Skip Nav Destination
Close Modal
Update search
Filter
- Title
- Authors
- Author Affiliations
- Full Text
- Abstract
- Keywords
- DOI
- ISBN
- EISBN
- Issue
- ISSN
- EISSN
- Volume
- References
Filter
- Title
- Authors
- Author Affiliations
- Full Text
- Abstract
- Keywords
- DOI
- ISBN
- EISBN
- Issue
- ISSN
- EISSN
- Volume
- References
Filter
- Title
- Authors
- Author Affiliations
- Full Text
- Abstract
- Keywords
- DOI
- ISBN
- EISBN
- Issue
- ISSN
- EISSN
- Volume
- References
Filter
- Title
- Authors
- Author Affiliations
- Full Text
- Abstract
- Keywords
- DOI
- ISBN
- EISBN
- Issue
- ISSN
- EISSN
- Volume
- References
Filter
- Title
- Authors
- Author Affiliations
- Full Text
- Abstract
- Keywords
- DOI
- ISBN
- EISBN
- Issue
- ISSN
- EISSN
- Volume
- References
Filter
- Title
- Authors
- Author Affiliations
- Full Text
- Abstract
- Keywords
- DOI
- ISBN
- EISBN
- Issue
- ISSN
- EISSN
- Volume
- References
NARROW
Format
Topics
Subjects
Article Type
Volume Subject Area
Date
Availability
1-20 of 126
Portable electrical energy sources
Close
Follow your search
Access your saved searches in your account
Would you like to receive an alert when new items match your search?
1
Sort by
Proceedings Papers
ITSC2024, Thermal Spray 2024: Proceedings from the International Thermal Spray Conference, 8-16, April 29–May 1, 2024,
Abstract
View Paper
PDF
All solid-state sodium-ion batteries (ASS-SIBs) have great potential for application to large-scale energy storage devices due to their safety advantages by avoiding flammable organics and the abundance of sodium. In this study, plasma spraying was used to deposit Na 3 Zr 2 Si 2 PO 12 (NZSP) electrolyte for assembling high performance ASS-SIBs. NZSP electrolyte layers were deposited at different spray conditions using NZSP powders in different particle sizes. The factors influencing the microstructure and compositions of NZSP layers were examined by characterizing the compositions of splat and cross-sectional microstructures of the deposits. It was found that the preferential evaporation loss of Na and P elements occurs severely to result in a large composition deviation from initial powders and spray particle size is key factor which dominates their evaporation loss. The APS NZSP electrolytes present a dense microstructure with well bonded splats which is attributed to low melting point of NZSP. The apparent porosity of the as-sprayed NZSPs was lower than 3 %. The effect of annealing on the microstructure of APS NZSP was also investigated. The performance of typical APS NZSP was also evaluated by assembling an ASS-SIB battery with APS NaxCoO2 (NCO), Na 3 Zr 2 Si 2 PO 12 (NZSP) and Li 4 Ti 5 O 12 (LTO) as cathode, electrolyte and anode, respectively. Results showed that columnar-structured grains with a chemical inter-splat bonding were formed across the interfaces between electrodes and electrolyte. There is no evidence of inter-diffusion of zirconium, cobalt and silicon across the NCO/NZSP interface. With the preliminary battery, the solid electrolyte exhibited an ionic conductivity of 1.21 × 10 -4 S cm -1 at 200 o C. The SIB can operate at 2.5 V with a capacity of 10.5 mA h g -1 at current density of 37.4 μA cm -2 .
Proceedings Papers
ITSC2024, Thermal Spray 2024: Proceedings from the International Thermal Spray Conference, 59-66, April 29–May 1, 2024,
Abstract
View Paper
PDF
In this work, thermally sprayed sustainable coatings with spray additives recycled from dry alkaline batteries and solid-oxide fuel cells are developed to allow the growth of drought-resistant plants like moss, microclover and chamomile. It is assumed that these plants anchor to the coating with their rhizoids and hence can be grown without the presence of soil. Preliminary tests of a thermally sprayed Yttrium Stabilized Zirconia (YSZ) ceramic coating on sheet metal confirms the growth of chamomile plant.
