The HVOF spraying process was used to create layers consisting of mechanically mixed chromium(II) carbide + 25% NiCr, NiCr, and CoCr-based metal powder alloys. This paper provides the investigation of additional influences of a metallic phase with tribological properties under friction conditions on the layer. The tribological properties of the layers are characterized under dry friction. The paper investigates the tribological behavior of the layer and the tribological film layers created during dry friction. It analyzes and discusses the influences of temperature, pressure, and friction speed on the tribological behaviour. Paper includes a German-language abstract.