Aerosol deposition (AD) is a novel method for producing dense nanocrystalline ceramic films at room temperature. Previous studies primarily used flat substrates with varying hardness and roughness. However, the development of micro-device applications is increasing the demand for deposition on structured/patterned surfaces. To investigate the impact of substrate patterns on coating microstructure and growth mechanisms in AD, alumina coatings were deposited on patterned Si substrates. Si wafers with patterns of micropillars were employed. The coatings were characterized using laser scanning microscopy, scanning electron microscopy, and x-ray diffraction. The microstructure and density of coatings in the valleys were influenced by the size of and the spacing between the patterns. The results revealed that coatings initially formed in the valleys before covering the entire pattern. Fragments of the initial powder particles became trapped between the patterns, adhering to the groove bottoms and pillar sides. Subsequent particle impacts and densification processes transformed these fragments, ultimately filling the gaps between the walls. With further deposition, a uniform coating surface was achieved.

Hybrid plasma spraying combines deposition of coatings from coarse powders and liquids (suspensions or solutions) so that the benefits of both routes may be combined. In this study, failure evolution of early-stage thermal barrier coatings (TBCs) with hybrid YSZ-YSZ and YSZ-Al 2 O 3 top-coats deposited by hybrid water/argon-stabilized plasma torch was evaluated. In-situ bending experiment was carried out in SEM to assess potential influence of the secondary miniature phase addition on the coating failure during mechanical loading. Adapted high-resolution open-source strain-mapping code GCPU_Optical_flow was used to track evolution of the local coating failure. For the tested coatings, addition of miniature phase did not weaken the hybrid coating microstructure as the crack propagation was practically insensitive to the presence of the secondary phase and dissimilar splat boundaries. Main micromechanisms of the top-coat failure were thus splats cracking, loss of cohesion (splat debonding), and mutual splat sliding.

For the application of thermally sprayed titanium coatings, the high oxygen affinity and tendency to nitride formation in the presence of nitrogen represents a major challenge. Consequently, thermally sprayed titanium coatings are usually applied by cold gas spraying, vacuum plasma spraying and shrouded spraying processes. Nevertheless, the formation of oxides cannot be completely avoided with these methods. The pre-sent study demonstrates an alternative coating strategy for the application of oxide and nitride free thermally sprayed titanium coatings. Thereby, the previous limitations are overcome by transferring the coating process into a silane-doped argon gas environment to achieve an extremely low oxygen and nitrogen partial pressure. Thus, the created titanium coatings are oxide and nitride free and have an extremely low porosity. Moreover, by transferring of the corundum blasting process to this environment, the native oxide layer on the substrate surface can be removed and its reformation is suppressed. This results in full material bonding conditions with extremely high adhesive tensile strengths.

Thermal spraying of fine and ultrafine powders is realised by a novel method based on highly filled filaments as feedstock material for high velocity oxy fuel flame spraying (HVOF). Hereby, the desired coating material is supplied as finely dispersed powder within a polymer filament. Thus, the polymer works only as a transport medium and is fully decomposed when entering the combustion zone instantly releasing the solid dispersion, similar to the liquid dispersion medium in a suspension. It can work as an appropriate method to process fine and ultrafine powders. The solid nature of the dispersion medium poses several benefits compared to liquids, especially from the manufacturing point of view, since the process is geared to a wire flame spraying method. This work focusses on the challenges and benefits of this novel approach. First experimental results of spraying different filaments are presented.

In this work, a novel HVOAF process fueled with ethanol was employed to prepare NiCoCrAlYTa coatings on AISI 304 stainless steel substrate. To be able to add compressed air into the torch, it was designed to add a second-stage combustion chamber. Thereafter, investigations were carried out to determine the influence of different compressed air flow rates on the evolution of the microstructure and properties of the resulting NiCoCrAlYTa coatings. The phase composition, microstructure, porosity, microhardness, bond strength and wear resistance of the as-sprayed coatings have been studied in detail. The results reveal that the compressed air flow rate has a substantial effect on the coating's microstructure. The addition of compressed air also contributes to reduce the degree of oxidation of the coating, which could be attributable to a decrease in the temperature of the flying particles and an increase in their velocity. Although the use of compressed air diminishes the coating's bonding strength, it still has some elevated strength. Furthermore, the injection of compressed air improves the coating's sliding wear resistance dramatically. SEM and EDS were used to investigate the sliding wear mechanism of the coating. Detailed correlation between the compressed air flow rates and the coating properties are elaborated to identify the coatings exhibiting optimum performances.

