This paper discusses the challenges of constructing mathematical models of physicochemical and heat-mass transfer processes associated with reactive heterogeneous materials used in laser additive manufacturing. The results of calculations of thermocapillary convection induced by laser heating in an aluminum melt with an admixture of nickel particles are presented. Models of interphase and chemical interactions with the formation of intermediate phases and intermetallic compounds on nickel particles added to the melt during laser alloying or cladding are proposed, which make it possible to calculate the composition of intermetallic phases in the trace of the beam after crystallization and cooling.

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