Search Results for particle adhesion

Numerical studies directly quantifying particle-substrate adhesion under different spray process parameters during impact remain scarce, primarily due to the lack of consideration for adhesion models. This study addresses this gap by investigating bonding behavior under varying spray conditions using a single-particle model with the PD numerical method, incorporating adhesion forces.

Cold gas dynamic spraying, namely cold spray, is an innovative coating process in which powder particles are injected in a supersonic gas flow to be accelerated above a certain critical velocity. Even though particles adhesion onto the substrate has not be yet elucidated, it appears clearly that it is influenced by particle impact velocity, which results from spraying conditions, diameter of particles and their positions from the center of the particle jet. Particle velocity can change dramatically depending on particle position from the core to the rim of the jet. In the present work, an original experimental set-up was designed to discriminate the particles as a function of the levels of velocity to investigate the influence of this parameter on adhesion. Particles at given positions in the jet could therefore be observed using SEM (Scanning Electron Microscopy), which showed different morphologies and microstructures as a function of impact velocity. High pressure and tangential velocity at the interface during impact were calculated from numerical simulations using ABAQUS. TEM (Transmission Electron Microscopy) analyses of thin foils were carried out to investigate into resulting local interface phenomena. These were correlated to particle impact velocity and corresponding adhesion strength which was obtained from LASAT testing (LAser Shock Adhesion Test).

In wire arc spraying, atomizing gas velocity and particle velocity are important factors influencing coating quality. A nozzle with secondary gas injection has been developed to increase the gas velocity and to improve coating quality. In this study, wire arc spraying of stainless steel on aluminum substrates has been investigated with the objective of establishing correlations between atomizing gas velocities, particle velocities, particle sizes and coating bond strength. Cold gas velocity is measured with a Pitot tube. Particle velocities are determined from high speed images of particle streaks taken with a Kodak high speed vision system and evaluated using image analysis. Bond strength is measured with pull-off tensile test. Secondary gas atomization clearly leads to improved adhesion due to additional metallurgical bonding between the coating and the substrate achieved through higher particle temperatures at the moment of impact.

The adhesion mechanism of deposits/substrate interface prepared by cold spray method has not been fully understood up to now. It seems that the adhesion strength is mainly determined by the mechanical (including the plastic deformation of particle and substrate) and thermal interaction between the particle and substrate when the particles impact onto the substrate with a high velocity. In order to understand the adhesion mechanism, the influences of particle impact velocity on the adhesion strength were investigated in this study. The particle velocity was obtained with DPV-2000 measurement and CFD simulation. The relationships between the adhesion strength of deposits/substrate interface and particle velocity were discussed. The results show that greater adhesion strength can be obtained with the increase of particle velocity. There are two available ways to improve the adhesion strength. One is to increase the temperature of working gas, and another is to employ helium gas as the working gas instead of nitrogen gas.

NiCrBSi and Ni-50Cr coatings are deposited using High Velocity Oxygen-Fuel (HVOF) spray process under different spray parameters with two powders of different sizes to clarify the influence of melting state of spray particles on the adhesive strength of the coating. The adhesive strength of coating is estimated according to ASTM C633-79. The melting state of spray droplet is examined from the coating microstructure. It is found that the melting state of spray particles has significant effect on the adhesive strength of HVOF sprayed Ni-based coatings. The significant melting of spray particle does not contribute to the increase in the adhesion of HVOF metallic coatings. On the other hand, the deposition of partially melted large particle contributes to the substantial improvement of adhesive strength of HVOF coating. The subsequent coating presents a dense microstructure and yields an adhesive strength of over 76 MPa, which is doubled compared to the coating deposited with completely molten particles.

This paper presents some results of modelling of the adhesive interaction of solid particles with the substrate at collision parameters characteristic for the Cold Spray process. A simple physical model based on comparison of adhesion energy and energy of elastic deformation generated under the particle impact is suggested. Empirical expressions for energies of adhesion and elastic deformation are obtained. It is shown that there is an optimal range of particle size and velocity providing high deposition efficiency for a given particle material. The results of the modeling are in good qualitative agreement with experimental data.

Cold-spraying has been developed as a high-quality metallic coating process. Recently, it became possible to fabricate a brittle ceramic coating using a particular nano-structured powder. In order to improve and control the process, the bonding mechanism should be understood. In this study, the bonding mechanism between cold-sprayed TiO 2 particle and stainless steel substrate was investigated by cross-section observation and quantitative adhesion strength measurement for the individual particles. The adhesion strength was measured by the combination using of scanning probe microscope (SPM) imaging and nano scratch test. The result clearly revealed a correlation in adhesion strength with splat diameter. The smaller splat diameter exhibited higher adhesion strength, though it is generally difficult to penetrate the cold-sprayed small particles through a shock wave formed in front of the substrate. The cross-section microstructure of the splats prepared by focused ion beam (FIB) showed the particular deposition behavior of the TiO 2 particle. The collided particle didn’t deform the substrate surface and deformed the particle itself. The bottom center of the splat is densified by the deformation and the other parts maintain the porous structure or broke up. Hence the higher adhesion strength of smaller splat was caused by this typical TiO 2 deposition behavior.

