In this study, hydroxyapatite, titania, and HA-TiO 2 composite layers are deposited by suspension plasma spraying on titanium substrates and assessed by means of SEM and XRD analysis, Raman spectroscopy, and acoustic emission testing. The coatings exhibited dense microstructures with low porosity and good interfacial bond strength. The main phase in the HA and composite coatings was found to be similar to the peak of the feedstock powder. In the composite and titania coatings, besides rutile and anatase, a significant percentage of thermally stable Ti 3 O 5 was observed, which is favorable for photocatalytic performance.

In order to guarantee their protective function, thermal sprayings must be free from cracks, which expose the substrate surface to e.g. corrosive media. Cracks in thermal sprayings are usually formed because of tensile residual stresses. Most commonly, the crack occurrence is determined after the thermal spraying process by examination of metallographic cross-sections of the coating. Recent efforts focus on in situ monitoring of crack formation by means of acoustic emission analysis. However, the acoustic signals related to crack propagation can be absorbed by the noise of the thermal spraying process. In this work, a high-frequency impulse measurement technique was applied to separate different acoustic sources by visualizing the characteristic signal of crack formation via quasi-real-time Fourier analysis. The investigations were carried out on a twin wire arc spraying process, utilizing FeCrBSi as a coating material. The impact of the process parameters on the acoustic emission spectrum was studied. Acoustic emission analysis enables to obtain global and integral information on the formed cracks. The coating morphology as well as coating defects were inspected using light microscopy on metallographic cross-sections. Additionally, the resulting crack patterns were imaged in 3D by means of X-ray micro-tomography.

In this study, acoustic emission sensing is used to monitor interfacial cracking in thermal barrier coatings during uniaxial tensile adhesion testing. The TBCs consist of a ZrO 2 topcoat and a NiCrAl bond coat, both of which are applied by atmospheric plasma spraying. Tensile testing was performed to failure and the resulting fracture surfaces were examined by SEM and XRD analysis. Experimental results show that cracks usually initiate in the ceramic layer then propagate toward the metallic-ceramic interface where failure occurs. Finite element simulations were also conducted, confirming the experimental findings.

This study demonstrates an experimental setup in which acoustic emission sensing is used to monitor a twin wire arc spraying (TWAS) process. Emitted acoustic signals were recorded by broadband sensors attached to the spray nozzle and mounted under the substrate. Sensor outputs were converted from the time domain to the frequency domain by fast Fourier analysis. Acoustic emission amplitude plots were produced and are correlated with gas pressure, arc voltage, in-flight particle velocity and temperature, coating thickness, and crack formation due to cooling.

One of the greatest obstacles for a wide distribution of thermal spraying techniques is the lack of online control over the spraying process. The thermally sprayed coatings are optimized by an empirical modification of the spraying parameters and the subsequent correlation of these parameters to the obtained coatings. Some intrinsic parameters, such as the fluctuations in twin wire arc spraying and wear in the atomization nozzle, are not adjustable. Even though they have an enormous impact on the obtained coating quality, they are often scientifically neglected for reasons of simplification. In this work, acoustic emission analysis is utilized to study the effect of uncontrollable parameters on acoustic signals. In order to enable an easy determination of the changes in the acoustic signals, the acoustic sensors were mounted on the spraying nozzle as well as on the substrate. At increased current, a lower acoustic emission is recorded. A correlation between uncontrollable parameters, the acoustic signals, and the obtained coating quality was observed. This research contributes to the online control of the spraying process.

Near net shape coating is a trend in thermal spraying being aimed at for several years to lower costs through shortened spray time and reduced after treatment work. Because of better microstructure compared to conventional coatings, the thickness is often also reduced. To characterise the quality of those thin layer systems the standardized tensile adhesive test is not suitable, as the adhesion outweighs the cohesion by far due to reduced quantities of coating defects. To characterize the coatings behaviour under tensile stress, three-point bending tests were performed. As especially thin cermet coatings do not show abrupt catastrophic failure in bending tests, ultrasonic signals being emitted from cracks propagating through the coatings were taken during the tests. Three coating systems (Cr 2 O 3 , Cr 3 C 2 -NiCr and WCCoCr) were investigated in this work using fine grained feedstock powders with three different size distributions per system. The tests showed the negative influence of stress moments in case of the oxide ceramic and the embrittlement of the cermets, especially the Cr 3 C 2 -NiCr, with increasing spraying temperature regime due to increased formation of solid solutions and decarburization. It can be said, that the analysis of acoustic emission during bending tests gives valuable information about how to achieve thin wear and corrosive protecting coatings being qualified for high operational demands.

