Martensitic stainless steels are an important group of steels for applications as knives, tools & molds and highly loaded parts in the food and plastics processing industry as well as for machinery components. Their typical hardening consists of quenching and (multiple) tempering (Q&T). As many of these steels contain at least smaller amounts of retained austenite (RA) after quenching, partitioning of carbon and nitrogen from the martensite into the RA can take place during tempering, changing it from Q&T to quenching & partitioning (Q&P). This contribution provides as systematic overview of such partitioning effects on the microstructure like the amount and stability of retained austenite as well as on subsequent effects on material properties such as hardness, toughness, strength and ductility. The various effects were investigated on several steel grades and cover also the effect of variation in heat treatment parameters like austenitizing temperature, quench rate, quenching temperature, number, duration and temperature of the tempering, respectively partitioning. The results clearly show that partitioning dominates over tempering effects at temperatures up to 500°C. Higher quenching temperatures can increase the RA-content similar to higher austenitizing temperatures. Lower quench rates can reduce it due to carbide (nitride) precipitation. Rising tempering (partitioning) temperatures up to 400°C enhances the austenite stabilization. Higher amounts of RA with reduced stability promotes transformation induced plasticity (TRIP), providing the possibility to optimized ductility and tensile strength but reduces yield strength. Increased amounts of RA with sufficient stability increases impact toughness at slightly reduced hardness. Increasing the tempering temperature above 500°C in contrast promotes, after a certain nucleation time, carbide and nitride precipitation, resulting in the elimination of the retained austenite and therefore a typical tempering condition.

Quenching and tempering (Q&T) allows a wide range of strength and toughness combinations to be produced in martensitic steels. Tempering is generally done to increase toughness, although embrittling mechanisms result in temperature ranges where strength and toughness may decrease simultaneously. Tempered martensite embrittlement (TME) represents one such mechanism, associated with the decomposition of retained austenite and precipitation of cementite during tempering, usually between 250 and 450 °C. The use of induction heating allows for time-temperature combinations, previously unobtainable by conventional methods, that have been shown to improve properties. The present work shows a beneficial effect of rapid tempering in alloy 1045, with an increase in energy absorption of about 50% when measured at room temperature via a three-point bending fracture test in the TME regime. Phase fraction measurements by Mössbauer spectroscopy showed that increased energy absorption was obtained despite essentially complete decomposition of retained austenite during tempering. Scanning electron microscopy (SEM) investigation of the carbide distribution showed refinement of the average carbide size of approximately 15% in the rapid tempered conditions. SEM characterization of the fracture surfaces of the rapid tempered three-point bend samples showed that, despite an increase in energy absorption in the TME regime, increased microscopic ductile fracture appearance was observed only at the highest test temperature.

Increasing power density and rotational speed pose significant challenges for transmission design, especially in the aerospace and electro mobility sectors. Due to increased energy input and reduced heat dissipation, higher operating temperatures occur in high performance gears. At higher temperatures, the hardness and microstructure of conventional bearing and gear materials are affected by annealing effects, which can reduce the load capacity of these components. Therefore, increased operating temperatures can only be considered if the components are made of special heat-resistant, high-performance material systems. Heat treatment is essential to achieve the required performance. Today, high performance gears are typically case hardened to achieve the best performance in service. Due to the meta-stable properties of martensite and retained austenite, especially for low alloy case hardening steels, the microstructure can degrade in service if the temperature equals or exceeds the previous tempering. As a result, the hardness and performance of the components will decrease. Alternative steel grades with increased alloy content can mitigate but are in most cases more expensive. Therefore, an increase in temperature resistance through heat treatment of the low-alloy steels would be of increased interest. To achieve a more stable microstructure state, new heat treatments and alternative microstructures must be considered. This presentation will address the tempering behavior of martensitic and bainitic microstructures under long-term thermal stress above typical tempering conditions at 210 °C for up to 200 hours. The microstructure degradation and hardness change are shown.

The objective of this work was conducted to investigate the influence of nickel (Ni) content and retained austenite on rolling-sliding contact fatigue (RSCF) life in carburized gear steel. In order to evaluate Ni and retained austenite effects, this study utilized carburized steel specimens of 4120 (0.13 wt pct Ni) and 4820 (3.38 wt pct Ni), which were subjected to RSCF testing. The specimens were gas carburized with a resulting case depth of approximately 1.3 mm, based on a hardness of 500 HV. The retained austenite was measured using x-ray diffraction at depths beneath the surface of 50, 250, 450, 650 μm. The 4120 specimens have a higher surface retained austenite content than the 4820. Specimens were surface ground to an average surface roughness of 0.2 μm to decrease the effect of as-carburized surface roughness on the fatigue life. The specimens underwent RSCF testing, with a surface contact stress of 2.5 GA and a slide to roll ratio of -20 pct, until a pit formed, as detected by an accelerometer. The pits that formed on the surface of the specimens were analysed with secondary electron microscopy, macrophotographs, and light optical microscopy. The pits that formed from the RSCF testing conditions were surface-initiated. The fatigue life of the 4820 specimens was higher than the fatigue life of the 4120 specimens, suggesting that the higher Ni level is beneficial to the fatigue life.