This study deals with the influence of spray angle on the deposition of cold-sprayed Al particles. Spray trails were conducted in parallel with finite element simulations of particle deformation and coating build-up as a function of spray angle, powder size, substrate roughness, and surface configuration. Coating cross-sections and splats were examined by SEM; bonding strength and particle adhesion were determined via laser shock adhesion testing. Experimental as well as modeling results show that splats deposited at spray angles less than 60° are highly deformed and poorly adhered. Based on the findings, several conclusions are drawn with regard to the potential use of cold spraying for the repair of aircraft components.

This study assesses the feasibility of cold spraying metal onto wood for commercial applications. It was found that particle adhesion and coating build-up differ significantly from the standard case of spraying metal on metal. Phenomena such as fiber rupture and buckling, pore filling, and particle anchoring required a new approach for process development and verification. First, a microscale analysis of the unique features of wood was necessary to define the deposition surface. Next, a wide range of cold spray tests were conducted to obtain metal coatings on four species of wood. To better understand the dependency of deposition efficiency on particle state conditions, a CFD models and FEA simulations were used to investigate single and multi-particle impacts on local wood structures as observed in SEM and microtomography images. A conventional pull-off test was used to collect adhesion strength data and a numerical counterpart of the test has been developed, making it possible to compare macroscopic adhesion behavior of real and virtual interfaces.

In the Cold Spray process, the sprayed particles are in solid state, and unlike thermal spray, the effect of the coating erosion by reflected particles can play a more significant role. This paper is an attempt of modeling the process of the Cold Spray coating formation taking into account the influence of the erosion process. The objective was to study the kinetics of the coating formation. Using an analytical approach, equations of the coating formation process are obtained. The approach is based on a comparison of the effect of particle adhesion to the coating combined with the effect of coating erosion. Adhesion and erosion are taken into account by introducing some probability values of these processes.

High quality coatings of titanium can be obtained by cold spraying using high process gas temperatures and pressures. However, the performance of cold sprayed coatings is determined not only by the respective material properties and the impact conditions, but also by the temperature and properties of the substrate—including the already deposited— material. In the present study, cold spray of spherical titanium grade II powders was performed on titanium grade II, copper, and stainless steel substrates, using two sets of parameters and three different substrate temperatures. Single impacts and respective particle adhesion were investigated using wipe tests followed by a modified cavitation test. Higher bond strengths were achieved for substrates that were held at higher temperatures during spraying. Moreover, the electrical conductivity of coating, taken as a measure of particle-particle bonding quality within the coating, improved and the porosity decreased for increased substrate temperatures. The findings are discussed in view of the thermal conditions, as well as the mechanical response of the uppermost layer of the substrate/deposit set.

A model that takes into account the influence of surface activation by particles of the sprayed material on Cold Spray process is proposed in the present paper. With the help of this model, particle adhesion to the surface is numerically calculated. Some typical dependences of the coated area on the number of impacts for different particle velocities and temperatures are obtained. These dependences are in satisfactory agreement with the results of experiments.

Low pressure cold spraying is an attractive technique for onsite metal coating fabrication due to its compactness and portability. However, the bonding strength of the coating prepared by low pressure cold spraying is generally low, which restricts the further applications in engineering and industrial fields. To improve the bonding strength, pre-treatment on substrate surface can be an effective procedure. In this study, a low-temperature plasma treatment was applied to a pretreatment technique, and the effect of the treatment on particle bonding was compared with that of a laser treatment. Copper coatings on aluminum and copper substrates were selected and studied as basic metal materials. The SEM observation results show that the particle adhesion rate significantly increases by the laser and plasma treatments, due to the removal of the native oxide films on the substrates. The particle bonding on the plasma-treated substrate reveals better interfacial adhesion with less gap compared with the laser-treated one. The pre-treatment by low-temperature plasma can be an attractive technique to assist the cold spraying process due to the oxide removal ability and no thermal effect which can apply a wide range of materials.

To answer current issues adequately considering technical, economic, as well as environmental requirements, material transformation and especially surface treatment industries must be source of innovations to be proactive. As a result, developing new alternative solutions to existing ones had become a top priority. Considering surface treatment processes, conventional ones (thermal spraying, plasma transferred arc) do not allow to consider this approach since the processes themselves (co-treatment of different powders) do not permit to guarantee the initial composition nor do they ensure a sufficient homogeneity to the coating structure. If indeed the dry surface treatment processes have already shown large potential, several limits remain such as an inefficient adhesion, an environmental impact over the life cycle or almost no materials on the market. To overcome these issues hybrid coating technologies (combining several processes) are likely to be developed. From all of them, laser technology seems to be very promising due to its high flexibility considering all the potential parameters (varying power, continuous or pulsed beam, etc.) and the localised treated area. For instance, combining simultaneously a laser with a thermal spray process enables the elaboration of a thick coating showing a good adherence. The ablation laser applied on the substrate surface just before the impacting particles as promoted in the PROTAL process permit to insure a suitable surface state favourable to the particles adhesion. The control of the coating microstructure was not so much studied. That is why, to complete the knowledge in this area, this work aims at studying the influence of laser technology in association with plasma spraying on the coating microstructure and more precisely on the coating mechanical properties. Coatings were characterized by SEM and void content was evaluated through image analysis and Archimedean porosimetry. Mechanical properties were assessed by the four points bending test for evaluating the coating apparent Young modulus.