One major shortcoming of thermal barrier coatings applied to gas turbine components is the spallation of the ceramic coating under mechanical stress developing during thermal cycling environments. In order to study the evolution of failure and the expectancy of lifetime under realistic conditions cycling burner rig tests are a well established matter of choice. In the same way the techniques of acoustic emission (AE) testing and infrared (IR) thermography have been widely proofed to provide insight to microscopic crack formation and localization of hidden delaminations, respectively. Both techniques can be utilized to record the evolution of microscopic and macroscopic defects in advance to the apparent failure. Indirectly, this knowledge allows to verify and to improve lifetime models. The aim of this study is to expand the use of AE and IR testing as a rugged in-situ monitoring tools for combustion driven cycling rigs and to provide spatial resolved information on thermal load and failure evolution of the TBC in those tests. For a successful application to an experiment using a gas fired and air cooled burner rig some it is necessary to overcome some limitations which are mainly due to the high level of interfering signals under those experimental conditions.

The acoustic emission (AE) technique, when used with the four-point bend test, is potentially an effective method for characterization of the ductility and fracture behaviour of certain thermally sprayed coatings. Monitoring of AE during such tests on brittle coatings reveals that the rate of the occurrence of events with increasing load changes gradually over the duration of the test. In this work, finite element modelling (FEM) of a brittle coating on an elastic substrate in four-point bending is used to analyze the fracture behaviour of the coating and predict its AE behaviour. The results from the FE analysis show good agreement with experimental data from four-point bending of thermally sprayed WC-Co coatings.

This research examined the use of 4-point bend testing, with in-situ acoustic emission analysis, for the characterization of the deformation of WC-Co coatings sprayed by the high-velocity oxy-fuel method. Coatings were deposited from WC- 17wt.%Co powders using a Praxair JP5000 system. Two sets of gun operating parameters were employed to produce coatings with distinctly different structures. In the present studies the cracking behaviour of the coatings was investigated through analysis of the acoustic emission (AE) data. In particular, AE data recorded has shown clear differences between the two coating types, in terms of the critical strain level and amount of energy released during cracking. The critical strain levels for the different coatings were 0.32% and 0.6% respectively. Analysis of the coatings by scanning electron microscopy and X-ray diffraction has allowed correlations to be made between the principle microstructural features of the coatings and the mechanical behaviour under bending. The AE responses for these cermet coatings were highly reproducible.

Four-point bend test using acoustic emission (AE) was used to compare coating properties under mechanical solicitation, mainly the toughness and the spalling behaviour. Coatings are made from the same material; the 2005NS (WC-17Co), sprayed with an HVOF gun at various spray parameters. Coatings deposited on thin rectangular substrates were tested with the coating bent in tension and in compression. AE features like the event number, energy per event and cumulative energy were used to assess the damage in the coatings. The results are analyzed in relation with the coating microstructure.

Thermal barrier coatings are mainly used to protect underlying alloys from heat and chemical aggressions, especially in jet turbines and diesel engines. The challenge in TBCs’ applications is to use them to protect the upper moving turbine’s blades where their surface temperature can reach 1200°C. The limiting effect is the reliability of these coatings. The work described in this paper is a continuation of our earlier research work, which is focused on the use of Acoustic Emission Technique to assess the long-term behavior of thermal barrier coatings under thermal cycling conditions. Emphasis is placed in this presentation on the comparison of different signal processing techniques and the evaluation of their potential usefulness for the prediction of the coating behavior and failure modes. The work is carried out in parallel with a finite element modeling study of the thermal and stress distribution in the coating, which provides a valuable insight in the coating stress distribution prior to failure.

The thermal shock resistance of thermal barrier coating depends strongly on the shear stress generated by the thermal expansion mismatch between the ceramic and bond coat layer. Applying a functionally graded structure composing of NiCoCrAlY and YSZ along the coating can mitigate this effect. The paper studied the improvement of thermal shock properties with different number of intermediate layers (2 - 4) added over the temperature cooling range 900 - 30 °C. Acoustic emission (AE) technique was utilised to determine the moment of occurrence of damage within the coatings, and thus help to identify the corresponding failure mechanisms. Cross section analysis of the coatings after thermal shock tests revealed that the coatings generally failed by two mechanisms: edge delamination and segmentation of zirconia topcoat. Failures in the coatings with 2 and 3 intermediate layers (total of 3 and 4 layers respectively in the overall coating) were dominated by edge delamination while the coating with 4 intermediate layers exhibited only segmentation of the top zirconia layer. This points to the fact that interfacial stresses were not critically affecting the integrity of the 5-layer coating (4 intermediate layers plus the ceramic top layer). The cumulative and rate energy results showed that the energy released by the coatings during the thermal shock tests were in the order of 3-layer coating > 4-layer coating > 5-layer coating. The 5-layer coating had demonstrated the best thermal shock resistance among the four coatings.

A thermal cycling test rig and procedure was designed in order to predict the life expectancy of Thermal Barrier Coatings (TBC) under thermal cycling conditions similar to those meet in combustion chambers. Two 2kW-halogen lamps highly focused on the TBC were used to expose the surface of the coating to an intense heat flux. A 25x100 mm TBC is Air Plasma Sprayed (APS) centered onto a substrate 25x370 mm. The thermal cycling can be done either under inert or oxidizing atmosphere in order to separate oxidation-induced acoustic emissions from that resulting from the mismatch of the Coefficient of Thermal Expansion (CTE) of the coating compared to that of the substrate. Two transducers located at each end of the substrate monitor the Acoustic Emission (AE) signals emitted by crack initiation and/or propagation, were recorded and analyzed in order to deduce available information about TBC behavior under thermal load. The use of two transducers with a time of flight approach provides a valuable means of identifying both the crack formation and its location. This thermal cycling test is adequate for the study of various samples, like welded substrates coated with TBC or TBC coated around holes. The presence of cracks is observed using metallography preparation and microscopic observation.