Proceedings Papers
ITSC2023, Thermal Spray 2023: Proceedings from the International Thermal Spray Conference, 604-609, May 22–25, 2023,
Abstract
View Paper
PDF
The previous results have shown that dense bismuth oxidebased electrolytes can be fabricated simply by plasma spraying owing to their low melting point. In this study, the Bi 2 O 3 – Er 2 O 3 –WO 3 electrolyte of high ionic conductivity was deposited by the cost-effective plasma spraying to assemble the SOFC for examining its electrochemical performance. The SOFC cell consisted of FeCr 24.5 metal support, NiO-YSZ anode, 10 mol% scandium oxide-stabilized zirconium oxide (ScSZ) electrolyte, (Bi 2 O 3 ) 0.705 (Er 2 O 3 ) 0.245 (WO 3 ) 0.05 (EWSB) electrolyte, and La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3 (LSCF) cathode. The ScSZ electrolyte interlayer was introduced between the anode and EWSB electrolyte to hinder the reduction of EWSB in the anode environment. NiO-YSZ, ScSZ, EWSB, and LSCF were deposited by plasma spraying on the metal support which was prepared by a press-forming-sintering process. The NiO-YSZ/ ScSZ/ EWSB/ LSCF single cell assembled with the as-sprayed ScSZ presented an open circuit potential of 0.90V at 600 °C and the maximum power density of 1130 mW cm -2 at 750 °C, 450 mW cm -2 at 650 °C, and 128 mW cm -2 at 550 °C. The plasma sprayed ScSZ electrolyte was then densified through impregnating using yttrium and zirconium nitrate solutions followed by annealing treatment. The single cell assembled with the densified ScSZ presented an open circuit potential up to 1.004V at 600 °C and the maximum power density of 1356 mW cm -2 at 750 °C, 619 mW cm -2 at 650 °C, and 163 mW cm -2 at 550 °C. The performance of the cell was significantly improved by the post-spray densification treatment of the ScSZ electrolyte. The present result shows that the high performance NiO-YSZ/ScSZ/EWSB/LSCF cell at intermediate temperatures can be successfully fabricated by plasma spraying.
Proceedings Papers
ITSC 2022, Thermal Spray 2022: Proceedings from the International Thermal Spray Conference, 789-797, May 4–6, 2022,
Abstract
View Paper
PDF
A solid oxide fuel cell is an electrochemical conversion device that produces electricity directly from oxidizing a fuel. It involves ionic transport and electrochemical reactions where the electrolyte and electrode properties play a major role in performance, along with a range of complementary materials that need to ensure equally relevant functions across the cell. The lifetime of such functional materials is expected to reach many thousands of hours with minimal degradation. This article is centred around the process development, optimization and scale up of a thin plasma sprayed ceramic barrier layer to mitigate long-term performance degradation of metal-supported solid oxide fuel cells. The evolution from the proof of concept in a laboratory environment to the scale up toward large scale manufacturing production is discussed. The challenges associated with minimizing application time and lowering cost while maintaining high coating performance at high yield are discussed. Empirical observations such as microstructural analysis and in-flight particle monitoring are used to gain understanding of the plasma spray process and guide its development for high-volume production. Results show how this effort has led to the reduction of the coating deposition time by 94% to enable large-scale manufacturing at high yield.
Proceedings Papers
ITSC 2021, Thermal Spray 2021: Proceedings from the International Thermal Spray Conference, 440-446, May 24–28, 2021,
Abstract
View Paper
PDF
Stabilized bismuth oxide with fluorite structure is considered a promising electrolyte material for intermediate temperature solid-oxide fuel cells (SOFCs) due to its high oxygen ion conductivity. The ternary system, Bi2O3-Er2O3-WO3, is of particular interest because it is ionically conductive as well as thermally stable. This study investigates the quality of Bi2O3-Er2O3-WO3 (EWSB) electrolyte produced by plasma spraying. The phase structure and cross-sectional microstructure of plasma-sprayed EWSB were characterized by XRD and SEM. The as-sprayed EWSB was found to have a dense microstructure with well bonded lamellae. XRD analysis showed the formation of EWSB with δ-phase and a trace of β-phase, while the β-phase disappeared after annealing at 750°C for 10h. Electrical property tests revealed that the plasma-sprayed electrolyte also had excellent ionic conductivity (0.26 S cm-1 at 750 °C), making it a strong candidate for use in SOFCs at intermediate temperatures.
Proceedings Papers
ITSC 2019, Thermal Spray 2019: Proceedings from the International Thermal Spray Conference, 376-381, May 26–29, 2019,
Abstract
View Paper
PDF
This study investigates the effect of deposition temperature and particle size on lanthanum strontium chromite (LSC) deposits produced by atmospheric plasma spraying. The results show that dense deposits with lamellar interface bonding can be achieved at temperatures above the critical bonding temperature and that particle size has a significant effect on chromium vaporization losses. The loss of chromium may be responsible for the low electrical conductivity of LSC deposits produced from small powders, which suggests that conductivity can be controlled with appropriate process adjustments.