The proposition that compressive residual stresses are beneficial in improving the service life of components subject to rolling contact fatigue is well documented. However, the exact nature of the relationship between effective case depth (ECD) and the residual stress state is not well understood for components with deep case depth (>0.050inches, 1.27mm). It is expected that compressive residual stresses will gradually transition to tensile stresses as the case depth increases beyond a threshold value. In addition, the strain-induced transformation of retained austenite and its influence on the residual stress state of components resulting from service was explored. This study measured the residual stress state of components prepared with various ECD before and after simulated service with the goal of determining where the compressive to tensile transition occurs. Residual stress and retained austenite measurements were conducted using X-ray diffraction.

The influence of microstructure on hydrogen embrittlement of high strength steels for fastener applications is explored in this study. Space limiting applications in areas such as the automotive or agricultural industries provide a need for higher strength fasteners. Albeit, hydrogen embrittlement susceptibility typically increases with strength. Using a 9260 steel alloy, the influence of retained austenite volume fraction in a martensitic matrix was evaluated with microstructures generated via quenching and partitioning. X-ray diffraction and scanning electron microscopy were used to assess the influence of retained austenite in the matrix with different quenching parameters. The quench temperatures varied from 160 °C up to 220 °C, and a constant partitioning temperature of 290 °C was employed for all quench and partitioned conditions. The target hardness for all testing conditions was 52-54 HRC. Slow strain rate tensile testing was conducted with cathodic hydrogen pre-charging that introduced a hydrogen concentration of 1.0-1.5 ppm to evaluate hydrogen embrittlement susceptibility of these various microstructures. The retained austenite volume fraction and carbon content varied with the initial quench temperature. Additionally, the lowest initial quench temperature employed, which had the highest austenite carbon content, had the greatest hydrogen embrittlement resistance for a hydrogen concentration level of 1.0-1.5 ppm.

Press hardening steel (PHS) applications predominately use 22MnB5 AlSi coated in the automotive industry. This material has a limited supply chain. Increasing the tensile strength and bendability of the PHS material will enable light-weighting while maintaining crash protection. In this paper, a novel PHS is introduced, and properties are compared to 22MnB5. The new Coating Free PHS (CFPHS) steel, 25MnCr, has increased carbon, with chromium and silicon additions for oxidation resistance. Its ultimate tensile strength (UTS) of 1.7 GPa with bending angle above 55° at 1.4 mm thickness improves upon the 22MnB5 grade. This steel is not pre-coated, is oxidation resistant at high temperature, thus eliminating the need for AlSi or shot blasting post processing to maintain surface quality. Microstructural mechanisms used to enhance bendability and energy absorption are discussed for the novel steel. Performance evaluations such as: weldability, component level crush and intrusion testing and e-coat adhesion, are conducted on samples from industrial coils.

Low pressure carbonitriding and pressurized gas quenching heat treatments were conducted on four steel alloys. Bending fatigue tests were performed, and the highest endurance limit was attained by 20MnCr5+B, followed by 20MnCr5, SAE 8620+Nb, and SAE 8620. The differences in fatigue endurance limit occurred despite similar case depths and surface hardness between alloys. Low magnitude tensile residual stresses were measured near the surface in all conditions. Additionally, nonmartensitic transformation products (NMTPs) were observed to various extents near the surface. However, there were no differences in retained austenite profiles, and retained austenite was mostly stable against deformation-induced transformation to martensite during fatigue testing, contrasting some studies on carburized steels. The results suggest that the observed difference in fatigue lives is due to differences in chemical composition and prior austenite grain size. Alloys containing B and Nb had refined prior austenite grain sizes compared to their counterparts in each alloy class.

Retained austenite may be helpful or detrimental to the life of heat-treated components, but it can be difficult to accurately measure in manufactured steels. Commonly used visual sample investigations are subjective and often incorrect, magnetic measurements require part-specific calibration, and electron backscattering involves expensive equipment, intensive sample preparation, and long measurement times. Recent developments in X-ray diffractometry, however, provide measurements in minutes and can compensate for the influence of carbides in high-carbon steels as well as texture orientations in rolled sheet metals. This paper discusses the use of X-ray diffraction for measuring retained austenite and compares and contrasts it with other methods. It also provides a brief review of the formation of austenite and its effect on carburized gears, TRIP steels, and bearings.

