Low pressure cold spraying is an attractive technique for onsite metal coating fabrication due to its compactness and portability. However, the bonding strength of the coating prepared by low pressure cold spraying is generally low, which restricts the further applications in engineering and industrial fields. To improve the bonding strength, pre-treatment on substrate surface can be an effective procedure. In this study, a low-temperature plasma treatment was applied to a pretreatment technique, and the effect of the treatment on particle bonding was compared with that of a laser treatment. Copper coatings on aluminum and copper substrates were selected and studied as basic metal materials. The SEM observation results show that the particle adhesion rate significantly increases by the laser and plasma treatments, due to the removal of the native oxide films on the substrates. The particle bonding on the plasma-treated substrate reveals better interfacial adhesion with less gap compared with the laser-treated one. The pre-treatment by low-temperature plasma can be an attractive technique to assist the cold spraying process due to the oxide removal ability and no thermal effect which can apply a wide range of materials.

In this study, superhydrophobic samaria-doped ceria coatings are produced by plasma spray physical vapor deposition (PS-PVD) followed by fluorination treatment. Samples are sprayed at distances of 300, 400, and 500 mm in order to obtain surfaces with different morphology. SEM examination shows that the surfaces have a hierarchical structure with island-like features consisting of nanoparticles, the size of which is shown to influence sliding behavior. The superhydrophobic coating surfaces also exhibited good stability in repeated adhesive-tape tear tests.

This work assesses the challenges of preparing dense technical ceramic substrates for thermal spraying and evaluates the capabilities of laser ablation in comparison with sandblasting. Sintered Si3N4 and AlN substrates were prepared by both methods and surface roughness was measured before and after treatment. Alumina coatings were deposited by suspension-HVOF and atmospheric plasma spraying, and coating cross-sections were analyzed by optical microscopy and SEM. Sandblasting had little or no effect on surface roughness and cracks were observed in coating cross-sections at the near-surface region of the substrate. Laser ablation, on the other hand, significantly increased surface roughness for both ceramics, producing hole patterns that are shown to vary with laser power and pulse timing. In the case of plasma spraying, the best coatings were achieved when the holes in the substrate were less than 100 µm in depth. With suspension sprayed coatings, the best results were obtained on substrates with deeper (> 100 µm) holes.

This study analyzes the mechanical properties of aluminum alloy substrates, in particular, changes in flexural behavior of laser-textured surfaces. Bending tests are conducted on samples treated by laser texturing and by conventional methods such as chemical degreasing and sandblasting. A comparison of flexural strengths caused by the different surface pre-treatments method is presented.

Since 2000, cast iron-liners have been replaced in several engine projects by Fe-based thermally sprayed coatings in the bores of a light metal crankcase. In contrast to cast in liners the linerless versions of these Al-crankcases are very demanding with regard to the porosity and tensile strength in the areas around the bores. The casting porosity has to be diminished to maximum pores smaller than 1mm² due to the roughening procedure, either mechanical roughening (MR) or high power water jet roughening (WR), in order to prevent either tool failure (MR) or widened pores (WR). At Nemak Dillingen these challenges are met by the Core Package Process (CPS), offering the advantages of a highly flexible casting design and a nearly unlimited choice of the cast alloy. These boundaries enable the production of lightweight crankcases made of the strong and creep resistant Al-Si-Cu based secondary alloy A319. The high quality of the cylinder bore surface is achieved by a carefully designed thermal household of the solidifying casting. The cylinder chill form a stable and sound shell in the very beginning of solidification, whereas feeding takes place from the sidewall structure of the crankcase. At the same time, specially designed chills for the bearing seat enable a very short solidification time, the resulting properties are crucial for highly loaded diesel engines. After casting and machining, the crankcases have been mechanically roughened and coated with 0.8 % C-Steel. The coatings and the interface between the coating and the casted Al-substrate have been investigated by means of light microscopy regarding the interlock between coating and substrate and the near-surface porosity of the cast metal.

The application of thermal coatings in cylinder bores is depending on above all functionality, process reliability and economy of pre treatment of the substrate surfaces. Different removing processes like water jetting or sand blasting are increasingly substituted by mechanical machining. Thereby great importance is attached to functionality and degree of automation. For an assured engine function, high bond strength is required. The roughening process as a modified cutting machining meets the requirements of modern production lines. Removing overspray after thermal coating by a water jetting process, is a further contribution for a higher automation degree. The final machining of sprayed surfaces is effected by a multi stage honing process. The composite structures of thermal coated layers call for high performance diamond abrasives. The finished functional cylinder surface comprehends cavities of thermal coated layer and smooth honing pattern. The technological description of roughening and honing, the process components as well as the machining results will be presented. Pre and post treatment are essential processes, which enable the application of high performance thermal coating materials in friction optimized combustion engines.

This work investigates the processes involved in the formation of fragmented layers produced on the surface of ceramic coatings by means of laser melting. For the experiments, plasma sprayed zirconia was applied to steel substrates and treated with CO 2 and Nd:YAG lasers. The modified layers were found to consist of macro-fragments 500-2000 µm in size, which in turn consist of micro-fragments 20-70 µm in size. Crack gaps were observed at both levels with widths of 10-15 µm and 1-5 µm, respectively. Heat resistance, hardness, density, and roughness were determined before and after laser melting, and the changes measured are shown to depend on emitted laser power. Paper includes a German-language abstract.

Transferred-arc cleaning is being investigated as a solvent-free cleaning method for various metallic substrates. With the recent increase in attention given the hazards involved in the storage, use and disposal of organic solvents, cleaning methods which promise comparable cleaning effectiveness with reduced hazards are being sought. Transferred-arc cleaning of tungsten substrates has been studied to identify the effect of processing conditions on cleaning and roughening characteristics. A Box-Behnken response surface designed experiment varying the chamber pressure, substrate standoff distance and plasma torch arc current while observing the transferred-arc voltage, current, surface cleanliness and surface roughness was performed. The results of the analysis show the effect of the various independent variables on the measured responses. Particular difficulties in roughening tungsten are due to its exceptionally high arc voltage for metal arc attachment. The results presented here provide an enhanced understanding of the arcing properties of various cathode materials. Such information is useful in obtaining the desired cleaning and/or roughening of the substrate.

Transferred-arc cleaning and roughening as discussed in the patent by Muhlberger is often used as a surface preparation method prior to low pressure plasma spray (LPPS) deposition of coatings. In this article, electrically transmitted arc cleaning is investigated as a precision cleaning method for thin films lubricating substrates as well as traditional cleaning and roughening for LPPS. A Box-Behnken reaction surface construction test is carried out with variation of the chamber pressure, the substrate distance and the torch current taking into account the transferred arc voltage, the voltage fluctuation, the current, the emitted light, and the surface cleanliness. The results of the analysis show the effect of the various independent quantities on the measured responses. Different stages in the cleaning process are determined by their sample cleanliness, their voltage level, their voltage fluctuation, their emitted light and their rate of erosion. Paper includes a German-language abstract.