Repair methods are of great interest to the aeronautic industry, especially for turbines. Deposition techniques that can quickly and easily repair small localised areas of damage in Thermal Barrier Coatings (TBCs) on combustion chambers could be financially worthwhile. In a first approach, a Low-Power Plasma Reactor (LPPR) operating at low pressure (< 1000 Pa, 240 W) was tested to locally deposit effective Yttria partially Stabilised Zirconia (YSZ) as TBC; however, a vacuum chamber would be more difficult to implement on an industrial scale. For this reason, a new LPPR (< 1 kW) operating at atmospheric pressure with solution precursors was investigated. The precursors were injected in the plasma afterglow to be sprayed and deposited onto parts of combustion chambers. As the afterglow temperature was cooler than for most thermal spray processes, spray distance was less than 10 mm. As such, YSZ deposition could be performed locally in hard-to-reach areas. YSZ coating characteristics were studied by FTIR and SEM analyses. For example, YSZ coatings exhibited the expected stoichiometry, a precursor conversion of 98 mol%, good adherence, and a porosity evaluated at approximately 30 vol%. In addition, YSZ coating thickness could be greater than 200 μm.

Hybrid aerosol deposition (HAD) is a new coating method to deposit homogeneous nano-structured ceramic coatings. An accurate evaluation of the fabricated coating properties is required. In this study, α-Al 2 O 3 fine powder was sprayed by HAD. The obtained coatings were dense and uniform with a nanocrystalline structure. An X-ray diffraction measurement revealed that the fabricated HAD Al 2 O 3 coatings mainly consisted of α-Al 2 O 3 phase. The hardness and Young's modulus of the HAD Al 2 O 3 coatings were evaluated by a micro-Vickers method and a nanoindentation method using the Weibull distribution. The hardness of HAD Al 2 O 3 coatings measured by micro-Vickers was ~1400 HV (~15 GPa). The variation of mechanical properties of HAD coatings measured by the nanoindentation method was extremely small compared to those of plasma-sprayed coatings, which also indicates that HAD coatings contain less pores and cracks than plasma-sprayed coatings.

In the past few years, the Extreme High-Speed Laser Material Deposition (EHLA) process has been used as a coating technology alongside conventional processes due to its unique process characteristics and is an economical and sustainable alternative to traditional technologies. The essential characteristic of the process is that the main energy is absorbed by the powder particles so that they reach the substrate surface in a molten state. Thereby, metallurgically bonded and dense wear and corrosion protection coatings are generated. This leads to significantly higher surface and deposition rates can be achieved in comparison to Laser Material Deposition (LMD), and heat-sensitive substrates can be coated. Moreover, in addition to this resource efficiency, the process is not only economically attractive but also sustainable. To reduce component weights as well as secondary energy consumption, aluminium has become an essential base material in most industrial sectors. Aluminium is not simple to process and the wear resistance is small due to the low hardness in comparison to widely used steels. Various technology solutions are currently being investigated for the coating of aluminium. The low melting temperature of aluminium (approx. 750 °C) poses a great challenge when coating with, for example, iron-based alloys. Another challenge for laser-based systems is the reflectance of aluminium in the wavelength range approx. between 1030-1070 nm of conventional laser beam sources. The high degree of reflection of aluminium is the reason why additive processing quiet challenging is. Therefore, for conventional laser-based processes, laser beam sources in other wavelength spectra, e.g. green or blue, are being developed to improve the processing of aluminium. Currently, commercially available multi-kW lasers in the visible light spectrum are still below the available power of IR beam sources. In the context of this study, the feasibility of coating aluminium using EHLA is investigated. A high power 8 kW IR disk laser of the TRUMPF company is used to determine the maximum possible deposition and surface rate.

Deposition of protective dense environmental barrier layers is a promising solution to improve the reliability and environmental durability of the next-generation turbines and other industrial applications. In this context, spraying of fine particles could enhance the formation of fine dense coating microstructures with improved properties. In AIST we are focusing on the spraying of the fine particles via different spraying technologies including suspension plasma spraying, as well as deposition of the fine solid particles directly by aerosol deposition (AD) and plasma-assisted aerosol deposition (so-called Hybrid Aerosol Deposition; HAD. The HAD is a new coating window to spray the fine ceramic particles via the implementation of a low-power rf-plasma source to assist the aerosol deposition at room temperature. This study introduced the feasibility of utilization of HAD as an outstanding technology for deposition of dense ceramic coatings on different substrate materials and 3D deposition capability. Highly dense and well-adhered Al 2 O 3 coatings without obvious observable cracks and bulk-like properties were successfully fabricated on different substrate materials of SUS 304, Aluminium, Al 2 O 3 and glass, via HAD of fine particles. The substrate material and its hardness significantly influenced the first deposition step, which determined the coating adhesion and properties. Furthermore, homogeneously uniform, dense, and crack-free coating with a strong adhesion has been fabricated successfully on cylindrical substrates with 6.3 mm diameter. During HAD spraying the plasma activated the surface of the particles without reaching to the molten state, then the activated particles impact and stuck with the substrate by room temperature impact consolidation mechanism. Therefore, the fabricated coatings had the same crystal structure as the starting feedstock powder, and the activated surface act as glue and improved the deposition efficiency and 3D capabilities. Herein, the deposition phenomena of HAD makes it as a promising candidate technology for development of environmental and sealing layers of highly dense microstructure, with the targeted crystalline phase structure, without stoichiometric composition nor phase transformation and improved deposition efficiency on multi-shape components in different fields such as environmental, thermal barrier coatings (TBCs), environmental barrier coatings (EBCs) and gas turbine applications.