The notion that compressive residual stresses can extend the service life of components subject to rolling contact fatigue is well documented. However, the exact nature of the relationship between effective case depth and the residual stress state is not well understood for components with case depths greater than 0.050 in. (1.27 mm). It is expected that compressive residual stresses gradually transition to tensile stresses as case depth increases beyond a threshold value. This study will measure the residual stress state of components with different case depths before and after simulated service in order to determine where the compressive to tensile transition occurs. It will also investigate the role of retained austenite and the effect of strain-induced transformation caused by rolling contact. Residual stress and retained austenite measurements will be conducted using X-ray diffraction.

Microstructure refinement strategies for carburized steel were evaluated to assess their effect on the fatigue performance of case carburized components. Commercial 52100 steel samples were subjected to various treatments and analyzed to determine the micro-geometry of plate martensite and the size distribution of retained-austenite regions. Decreasing reheat temperature produced finer austenite grain size, while multiple reheating cycles helped narrow grain size distribution. The refinement of austenite grain size also led to a reduction in martensite plate size and finer distribution of retained austenite.

The present work is the first stage of an ongoing research project concerning with integration of quenching and partitioning heat treatment into the traditional hot stamping process, for 22MnB5 alloy, high Si and high Mn steels, last two proposed for the research with a special chemical composition to enhance Quenching and partitioning (Q&P) process. The above, in order to produce a microstructure containing retained austenite and martensite to improve the ductility of resultant components. The investigations of quenching and partitioning process were made by means of dilatometry and hot stamping plus quenching and partitioning (HS - Q&P) process experiments by a special experimental tool. The resulting microstructure was examined using light optical and scanning electron microscope as X-ray diffraction too. Some results obtained shown that compared with conventional hot stamping samples, the HS-Q&P process improves elongation effectively and maintains high-strength at the same time.

To experimentally investigate the effect of tempering temperature and time on the structure and composition of martensite, AISI 52100 was austenized at 1000°C for 40 minutes and quenched in agitated water at 21°C. The as-quenched steel contained body-centered tetragonal (BCT) martensite with 22% retained austenite. These samples were tempered at 100°C, 200°C, and 300°C with different holding times and then were characterized by x-ray diffraction (XRD) to determine the effect on the structure of the martensite. It was found that the content of retained austenite did not change after tempering at 100°C. Retained austenite decomposed after tempering for 40 minutes at 300°C. The changes in crystal structures and lattice parameters for tempered martensite with different holding times and temperatures were measured. The effect of sample preparation on retained austenite and the structure of martensite and tempered martensite was evaluated. An effective technique for carbide extraction and collection in steel is introduced.

A software simulation tool, CarbonitrideTool, has been developed by Center for Heat Treatment Excellence (CHTE) to predict the Nitrogen and Carbon concentration profiles in selected steels. In this paper, the introduction of the software will be presented. In addition, enhancements have been made to improve the CarbonitrideTool. The diffusion of nitrogen increases the amount of retained Austenite (RA) by changing the Ms temperature. In this paper, the modification has been made to calculate the RA fraction. The empirical prediction of microhardness profile will also be presented. The results of verification experiments will be presented and discussed.

Late research projects show that retained austenite, if stabilized by nitrogen, has a positive influence on the fatigue strength of work pieces. The combined diffusion profile of carbon and nitrogen applied in a carbonitriding process plays the major role, besides the process temperature. Yet today, only the carbon potential is somehow controlled and even this is not easy to achieve. This paper will present a new system able to measure and control both, the carbon potential and the nitrogen potential independently. The knowledge of the activities of nitrogen and carbon in iron and the effect of alloying elements on such activities as well as the solubilities offers an easy to use method to apply the potentials on real steels.

In the last centuries carbonitriding was mainly used to enhance the hardenability of unalloyed steels. IWT developed gas-carbonitriding and low-pressure-carbonitriding processes to increase fatigue behavior and quality compared to case hardening. For example, modern gas-carbonitriding processes make it possible to extend materials ́ strength, so that the limit of use of a given alloy can be expanded. The paper shows examples for the treatment of ball bearing and case hardening steels. The treatment results in microstructures, which are unusual, compared with conventional heat treated parts. They are characterized by high amounts of retained austenite and carbonitride precipitations. By a controlled process, which has been developed in cooperation with PROCESS-ELECTRONIC, it is possible to adjust surface carbon- and nitrogen content independently. Low pressure carburized parts have the advantage that no internal oxidation occurs. So they have the potential of leading to a higher strength. Nowadays LP-carburizing is used in a wide range, whereas LP-carbonitriding processes are at a starting point. In this paper possibilities and limitations of this process are shown. So, inline controlling of LP-processes in a classical way is not possible, but simulation guided process control. The paper will give examples for LP-carbonitriding processes and the resulting microstructure.