Ductility dip cracking (DDC) is a detrimental solid-state cracking phenomenon that can occur during welding of copper-nickel (Cu-Ni) alloys used in naval vessels. The presence of these cracks has several deleterious effects, including reduced fatigue life and increased susceptibility to corrosion. The mechanism of DDC remains highly debated and understudied, especially in material systems outside of Ni-Cr-Fe alloys. The predominant mechanisms that have been proposed include: 1. Grain boundary sliding, 2. Precipitate-induced strain, and 3. Impurity element segregation. In the present body of research, thermal-mechanical testing over a wide range of strain rates and temperatures was performed using a Gleeble 3500. Both flow-stress and fracture morphology of wrought 70/30 Cu- Ni are considered. Following fracture, microstructural analyses using both scanning electron microscopy and optical microscopy were conducted to observe and quantify intergranular cracking and fracture surface features. Results show a strong correlation among fracture morphology, ductility, and temperature.

Decarburization of steel parts during heat treating results in a lower surface hardness, undesirable residual stress profiles, and poor part performance. Significant effort has been made towards preventing decarburization and determining the impact of annealing time and temperature on decarburization rate. Much of the published research has focused on medium carbon steels, ranging from 0.3wt% C to the eutectoid composition. The goal of the current research is to determine decarburization rates for steels with carbon concentrations above the eutectoid concentration. AISI 52100 steel was heated in air for 12, 24, and 36 hours at three temperature ranges (below A 1 , above A cm , and between A 1 and A cm ). Optical microscopy was used to determine the carbon concentration as a function of depth from the surface. The diffusion coefficients of carbon in austenite and ferrite plus cementite phase assemblages were calculated. These diffusion coefficients can be used in a finite difference simulation to predict decarburization at different temperatures and times.

Prof. Tatsuo Inoue passed away on September 23, 2023, at the age of 83. He held a professorship at Kyoto University from 1983 to 2003 and made significant contributions to the theory of heat treatment simulation, which is now widely used. His theory was reported at an international conference in Linkoping, Sweden in 1984. Fundamental equations in his theory cover metallurgical coupling effects caused by changes due to phase transformation, temperature, and inelastic stress/strain as well as carbon diffusion during the carburizing process. Prof. Inoue designated these effects as “metallothermo- mechanical coupling”. Software applying his theory was presented at ASM International’s 1st International Conference on Quenching and the Control of Distortion in 1992, where its advanced nature was recognized. In 1994, Prof. Inoue published a paper on the application of heat treatment simulation to the quenching of Japanese swords, revealing changes in temperature, curving, microstructure, and stress/strain in their model during the traditional quenching process. In 2017, he published “The Science of Japanese Swords” with Sumihira Manabe, a swordsmith, to communicate his specific achievements to the general public.

Determination of flow stress behavior of materials is a critical aspect of understanding and predicting behavior of materials during manufacturing and use. However, accurately capturing the flow stress behavior of a material at different strain rates and temperatures can be challenging. Non-uniform deformation and thermal gradients within the test sample make it difficult to match test results directly to constitutive equations that describe the material behavior. In this study, we have tested AISI 9310 steel using a Gleeble 3500 physical simulator and Digital Image Correlation system to capture transient mechanical properties at elevated temperatures (300°C – 600°C) while controlling strain rate (0.01 s -1 to 0.1 s -1 ). The data presented here illustrate the benefit of capturing non-uniform plastic strain of the test specimens along the sample length, and we characterize the differences between different test modes and the impact of the resulting data that describe the flow stress behavior.

This paper discuss recent developments in mesh belt heat treating systems used in the production of automotive fasteners. Methods for heat treating threaded fasteners have evolved significantly over the last 20 years as low-capacity shaker hearth, rotary hearth, and plate-belt systems are replaced by soft handling mesh belt heat treatment systems. Design innovations for improving the accuracy of tempering furnace tolerance bands and integrating inline zinc phosphate removal systems are discussed along with their respective benefits.

A study on the microstructural evolution of a Ni-base superalloy (Allvac 718plus) was conducted to better understand how solutionizing temperature affects the final microstructure of solutionized and aged test samples. Four different solutionizing temperatures were used to obtain different fractions of gamma prime (γ’) and delta (δ) phase precipitates. This paper describes the solutionizing treatments and presents and analyzes the results of SE-SEM, EBSD, EDS, and XRD testing.

This paper examines the causes of distortion in heat treated 1080 steel parts and the influence of quenchants and quenching temperature. A comparison of parts produced using a different oil and different quench temperatures shows that a significant improvement can be achieved in distortion with only minor grain growth and a slight reduction in hardness.

This work investigates the cooling performance of different salt solutions and quench bath parameters. The results show that increasing quenchant temperature can stabilize the vapor film, while the presence of various additives and the use of agitation can hasten its collapse. Ionic solutions containing NaCl, Na2SO4, NaOH, and NaNO2 were found to inhibit the vapor blanket at 35°C and improve cooling power. Adding salt-forming solutions promoted a more homogeneous cooling with high values of heat flux over most of the cooling cycle.