A thermal cycling test was designed in order to predict thermal barrier coatings (TBC) life of combustion chambers. The thermal cycle is produced by two 2kW halogen lamps highly focused on the TBC. A 25X100 mm TBC is plasma sprayed centered onto a substrate 25X300 mm. The thermal cycling can be done either under argon atmosphere or air in order to be able to discriminate the oxidation induced acoustic emissions from the expansion mismatch. Two transducers located at each end of the substrate monitor the acoustic signals emitted by crack initiation and/or propagation. The advantage of using two transducers is that with a time of flight approach cracking phenomena can be located along the TBC. This process allows the study of welded substrates coated with TBC, TBC coated around holes and to check for the presence of cracks by using metallography preparation. The challenge of the test is to use the early cycles emission signatures in order to predict the long term durability of the TBC.

The aim of this work is to study the adhesion of WC-Co coatings using acoustic emission testing. The coatings were produced by HVOF spraying then subjected to four-point bending while in situ acoustic emission measurements were made. The test specimens were then examined under a microscope, revealing regularly spaced transverse cracks on the coating surface as well as interfacial cracking. An analysis of the acoustic emission data revealed two types of acoustic events based on absolute energy and amplitude. This appears to be linked to the cracks that were observed forming the basis for an interfacial cracking model.

This paper describes the development of an online process control system for spraying thick thermal barrier coatings as part of a Brite Euram research project. In addition to the evaluation of the substrate temperature, a system for acoustic emission analysis for particle impact and for controlling crack propagation is developed. The procedure, the problems overcome, and the results obtained are described. Paper includes a German-language abstract.

During the coating of components like rolls the major parameters are easily to control. But this is not sufficient to guarantee and stable a high coating quality. Additionally non-controllable parameters, e. g. nozzle wear, influence the process mainly. For this purpose a new testing method is necessary. On base of the acoustic emission analysis a testing equipment was developed in order to control the spraying conditions. In this investigation acoustic emission is applied to anlyse the signals generated by the impact of the molten particels on the component surface. The analysis of the signals is carried out in combination with a new classification method. The results of controlling APS(Atmosperical Plasma Spraying)-process during the disposition of a Cr2O3- coating will be presented. Paper text in German.

In this paper, plasma sprayed thermal barrier coatings (TBCs) with and without bond coat are stressed to various stress levels under four point bending with in situ acoustic emission (AE) to monitor any cracking activities. Micro- and macro-cracks occurring during the tests are investigated to better understand the failure mechanisms of TBCs. The results show that limited AE activities were detected in the first four stress-relief cycles, while plastic deformation and the greatest AE activity were observed when the applied load exceeded the yield point. In addition, they show that a TBC system that contained an adhesive layer had less AE activity (cracking events) than the TBC without an adhesive layer. In addition, the samples tested at a main speed of 5 micrometer/s resulted in a higher AE activity than the samples tested at 10 micrometer/s. With increasing plastic deformation, macro cracks and surface cracks also occurred. Paper includes a German-language abstract.

In this paper, the mechanical properties and cracking features of yttria stabilized zirconia with and without bond coat on steel substrates is investigated. Four point bending tests have been used to evaluate the mechanical properties, while acoustic emission (AE) has been used to in situ monitor the cracking behavior during the bend tests. In the sprayed state, the samples were characterized by four-point bending tests with local noise emission. In comparison with the substrate, the coated samples showed an increased flow pressure. It is also shown that the processing parameters, the cooling, and the adhesive layer have a significant influence on the flow pressure. It is proven that the cooling affects the behavior of the load-displacement curves. The AE analysis shows the different deformation behavior of the coating-substrate system for the different processing conditions. This is supported by the surface crack analysis. Paper includes a German-language abstract.

Microscopic fracture mechanisms of thermal spray coatings under bending stress are investigated. Samples of thermally sprayed coatings were made using three distances. The sprayed powder was pure molybdenum. Vertical microcracks occur in lamellae and subsequently, these cracks join together and form vertical macrocracks in the samples sprayed with a short spraying distance. On the other hand, horizontal microcracks occur at the lamellae interfaces, and these cracks link together in the samples sprayed with a long spraying distance. These tendencies can be explained in terms of the hardness of the lamella and the bonding strength between each lamella. It is clarified that the bonding strength between each lamella corresponds to the applied strain at the point of rapid increase of the acoustic emission (AE) event. The amplitude and rate of AE beyond the point of rapid increase are high in the coatings which formed macrocracks. It is concluded that the coating which has high resistance to crack formation has a high point of AE increase, low AE amplitude and low AE increasing rate.