Proceedings Papers
ITSC 2019, Thermal Spray 2019: Proceedings from the International Thermal Spray Conference, 382-387, May 26–29, 2019,
Abstract
View Paper
PDF
This study assesses the potential of scandia-stabilized zirconia (ScSZ) produced by very low-pressure plasma spraying (VLPPS) for metal-supported solid oxide fuel cell (MS-SOFC) applications. To investigate the microstructure of ScSZ, coating samples were deposited at spraying distances of 150, 250, 350 mm. The fragile nature of coating cross-sections suggests that the typical lamellar structure of zirconia is replaced by a transgranular structure. Nonetheless, apparent porosity, ionic conductivity, open circuit voltage, and ohmic resistance measurements indicate that VLPPS is a viable method for producing MS-SOFCs.
Proceedings Papers
ITSC 2018, Thermal Spray 2018: Proceedings from the International Thermal Spray Conference, 655-659, May 7–10, 2018,
Abstract
View Paper
PDF
Ni-Co-Al-Li oxide (NCAL) is an important catalyst material for low-temperature solid oxide fuel cells (LTSOFCs). In this paper, air-plasma spray (APS) coating technology was applied to make NCAL layers on porous steel supports for the LTSOFC. The results showed that NCAL was well deposited on the skeletons of the support. Due to the plasma heating, the original LiMO 2 phase transferred to Li-deficient Li 0.4 M 1.6 O 2 phase simultaneously forming Li-rich oxide. New fuel cell structures were designed. The stability of the fuel cells was evaluated by performing galvanostatic test at 500 °C. The influence of the cell structures and quality on the electronic property of the cells was discussed.
Proceedings Papers
ITSC 2018, Thermal Spray 2018: Proceedings from the International Thermal Spray Conference, 665-669, May 7–10, 2018,
Abstract
View Paper
PDF
High manufacturing costs and long-term degradation are the main problems that have become a “bottleneck” and impeded SOFC’s further development. It is well known that a high operating temperature is the major cause that leads to these problems. As such, reducing the operating temperature becomes a hotspot of research. It has been reported that a uniform and dense coating can be prepared by using very low pressure plasma spraying (VLPPS) technology. The current study focuses on VLPPS for application in large-area (~100 × 100 mm) porous metal supported solid oxide fuel cell (MSSOFC), especially for the preparation of the electrolyte. It was found that the densification of the electrolyte was very good, as confirmed by the open-circuit voltage (OCV) of the cell. In the temperature range of 550~750°C, the OCV of the cell stabilized between 1.05 V and 1.1 V. The power density of the cell was also measured.
Proceedings Papers
ITSC 2017, Thermal Spray 2017: Proceedings from the International Thermal Spray Conference, 132-137, June 7–9, 2017,
Abstract
View Paper
PDF
Solid oxide fuel cell (SOFC) has been developed for a hundred year and met a great challenge on material design and marketing. In recent years, new SOFC materials are dug up to achieve high energy-output performance at lower working temperature (300~600 °C), namely low-temperature SOFC (LTSOFC). In this study, Ni-Co-Al-Li oxide (NCAL) was used for making dense, thin and uniform coatings on grooved bipolar electrode substrate for LTSOFC. Low-pressure plasma spray (LPPS) technology was applied to manufacture the NCAL coatings. The performance of a fuel cell package using the coated bipolars was tested between 350 and 600 °C, showing 6~8 W power output with 4 single fuel cells (active area of 25 cm 2 ). The LPPS technology is believed to be one of the ultimate ways for manufacturing the thin film/coatings for SOFC applications in future.
Proceedings Papers
ITSC 2017, Thermal Spray 2017: Proceedings from the International Thermal Spray Conference, 840-842, June 7–9, 2017,
Abstract
View Paper
PDF
The present work deals with a Laves phase C14 AB2 alloy, namely (TiZr)(VNiMnCrSn)2. The alloy in many ways is a good alternative to a rare earth AB5 alloy with a superior capacity reaching a value of 400 mAh/g. A drawback with this alloy is that it is difficult to activate and therefore it is desirable to develop processing techniques which would readily activate the alloy. In this study we have plasma processed the alloy so as to see if this processing would exercise a positive effect on activation. AB2 powder was therefore fed to plasma torch with 25 kW power. The powders of -325 mesh had a range of particles sizes, the finer ones were evaporated and condensed into nanoparticles less than 100 nm in size. The larger ones spheroidized and were collected in the form of two groups of powders. We have characterized all three groups of powders both chemically and the latter two in terms of electrochemical performance.
