard coatings while due to the wide range of process temperatures it is possible to process a wide range of materials, both as coating and structure. In this paper the some recent and important developments in Thermal Spraying to produce coatings for technical demanding structures will be described. These developments consist of High Power Plasma Spraying, powder- and process control development. To ensure process consistency during long spraying times and to apply reproducible coating quality a suitable process control is of great importance and the development of temperature control by Pyrometry and Thermography will be presented. The example will be drawn according to the application of a coating on a ball valve for off-shore and ship diesel engine parts (piston and valve).

Stainless Steels are required for many applications for ship building as well as for offshore structures such as oil exploration. AISI type 304 stainless steel is not very suitable for such applications as it has a strong tendency for pitting and crevice corrosion. Even type 316 and 317 stainless steels which have respectively 2.5 and 3.5% Mo are not very effective in these environments. Commercially available stainless steels, viz., Avesta 254 SMO is being employed for such applications because of its strong resistance to pitting and crevice corrosion. This is mainly because of high Mo concentration (6.5%). Such steels are not only costly but are prone to form deleterious phases such as delta ferrite and sigma during welding or other heat treatment operations. Hence, an alternative technique to restrict Mo at the surface is needed. In the present work, surface alloys consisting of an austenitic stainless steel with Mo content as high as 10-12% have been formed on stainless steel type 304 substrates. These steels show enhanced passivity and strong resistance to pitting corrosion.

High Velocity Oxy-Fuel Thermal Spray has been used by the Navy for repairing components for several years with great success. This paper will discuss some of the applications being done, the results of these applications and where the technology will be utilized on the future. The Office of Naval Research in conjunction with Naval Research Laboratory and Naval Surface Warfare Center is investigating replacements for chrome plating. One of the technologies being looked at is HVOF Thermal Spray. This paper will discuss this program, new materials being developed and new applications being done. The superior physical characteristic of HVOF has increased the utility of this technology from mechanical components to aircraft and submarine components. Acceptance of these coatings at various levels at NAVSEA will be discussed and criteria established for these acceptances will be reviewed. The role of these coatings in ship repairs as well as the implications for new construction will be discussed. Specific examples of repairs will be shown and updated reports will be provided as to their service. Locations that have services available will be detailed and future growth of this technology within the Navy will be reviewed. A quick overview of similar emerging technologies will be provided. A highlight of the presentation will be an update of the repair done with HVOF Tungsten Carbide on the Rudder Rams on the USS Saipan.

Successful cold spray of tool steels and other hard steels would unlock several opportunities, including the repair of molds as well as ships and heavy industry components. However, the high hardness of typical atomized steel powders strongly limits their cold sprayability. It has been recently demonstrated that heat treatment in a rotating furnace can significantly improve H13 cold sprayability via softening and agglomeration. In this work, this powder modification method is extended to a range of transformation hardenable steels: 4340, SS420, A588, 1040 and P20. The results show that powder heat treatment improves the powder deposition efficiency and the quality of the final cold sprayed coating, probably as the result of the decreased powder micro-hardness. The effects of the powder heat treatment atmosphere, a key parameter, will also be presented and discussed.

To evaluate the corrosion resistance of various coatings applied by the flame spraying method, and to compare their protective properties in sweet- and sea-water samples with seven types of coatings were made, one of them is paint, used to coat ship’s bottom. SEM, Neutral spray salt, according to ASTM B117, erosion-corrosion (E-C) tests in sweet- and sea-water were carried out. The test results showed that coatings based on zinc alloys and polymer are much more effective than standard epoxy coatings and can be compared with expensive zinc-filled paints, because the latter require frequent repairs and repainting. Moreover, the developed coatings are supposed to protect against fouling. At the moment, the fouling tests are continuing.

Cavitation erosion frequently occurs in hydraulic components such as turbines, valves, pumps, and ship propellers. Arc thermal spray processing has the possibility to be used for maintenance recovering of hydraulic blade runners. Fe-Cr-Mn-Si is a cavitation-resistant class of steel with a high concentration of oxidation elements—which can be important for arc thermally sprayed coatings—and a strain-induced phase transformation. The influence of chemical composition on oxide formation, microstructure, and cavitation resistance of Fe- Mn-Cr-Si thermally sprayed coatings was studied, and its field performance in a Francis type runner was evaluated. Microstructures and properties were investigated by XPS, XRD, optical microscopy, and ultrasonic cavitation testing. The best cavitation resistance was obtained in Fe-Mn-Cr-Si alloy with a nickel addition; this composition has lower oxide and splash droplets content and exhibits better splat wetting than Fe-Mn-Cr-Si without nickel. Strain-induced phase transformation occurred in arc thermally sprayed coatings during cavitation tests. Better performances for Fe-Mn-Cr-Si alloys, without nickel, were obtained in alloys with higher strain induced martensite contents after cavitation tests. In field tests, after 2000 operation hours, it was verified that the recovered areas presented only a small number of eroded areas, and cavitation erosion was reduced compared with uncoated areas.

