Hydraulic turbines, valves, and pumps operate in environments where they are exposed to cavitation phenomena and corrosion, which can result in mass loss, leading to reduced performance and failure. HVOF spraying has been used to repair eroded surfaces on such components and new alloys are being developed to reduce repair costs. This investigation assesses the cavitation resistance of FeMnCrSiNiB alloy coatings deposited by HVOF spraying. Corrosion rates and oxidation potentials are measured under different conditions and compared to stainless steel coatings normally used on water turbine runners.

In this study, nickel-base superalloy coatings are deposited on CrMoAl substrates by different spraying methods and the coatings are evaluated based on their microstructure, phase composition, surface and splat morphology, bond strength, and corrosion properties. In the experiments, NiCrAlY powders with a particle size range of 30-45 μm were sprayed by conventional air plasma and a new laser hybrid plasma spraying technique. The spraying parameters are presented along with test results, observations, and conclusions. The coatings produced by laser hybrid plasma spraying had an average porosity of 0.9%, a bonding strength of 117 MPa, and significantly better corrosion properties than the APS layers.

This study assesses the effect of different alloying elements on the microstructure, oxygen content, hardness, and corrosion resistance of stainless steel coatings produced by atmospheric plasma spraying. SUS836L stainless steel powder with Si, Mn, and B additions served as the base feedstock alloy to which different amounts of B, C, Mo, Ti, Nb, V, and Cu were added. The powder mixtures were sprayed on carbon steel substrates and the deposits were examined and tested. The results show that B and C additions of 2-3% have a beneficial effect, but at 5% cause a drop in corrosion resistance that proved to be remediable through the addition of Cu, which improves the corrosion potential of the matrix phase by its combined action with Mo, Si, and B. The effect of Ti, Nb, and V, which are added to suppress Cr oxidation in molten alloy particles during flight, is that it promotes that formation of fine carbide and boride compounds, increasing hardness without sacrificing corrosion resistance. In addition to these findings, the study also shows that the coatings developed are in many ways comparable to Ni-based self-fluxing alloy coatings.

The economic use of offshore wind turbines requires a reliable and long-lasting corrosion protection. Sophisticated multilayer coating systems consisting of a thermal spray coating – mainly ZnAl15, a sealer and several layers of organic coating – have been proven to provide such protection. Damages to these duplex-coatings can, however, not be prevented necessitating on-site repair. In case of severe damages, the remaining coating close to the damage is often removed and subsequently, the duplex coating is rebuilt from scratch. In the present study, two integrated coating removal and substrate pre-treatment methods are investigated. For this purpose, duplex-systems were produced, artificially damaged by milling and afterwards treated by either grit blasting or with a rotating steel-wire brush, i.e. a Monti Bristle Blaster. Afterwards, the duplex coating was re-applied in the considered area. To evaluate the influence of the pre-treatment method on the coatings’ corrosion protection potential, a 38 week-long salt spray test was used. The test revealed a pronounced influence of the pre-treatment method on the corrosion protection potential. In case of grit blasting, no substrate corrosion could be detected. The use of a Bristle Blaster, however, resulted in coating failure and some spots of red rust.

In this study, WC-CoCr coatings were deposited on an aluminum substrate by HVOF spraying. Layer thicknesses between 50 and 150 μm were achieved by stepwise increase of the number of torch scans. The stepwise method is shown to make the coatings not only thicker, but also denser due to peening effects and changes in the splat formation mechanism. It also explains the incremental improvement in coating hardness and corrosion and wear resistance observed over the first few torch scans, the largest of which occurs between the second and third scans. The coatings are also compared to anodized films and were found to have superior wear and impact resistance but less resistance to corrosion.

Repair of damaged ion vapor deposition aluminum (IVD-Al) on aircraft components generally requires the use of brush plating with hazardous materials including cadmium. This paper describes a cold spray process that uses aluminum transition metals to make such repairs. The aluminum layers are applied with a handheld cold spray gun and tested according to JTP-2003 requirements for corrosion resistant coatings on steel components.

Cold spraying enables the production of pure and dense metallic coatings with very little porosity and oxygen content, all of which play an important role in corrosion resistance. This study investigates the microstructure, denseness (impermeability), and corrosion properties of tantalum coatings produced by high-pressure cold spraying. Various tests were conducted to assess corrosion behaviors in different aqueous solutions. Microstructural studies showed that interfaces in the coatings were practically free of voids and confirmed that high levels of localized plastic deformation occurred as expected during spraying. The study also confirmed that the polarization behavior of the cold-sprayed tantalum is similar to that of the corresponding tantalum bulk in saline as well as sulfuric and hydrochloric acid solutions.

In this study, Cu-based bulk metallic glass coatings were deposited by atmospheric plasma spraying with different hydrogen flow rates. The crystallization and oxidation of the coatings is assessed along with corrosion resistance. As thermal energy in the plasma jet increases, the melting fraction and oxidation of particles in the coating increases as does porosity. All of these factors have an effect on the corrosion resistance of Cu-based bulk metallic glass coatings and their relative impact is discussed.

In this study, low-pressure cold spraying was used to deposit Al and Al-Al 2 O 3 composite powders on different substrate materials, including steel, aluminum, and magnesium alloy. Corrosion performance was evaluated by electrochemical testing in 1M NaCl electrolyte and microstructure was examined by means of SEM analysis. The results show that the corrosion potential of Al-Al 2 O 3 coatings depends on the content of alumina and that its presence does not appear to accelerate dissolution and failure of passivation oxide films. The investigation also revealed that pure aluminum coatings on aluminum alloy substrates can act as sacrificial anodes, thus providing corrosion protection.