Proceedings Papers
ITSC2016, Thermal Spray 2016: Proceedings from the International Thermal Spray Conference, 846-851, May 10–12, 2016,
Abstract
View Paper
PDF
In this work, liquid plasma spraying is used to deposit composite coatings for potential use as cathodes in intermediate-temperature solid oxide fuel cells. A suspension containing well-distributed Gd-doped ceria (GDC) nanoparticles in a lanthanum strontium cobalt ferrite precursor solution was used as the feedstock, and GDC concentration was varied to study its effect on phase composition, microstructure, surface morphology, and electrochemical performance. The results are presented and discussed.
Proceedings Papers
ITSC2016, Thermal Spray 2016: Proceedings from the International Thermal Spray Conference, 906-910, May 10–12, 2016,
Abstract
View Paper
PDF
Tubular asymmetric LSCF oxygen transport membranes (OTMs) were prepared on stainless steel substrates by PS-PVD and supersonic air-gas plasma spraying (SAPS). The microstructure of the thermally sprayed OTMs is examined by cross-sectional imaging and oxygen permeability is assessed via oxygen permeation flux measurements carried out at atmospheric pressure in an air-helium gradient. The findings from the cross-sectional analysis and oxygen permeation tests are reported and discussed.
Proceedings Papers
ITSC2016, Thermal Spray 2016: Proceedings from the International Thermal Spray Conference, 946-949, May 10–12, 2016,
Abstract
View Paper
PDF
In this work, pure silicon and Ni-P coated silicon powders were cold sprayed on copper foil. To thicken coating layers, 2-pass and 3-pass coatings were carried out. In the case of Ni-P coated silicon powders, coated anodes show excellent charge-discharge characteristics after two passes. For the pure silicon powders, however, even if a 2-pass operation is performed, the additional attached silicon mass is only 2~3 %. This means that multi-pass spraying is not an effective way to increase the thickness of pure silicon coatings produced by cold spraying.
Proceedings Papers
ITSC2016, Thermal Spray 2016: Proceedings from the International Thermal Spray Conference, 406-411, May 10–12, 2016,
Abstract
View Paper
PDF
Lanthanum gallate doped with strontium and magnesium (LSGM) is a good electrolyte candidate for Intermediate-temperature solid oxide fuel cells (IT-SOFCs). In this study, low-temperature sintering is used to increase the density of LSGM coatings prepared by vacuum cold spraying (VCS). LSGM layers with different thickness were deposited by VCS on NiO-YSZ substrates. In order to suppress chemical reactions between Ni and LSGM, the substrates were coated with gadolinium-doped ceria by tape casting. After sintering at 1200 °C, the coatings were found to be denser in most regions due to grain growth, which appears to be accompanied by cracking, particularly in thicker layers. A second layer was deposited on the annealed coatings to seal the cracks and the two-layer structure was further sintered. Gas permeability test results show that the multilayer films are dense enough to consider their use as electrolyte membranes in IT-SOFCs.
Proceedings Papers
ITSC 2015, Thermal Spray 2015: Proceedings from the International Thermal Spray Conference, 566-570, May 11–14, 2015,
Abstract
View Paper
PDF
Lithium-ion batteries have high energy efficiency and good cycling life and are considered as one of the best energy storage device for hybrid and/or electrical vehicle. Still, several problems must be solved prior to a broad adoption by the automotive industry: energy density, safety and costs. To enhance both energy density and safety, the current study aims at depositing binder-free cathode materials using inductively-coupled thermal plasma. In a first step, lithium iron phosphate LiFePO 4 powders are synthesized in an inductively-coupled thermal plasma reactor and dispersed in a conventional polyvinylidene fluoride (PVDF) binder. Then, binder-free LiFePO 4 coatings are directly deposited onto nickel current collectors by solution precursor plasma spraying (SPPS). These plasma-derived cathodes (with and without PVDF binder) are assembled in button cells and tested. Under optimized plasma conditions, cyclic voltammetry shows that the electrochemical reversibility of plasma-derived cathodes is improved over that of conventional sol-gel derived LiFePO 4 cathodes. Further results related to the substitution of iron with manganese in the SPPS precursors (LiMPO4, where M = Fe or Mn) are discussed.