This study investigates a new evaluation method that has the potential to differentiate between particle interfaces and grain boundaries in cold spray coatings. The method uses confidence index (CI) and image quality (IQ) values obtained from EBSD analysis to determine the location of grain boundaries as well as grain orientation and crystallinity of the deposit. In the case of a cold-sprayed copper deposit, the new method helps to explain the observed characteristics of the coating.

This study investigates the feasibility of forming amorphous iron-based coatings using the cold spray deposition process. Splat tests of cold-sprayed SAM1651 (Fe48Mo14Cr15Y2C15B6 at.%) particles impacting a mild steel substrate were performed using varying gas temperatures and particle diameters. Specimen inspection by scanning electron microscopy revealed splat morphologies that varied from well-adhered particles to substrate craters formed by rebounded particles. Particle flow was analyzed using a finite element model, and impact conditions were predicted using an experimentally validated analytical model, in empirically generating a temperature/velocity window of successful particle deposition as a framework for ongoing work on the formation of cold-sprayed SAM1651 coatings. The results indicate that the unique characteristics of the cold spray process offer a promising means for the formation of metallic glass coatings that successfully retain the amorphous structure, as well as the superior corrosion and wear resistant properties of the feedstock powder.

Cold spray process was chosen as a good candidate for dimensional restoration and protection of components. Commercially pure aluminum, aluminum-alloy or titanium were recommended for different applications. This paper investigates laser surface texturing association to enhance durability of sprayed coatings. Laser is easy automated, localized and reliable process. It was applied for prior-surface treatment. Textured surfaces were produced and compared to conventional treatments, such as grit-blasting, in terms of deposition efficiency and adhesion bond strength. Patterns promoted direct particle embedment. Particle-substrate interface exhibited significant temperature rate and strain in cavities. Intimate contacts and particle compressive states were assumed responsible for improvement. The particle deformation and bonding behaviors were evaluated and discussed for the different configurations. Thus, window of deposition was increased with laser surface texturing. Anchoring mechanisms increased two fold the adhesion strength compared to conventional pre-treatments. In one case, the interface was stronger than the coating cohesive strength.

This study investigates the deposition behavior of cold sprayed copper particles on flat surfaces. In the experiments, a Laval-barrel nozzle was used to spray water atomized spherical copper particles with a mean diameter of 5 µm onto mirror-polished stainless steel. The particles were similar in morphology regardless of spraying conditions with an average bonding strength of 60 MPa as determined by nano scratch (shear) testing. An amorphous-like layer at the particle-substrate interface indicates that the deformation of the particles initially destroys their surface oxide, revealing an active fresh surface that facilitates metallic bonding. At higher spray velocities, metal jetting is observed at the periphery of flattened particles and its relationship with deposition efficiency is statistically analyzed and put forth as a potential method for controlling the cold spray process.

Cold spraying has been developed as a high-quality coating process. However, the deposition materials were limited as metallic materials. In this paper, titanium dioxide (TiO 2 ) ceramic particles are deposited on several substrate materials and formed thick coatings, making this approach suitable for a wide range of photocatalytic applications. In order to understand the adhesion mechanism of solid ceramic particles, the structures of feedstock particles are carefully observed with a scanning electron microscope (SEM) and a high-resolution transmission electron microscope (TEM). We find a porous structure which is agglomerated with nano-scaled primary particles. It is assumed that the break down phenomenon occurs due to the cold spray process and influences the adhesion of ceramic particles. The primary particles are bonded within a single crystal. This particular structure is the main factor to make adhesion between the particle and the substrate. SEM and TEM analysis clearly reveals adhesion mechanisms related to the impact of spraying ceramic particles toward the substrate.

Yttria stabilized zirconia particles are plasma sprayed on polished stainless steel substrate. Starting powders are fused and crushed powder, and hollow spherical powder. Four types of the splat morphology, which are splash, rugged, gravel mounted, and disk splats, are observed. Splash and disk splats are fully melted particles, but rugged and gravel mounted like splats are partially melted particles Gravel mounted like splat is observed from only hollow spherical powder, and disk splat is observed in the case of high substrate temperature. It is found that the ratio of splat morphology changes with spraying parameters. Porosity of the coating from fused and crushed powder is higher and Young's modulus of that is lower than that from hollow spherical powder. The ratio of rugged and gravel mounted splats affect porosity and Young's modulus. Adhesive strength increases with the increase in the ratio of disk splat. So, the coating properties are improved by controlling splat morphology. KEYWORDS: Splat Morphology, Partially Melted Particle, Disk Splat, Porosity, Young's Modulus, Adhesive Strength