Cold spray is an effective technique to deposit pure metallic coatings on a variety of substrates. 1100 series aluminum-based coating has been deposited on similar aluminum substrate by cold spray technique using helium and a mixture of helium and nitrogen as powder carrying gases. The microstructural features of the coating were analyzed using optical micrography, Scanning Electron Microscopy (SEM) and Microhardness depth profiles. The electrochemical behavior of the materials was studied using 0.5 N H2SO4 as electrolyte. Tafel extrapolation experiments were carried out in order to calculate the corrosion rate, corrosion potential and the Tafel slopes, whereas, potentiodynamic polarization experiments were performed to understand the passivation behavior of the material under the experimental conditions. The electrochemical studies validate the use of cold sprayed aluminum coating for corrosion protection applications. SEM characterization of the coatings was also performed after the electrochemical experiments.

Coatings of HastelloyC fabricated by HVOF spraying with a gas shroud (GS) have shown the superior barrier characteristic and corrosion resistance in seawater environment. During immersion of these coatings in artificial seawater, however, vibrational behaviour of the corrosion potential was observed. Some types of surface modification of the sprayed coatings and changing of the spray condition were carried out and their effect on the corrosion potential was investigated. It was revealed that the vibration is related to surface oxides formed during the spray process. Surface modification of the sprayed coatings and changing of the spray condition could reduce the vibration effectively.

Two kinds of Fe-16Cr-30Mo-(C,B,P) alloy powders of different composition were thermal sprayed onto mild steel using HVOF and APS processes. Perfect amorphous coating was formed by HVOF and APS processes in both powders. The corrosion potential of the amorphous coatings sprayed by HVOF process was higher and the passive current density was lower than that of the amorphous coatings sprayed by APS process in 1N HCl solution. The coatings of perfect amorphous phase were little corroded after one week immersion tests and the corrosion rates of the amorphous coatings showed a fairly less value of 0.03 mm/y compared with Inconel 625 plate in 5N HCl solution at room temperature.

This paper evaluates an electrochemical mapping method for determining the corrosion resistance and structural integrity of thermally sprayed coatings. In the test setup, a potentiostat is suspended over the test sample, forming an electrochemical cell. The circuit is completed through an electrolyte-containing porous tip. Capillary forces keep the electrolyte on the surface of the tip, preventing transfer to the substrate surface. In the investigation, electrochemical, spatially resolved measurements are carried out on flame and vacuum plasma sprayed nickel-base coatings and compared with the results of salt spray testing. It is observed that the new method offers many advantages being faster, nondestructive, and quantitative in nature. Paper includes a German-language abstract.

This study evaluates the through-porosity of HVOF-sprayed Hastelloy C coatings on carbon steel with respect to coating thickness and combustion pressure. The amount of through-porosity in the NiCrMo alloy layer is determined by chemical analysis, using ICP emission spectroscopy, and compared with electrochemical measurements. Paper includes a German-language abstract.

This paper presents a process for manufacturing parts using HVOF spraying techniques. The parts are made from a mixture of chromium carbide and nickel chromium alloy powders and are characterized based on microstructure, hardness, and corrosion and wear performance. Paper includes a German-language abstract.

TiC-based coatings have proven to be very suitable candidates in various areas of thermal spraying when high corrosion and wear resistance is required. The most important advantages of these coatings are their high corrosion resistance compared to conventional coatings such as WC+Co and WC+Co+Cr, but also their low density. However, the main problem with HVOF spraying these materials is their high reactivity with the oxygen necessary for the flame. In this paper, Self-Propagating High-Temperature Synthesis-TiC+Ni-Ti base powder are processed with two different spray guns (Diamond Jet Hybrid (DJH) and CDS 100). This allows to compare the properties of the resultant coatings (wear and corrosion mainly) as a consequence of the main advantages of each variable (gun and gas) particularly in relation to the oxidation processes. It is observed that DJH coatings showed the best corrosion resistance whilst CDS coatings showed a corrosion potential closer to the steel value. Paper includes a German-language abstract.

This paper presents the electrochemical characterization of a chromium carbide-NiCr coating applied using high-speed flame spraying. It examines the behavior of the complete system, the steel, the steel coating, and the coating immersed in NaCl solution alone. The paper discusses electrochemical measurement methods such as the measurement of polarization resistance, anodic polarization, and open circuit potential. The tests are compared with each other and with results from metallographic examinations. The structure was characterized by light and scanning microscopy. In addition, an analysis of the residual water was carried out using an ICP technique. The paper also includes a study of the various mechanisms that could affect the behavior of such coating types in a corrosive environment. Paper includes a German-language abstract.

Stainless steel coatings were produced by supersonic air-gas plasma spraying method. Mixture of air and natural gas was used as a plasma forming gas. Powders of 304L and 316L stainless steels were used for plasma spraying. Thickness of coatings was up to 3 mm. Coating structure was studied. Dependence of oxygen content in coatings upon particle sizes and spraying conditions was established. Investigation of electrochemical properties of coatings was carried out by potentiostatic method. Corrosion potential and corrosion rate in sea water, hydrochloric and sulphuric acid solutions were determined.