Proceedings Papers
ITSC 2015, Thermal Spray 2015: Proceedings from the International Thermal Spray Conference, 996-1000, May 11–14, 2015,
Abstract
View Paper
PDF
LSCF(La 0.6 Sr 0.4 Co 0.2 Fe0 .8 O 3 ) with a perovskite structure has been widely studied as cathode materials for intermediate solid oxide fuel cell(SOFC). It has well-known excellent electrode performance due to its high ionic and electronic conductivity. However, application of LSCF cathode is likely to be limited by the surface catalytic properties and long term stability. Sr and Co may segregate from LSCF under cathode polarization, leading to increased resistance of the cathode. Oxygen hyper-stoichiometric La 2 NiO 4+δ with a K 2 NiF 4 structure possesses a higher catalytic properties, ionic conductivity and stability compared to LSCF cathode. However, the electrical conductivity of the La 2 NiO 4+δ (76 S cm –1 at 800 °C ) in the IT range are lower than 100 S/cm, which is regarded as the minimum requirement in electrical conductivity for an SOFC cathode. Taking account of both the advantages and disadvantages of the two different cathode materials, and good chemical compatibility of those two cathode materials, it is possible to prepare a composite cathode by infiltrating a thin film of La 2 NiO 4+ä on the porous LSCF to enhance the LSCF cathode performance. Therefore, in this study, the LSCF cathode was deposited by atmospheric plasma spray. The porous LSCF cathode was infiltrated by La 2 NiO 4+δ . The microstructure was characterized by SEM and TEM. The effect of infiltration on the polarization of LSCF cathode was investigated.
Proceedings Papers
ITSC 2015, Thermal Spray 2015: Proceedings from the International Thermal Spray Conference, 1138-1147, May 11–14, 2015,
Abstract
View Paper
PDF
The current paper reports self-healing plasma sprayed Mgspinel (MgAl 2 O 4 ) coatings. The coatings were used for electrical insulation in high temperature fuel cells. A range of potential self-healing additives consisting of SiC+X (where X was BaO, CaO, ZnO, Y 2 O 3 , GeO 2 , Ta 2 O 5 , V 2 O 5 ) were characterized and SiC+Y 2 O 3 was initially selected for coating development. Coatings of spinel with 20wt% additive were developed using vacuum plasma spraying (VPS) or atmospheric plasma spraying (APS). In the developed coatings, self-healing was demonstrated after heat treatment at 1050°C in air for 10 hour. Thermophysical and thermomechanical properties of self-healing coatings were determined and compared to spinel coatings. Lastly, a modelling technique is presented to simulate the effective elastic moduli of the coatings. Numerical results based on microstructural simulations showed good agreement with experimental data.
Proceedings Papers
ITSC 2015, Thermal Spray 2015: Proceedings from the International Thermal Spray Conference, 1148-1154, May 11–14, 2015,
Abstract
View Paper
PDF
Based on the specific structure of tubular solid oxide fuel cell stacks, a good chemical, microstructural and phase stability for the protective coating are required in both the oxidizing and reducing environments. In this work, MnCO 2 O 4 coatings of approximately 150 µm were deposited onto porous Ni50Cr50-Al 2 O 3 substrate by atmospheric plasma spray (APS) process. The coated samples were tested at 800°C with the coating exposed in air environment and the substrate in H 2 environment. Reducing and pre-oxidizing treatments were performed prior to the stability test. Then the tested coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD results elucidated that the tested coating had a high structural stability on the upper layer, while presented a reducing microstructure on the substrate side. The surface morphology of 100 hours tested coating indicated that the spinel granules still arranged closely with small particle size of ~ 250 nm and no obvious grain enlargement was observed. According to the cross-section, the upper layer kept stable and dense. While at the underneath region, the microstructure presented to be rather porous. However, the resistance presented a decreasing trend with the extension of exposure duration. After exposure for 95 h, the ASR decreased to 18.5 mΩ·cm 2 although a substantial Cr diffusion from the substrate was detected.
Proceedings Papers
ITSC2014, Thermal Spray 2014: Proceedings from the International Thermal Spray Conference, 768-773, May 21–23, 2014,
Abstract
View Paper
PDF
Lanthanum-doped strontium titanate (LST) and samarium-doped ceria (SDC) are promising materials for intermediate-temperature solid oxide fuel cells (IT-SOFCs). In this study, LST-SDC composite anodes are produced by suspension plasma spraying and the effects of annealing are assessed. XRD results show that the coatings and powders have the same phase structure. The coatings have a fine porous structure which is beneficial for gas permeability and long three-phase boundaries that facilitate anode reactions. A single cell based on the LST-SDC composite anode was found to perform well at 650-800°C. The results show that annealing improves interface bonding between particles in the anode and at the interface between the anode and electrolyte.
1