Bronze materials such as Ni-Al-bronze show exceptional performance against corrosion, erosive wear, and cavitation erosion due to their high fatigue strength and resistance to plastic deformation, and are thus used for ship propellers and in turbines, pumps, and other equipment where alternating stresses occur. Usually, the respective parts are cast, but in this study, a number of opportunities are evaluated to apply bronze as a coating to critical part surfaces. Initial experiments with cold gas spraying were promising enough to assess the use of warm spraying, a nitrogen-cooled HVOF process that provides similar particle impact velocities but higher particle temperatures, while still minimizing the effects of oxidation. The formation and performance of warm sprayed Ni-Al-bronze coatings was systematically investigated for different combustion pressures and nitrogen flow rates. Substrate preheating was also used to improve coating adhesion. The coatings obtained show low porosities, high strengths, and in some cases, cavitation resistance similar to that of the bulk material.

Since its inception, the Office of Naval Research (ONR) program entitled, “Thermal Spray Processing of Nanostructured Coatings”, has produced numerous successes relating to military and industrial applications. Commercially available thermal spray processes have been used to apply ceramic coatings from nanostructured powders, producing dramatically improved wear performance over coatings from conventional non-nanostructured powder. The nanostructured alumina-titania coating has been instrumental in extending the life of a critical Navy need, the protection of the main propulsion shaft of mine countermeasures ships. The advancement in nanostructured oxide coatings has led to the development of the first industrial application of a thermal sprayed nanostructured coating. A nanostructured titanium oxide coating has been developed and successfully incorporated into severe-service ball valves used in hydrometallurgical extraction of gold, nickel, and cobalt. This paper will also present promising results from current development work relating to nanostructured coatings for thermal barrier, biomaterial, and reconditioning applications.

Naval ship components are subject to extreme operating conditions while at sea, either during regular sailing periods and/or during training exercises. The Chilean Navy has employed thermal spray technology since the early 1960 decade. By setting up a joint cooperative program between the Chilean Navy industry and suppliers, it has been possible to start regaining confidence in thermal spraying and positioning the same as a "must" technology in regular naval maintenance work. This article presents a description of the Naval Components Reclamation Program and discusses the processes involved in hard chrome plating replacement in naval components. It provides a review of characteristic thermal spray applications developed by the Joint Naval Components Reclamation Program.

The US Navy has adopted High-Pressure Cold Spray (HPCS) as a repair technique for corroded and worn components in their fleet of aircrafts, ships, and submarines. HPCS repairs are not only used for depositing corrosion and wear resistant coatings but is being successfully used for dimensional restoration in metal parts and components. By utilizing HPCS, the Navy ensures the longevity and reliability of critical components, even in harsh environments. Whether safeguarding against corrosion or restoring worn parts, HPCS is playing an increasingly critical role in maintaining operational readiness for the US Navy and other DOD agencies, as well as the commercial industry.

This paper discusses the principles of high velocity arc spraying (HVAS) and its use in surface engineering. It also reviews applications in marine environments and power plant boiler pipes, where HVAS coatings provide corrosion protection.

This paper provides an update on the state of cold spray corrosion mitigation and repair as it applies to equipment operated by the U.S. Navy. It also presents several application scenarios in which cold-sprayed Al 6061 and NiCr-CrC can improve preventative maintenance and dimensional restoration procedures currently used on A36 steel and CuNi structures.

In this investigation, aluminum-copper, aluminum-zinc, and zinc coatings were flame sprayed onto a sand-blasted mild steel substrate. The coatings were immersed in seawater and were examined on a monthly basis using EDS and XRD analysis to assess corrosion and marine fouling behaviors. The spraying and test procedures are described and the results are presented and discussed. Zinc and aluminum-zinc coatings with high zinc content proved to have good anti-corrosion and anti-fouling properties, but the aluminum-copper coatings did not.