The growing demand for flash memory in the artificial intelligence and big data industries has driven the development of Negative AND (NAND) gates. To increase yield and cost competitiveness, NAND has evolved to stack gates vertically, resulting in vertical NAND (VNAND) technology. However, this advancement has led to challenges, such as high aspect ratio-related difficulties and word line (WL) metal Tungsten (W) substitution process defects. In this study, we investigated Voltage Blocking Oxide Barrier (VBB) defects in VNAND cells under high-temperature conditions using in-situ heating TEM. By artificially creating VBB defect environments within VNAND cells and analyzing structural and chemical changes, we identified VBB defects expression phenomenon caused by residual HF(g) in metal voids during post-metal replacement processes. Our findings offer insights into defect-inducing heat treatment conditions affecting VBB in VNAND devices and propose directions for next-generation NAND flash processes.

Many semiconductor products are manufactured with mature technologies involving the uses of aluminum (Al) lines and tungsten (W) vias. High resistances of the vias were sometimes observed only after electrical or thermal stress. A layer of Ti oxide was found on such a via. In the wafer processing, the post W chemical mechanical planarization (WCMP) cleaning left residual W oxide on the W plugs. Ti from the overlaying metal line spontaneously reduced the W oxide, through which Ti oxide formed. Compared with W oxide, the Ti oxide has a larger formation enthalpy, and the valence electrons of Ti are more tightly bound to the O ion cores. As a result, the Ti oxide is more resistive than the W oxide. Consequently, the die functioned well in the first test in the fab, but the via resistance increased significantly after a thermal stress, which led to device failure in the second test. The NH4OH concentration was therefore increased to more effectively remove residual W oxide, which solved the problem. The thermal stress had prevented the latent issue from becoming a more costly field failure.

Manufacturing of integrated circuits (ICs) using a split foundry process expands design space in IC fabrication by employing unique capabilities of multiple foundries and provides added security for IC designers [1]. Defect localization and root cause analysis is critical to failure identification and implementation of corrective actions. In addition to split-foundry fabrication, the device addressed in this publication is comprised of 8 metal layers, aluminum test pads, and tungsten thru-silicon vias (TSVs) making the circuit area > 68% metal. This manuscript addresses the failure analysis efforts involved in root cause analysis, failure analysis findings, and the corrective actions implemented to eliminate these failure mechanisms from occurring in future product.

Rapid technology scaling results in ever shrinking device size. As such, sharper nanotips are required for application in nanoprobing systems. In this work, we present a two-step methodology of fabricating tungsten nanotips with radius of curvature down to 20 nm by using and optimized AC electrochemical etching of tungsten in KOH followed by laser irradiation in KOH. Finally we show the application of the fabricated nanotips with different radius of curvature (ROC) for nanoprobing.

We present an analysis of tungsten vias fabricated by a focused ion beam with regard to the understanding of circuit editing strategies. The growth rate of W is ~10 times faster in high aspect ratio vias than on flat surfaces, and W in vias has 4 at. % more C but only one-tenth the Ga of surface-deposited W. We propose that vias act like small Faraday cups, trapping the energy of the Ga+ ions and the reaction byproducts to enhance the growth rate of W and to increase the C to W ratio in vias compared to flat surfaces. The resistivity of W in the vias determined by a least squares fit to resistance data is 250μΩ-cm, unchanged from the resistivity of W deposited on a flat surface. The resistances of the vias fabricated in a SiO2 layer to contact an underlying Al sheet layer fit well to either of two models: 1) an effective area model that invokes resistive via sidewalls that do not participate in conduction, and 2) an contact resistance model that invokes tapered vias with a constricted W/Al contact area.

Circuit edit and failure analysis require tungsten deposition parameters to accomplish different goals. Circuit edit applications desire low resistivity values for rewiring, while failure analysis requires high deposition rates for capping layers. Tungsten deposition can be a well controlled process for a variety of beam parameters. For circuit edit, tungsten resistivity approaching below 150 µohm-cm and 50 μm 3 /nC is predicted. Material deposition rates of 80 μm 3 /nC can be achieved with reasonable pattern accuracy using defocus as a parameter.

In-line e-beam inspection is performed to detect dark voltage contrast (DVC) defects on normally bright W-plugs. Cross-sectional SEM and TEM in an FA lab verified that the different gray level values (GLV) of DVC defects are caused by different resistances of the W-plugs. We found that DVC defects with lower GLV (GLV1) are W-plugs that are open and almost open. DVC defects with GLV2 are caused by partially open W-plugs and in-plug voids.

Atomic force probing (AFP) uses very sharp tungsten tips (100nm in radius) which wear out rather quickly, even with the greater durability of tungsten as compared to silicon. This paper demonstrates how worn tips that no longer image and probe properly can be reconditioned using the focus ion beam (FIB) tool. The method works best for tips that are under approx. 750nm in diameter and are not bent. It works well for freshly manufactured tips that do not work properly due to mishandling or improper storage which allowed particulates/oxide to build up on the tip. The method also works well for fresh tips that have been worn down (or slightly bent) after several hours of scanning and probing. This method is straightforward and requires a minimal amount of time. Typically, four probe tips can be reconditioned in about 30 minutes on the FIB.

Interaction of inline SEM inspections with tungsten window-1 integrity were investigated. Multiple SEMs were utilized and various points in the processing were inspected. It was found that in certain circumstances inline SEM inspection induced increased window-1 contact resistance in both source/drain and gate contacts, up to and including electrical opens for the source/drain contacts.

For its latest generation of high performance logic applications, Motorola employs a 0.13 µm CMOS technology with shallow trench isolation (STI). The contact dimension and spacing requirements for the dense areas of the circuitry, such as the cache, are quite aggressive. We recently encountered single bit and massive array failures, which were traced to an electrical short between tungsten contacts. We report here the failure analysis, which involved electrical and physical testing techniques.

Smaller technologies and increasing chip functionality has resulted in tightly packed devices and more stacked metal layers. For technologies between 0.25µm and 0.14 µm, stacking packed metal layers required the combination of Tungsten plugs as interconnection and the utilization of Chemical Mechanical Polishing (CMP). “Pillar”, however, is a small metal line, which allows interlevel connections between Tungsten plugs. The size and shape of the pillar can be a yield limiting issue. The process of identification and resolution of the missing metal pillar included yield analysis, electrical and physical failure analysis, root cause analysis and the engineering coordination of photo engineering, etch process engineering, CMP engineering, integration engineering, and inline inspection. Resolving the missing pillar issue has proven to have significant contribution to yield.

The specimen preparation technique using focused ion beam (FIB) to generate cross-sectional transmission electron microscopy (XTEM) samples of chemical vapor deposition (CVD) of Tungsten-plug (W-plug) and Tungsten Silicides (WSi x ) was studied. Using the combination method including two axes tilting[l], gas enhanced focused ion beam milling[2] and sacrificial metal coating on both sides of electron transmission membrane[3], it was possible to prepare a sample with minimal thickness (less than 1000 A) to get high spatial resolution in TEM observation. Based on this novel thinning technique, some applications such as XTEM observation of W-plug with different aspect ratio (I - 6), and the grain structure of CVD W-plug and CVD WSi x were done. Also the problems and artifacts of XTEM sample preparation of high Z-factor material such as CVD W-plug and CVD WSi x were given and the ways to avoid or minimize them were suggested.