The use of metal powders is dynamically increasing in many different fields of research and industry. The development of additive manufacturing technology or innovative thermal spray processes still enhance the range of possible applications. This means that there is a big demand for high quality metal powder materials. Currently, the atomization methods, like water or gas atomization, seem to be most established technologies for metal powder production. This work concerns the development of an innovative technology of metal powder manufacturing, namely ultrasonic atomization. First, the general idea of ultrasonic atomization is discussed. The designing of sonotrode, in order to generate appropriate ultrasonic field responsible for metal stream atomization, is discussed. Then, the ultrasonic set-up was verified by using non-contact fiber optic displacement sensor. Finally, the developed system was preliminary tested under water loading and confirmed positively in terms of ultrasonic atomization capabilities.

Plasma spraying is a well established process for producing ceramic and metallic coatings for many technical applications. The quality of the coatings and the efficiency of the process depend on the powder and on the operating parameters as well as on the plasma torch properties. Whereas many efforts have been made on creating novel powders and on optimizing the operational parameters, the principle, however, of DC plasma torches has remained unchanged for many years. This was the reason for developing a novel DC plasma torch system. This paper presents the construction and operating principle of this innovative torch system. Its high performance is demonstrated in selected ceramic coatings. Paper includes a German-language abstract.

In order to coat hard-to-reach coating areas or parts with a complex geometry, it is often necessary to reduce the power of the "plasma flame." Conventional plasma systems are not designed for operation at lower power levels. Plasma arc stability as well as coating quality and performance are significantly reduced below a threshold current level. Conventional plasma systems are therefore unsuitable for this type of application. A novel inverter-based plasma system has been developed to overcome this problem. This paper provides information about this plasma system with technical properties and some application examples. The goal is to develop a plasma system designed to operate at lower power levels and at the same time be used for general "every day application". Paper includes a German-language abstract.

The production of functional coatings using Low Pressure Plasma Spraying (LPPS) has been successfully introduced into industrial application. Especially in the area of gas turbine coatings for resistance to hot gas corrosion, the efficiency and reliability of the LPPS process for consistent high quality coatings has provided it's leading position within the aircraft and energy market. Functional coatings with a specific thin coating thickness are interesting for many applications. In addition to the benefit of saving material, which is not required for the coating function itself, and the subsequent cost savings within the coating process, further advantages such as greater flexibility in the construction of the end product will be possible. This paper discusses the potential of LPPS technology in the area of thin coatings. Paper includes a German-language abstract.

A combination of pulsed combustion and advanced thermal spray technology has led to the development of the novel High Frequency Pulse Detonation (HFPD) spray technology by Aerostar Coatings. In the HFPD process, the flow of gaseous products from cycled explosions in the spray gun, is used to accelerate and heat the spray particles. This paper provides a fundamental description of this cyclical process, with the main differences to spray processes with stationary flow and also to traditional detonation spraying techniques in the center. Paper includes a German-language abstract.

This paper considers the problem of spraying the electrically conductive coatings on electrotechnical units for different purposes with the method of cold gas-dynamic spraying. It presents a general scheme of the spraying system, the characteristics of the spraying process and the main results of the property tests of electrotechnical units with coatings. The contact connections of copper bars provided with aluminum caps with protective coatings of copper, zinc, and nickel are tested. The paper demonstrates the conformity of the electrotechnical units injected using the CGS method with the requirements of the state standard. It was observed that while spraying the thin copper layer on aluminum caps by the CGS method the copper expenditurer 50 times decreases. The technical characteristics, with this, are close to the copper caps, and the cost is close to the aluminum caps. Paper includes a German-language abstract.

The name Champro was made up of the two words "chamber" and "process". It represents Sulzer Metco's thermal spray technology in a pressure chamber with a controlled environment. Different spray system types handle the process operating in a particular way. A part analysis for each type of spray system demonstrates the most economical customer solution. This paper discusses the processes involved in two types of thermal spray system for coating parts in a controlled atmosphere: type of system with continuous process and type of system with batch process. Paper includes a German-language abstract.