A variety of test systems have been developed to determine the cooling characteristics of quenchants. Although current test standards specify cylindrical probes for measuring quenchant temperatures and cooling rates, this review concerns the development, implementation, and potential of test systems that use ball probes instead. It assesses the strengths and limitations of different types of ball probes and describes prototype test systems that leverage ball probe capabilities while compensating for inherent weaknesses.

This paper presents the results of a study on the cooling performance of hot oil and molten salt quench media. It describes the tests performed, analyzes the results, and interprets the findings. It explains how the heat extraction mechanism in hot oil differs from that of NaNO2 eutectic mixtures and how it translates to differences in cooling rate, spatial uniformity, and hardness in quenched steel parts.

Blade curving due to quenching in the Japanese sword has been recognized by swordsmiths through the ages. In the late 1920s, Hattori noted that the sword curving is induced from not only martensitic transformation expansion in the near-edge region but also non-uniform elastic and plastic strains distributed in the section, based on his experimental results using cylindrical specimens. Our research for an updated explanation on the subject prepared Japanese sword (JS) type specimens made of the same steel and process as the Japanese sword, and model JS (MJS) type specimens with the almost same shape as the JS type specimens, which were machined from commercial carbon steel and austenite stainless steel bars. All specimens quenched by a swordsmith using the traditional way showed a usual curved shape with different curvatures. Curving, temperature, hardness, metallic structure and residual stress measurements for the specimens were performed to prepare their future simulation works.

The temperature profile in the Heat Affected Zone (HAZ) during induction welding is one of the most important factors determining the weld quality of High-Frequency Induction (HFI) welded steel tubes. In this work, numerical computation of the 3D temperature profile in the steel tube has been done by coupling the electromagnetic model with the thermal model. The high-frequency current and the magnetic fields in the tube, coil and impeder have been evaluated. The resulting power from the induced current is used to evaluate the temperature in the joining edges of the tube. The continuous tube movement has been implemented by considering an additional transport term in the heat equation. The simulations consider non-linear electromagnetic and thermal properties of the steel when it undergoes temperature rise to the welding temperature. The temperature profile from the resulting simulation gives information to control the subsequent process of joining the edges of the steel tube.

Larsen Miller is a formula used to calculate broad equivalent Thermal Effect (TE) stress relieving and tempering recipes. However, results are not precise. The purpose of this work is to determine a more exact procedure. ANOVA design of experiment was used and three supplemental variables were identified as a source of thermal effect variances added to temperature and time: ramp rate, soak time and correlation between Temperature and Soak time. It was then possible to predict the most effective process temperature and soak time necessary to produce the desired stress relief as defined by the angle position of a torsion spring. The results apply to one spring type and one configuration. More work is necessary to expand the methodology to families of parts, i.e. compression springs.

To experimentally investigate the effect of tempering temperature and time on the structure and composition of martensite, AISI 52100 was austenized at 1000°C for 40 minutes and quenched in agitated water at 21°C. The as-quenched steel contained body-centered tetragonal (BCT) martensite with 22% retained austenite. These samples were tempered at 100°C, 200°C, and 300°C with different holding times and then were characterized by x-ray diffraction (XRD) to determine the effect on the structure of the martensite. It was found that the content of retained austenite did not change after tempering at 100°C. Retained austenite decomposed after tempering for 40 minutes at 300°C. The changes in crystal structures and lattice parameters for tempered martensite with different holding times and temperatures were measured. The effect of sample preparation on retained austenite and the structure of martensite and tempered martensite was evaluated. An effective technique for carbide extraction and collection in steel is introduced.

Electric Furnaces have gained major ground in industrial heating, especially, in heat-treating where finer control of temperature is required along with improved efficiency and a reduced environmental impact at the point of use. Furthermore, due to energy costs and “line disturbance” penalties imposed by utility companies, many new power topologies have been developed with careful consideration to performance related to efficiency, power factor, harmonics, and line balance. In this paper we develop a systematic approach to defining power requirements and control approach. We consider a systemic thermo-electric model to specify power requirements, then a cost model to select the appropriate power supply topology. As a summary, a power supply topology is presented which combines the features that allows it to meet or exceed current and future requirements and provide the ability for a higher degree of integration.

In today’s competitive world of globalization and low cost manufacturing, it is essential that when engineering a job, to get it right the first time. This is especially true for capital equipment with a high cost and long expected lifetimes. It is even more critical, when the equipment must operate at high temperatures, and different potential for failure exists. In order to do it right the first time, engineers must understand high temperature properties, and incorporate these principles into the decision making process for materials. Some of these properties are intrinsic, some are affected by environment, and some are governed by thermodynamic and kinetic changes to the material at the operating temperatures. All must be considered.

Temperature Processing Inc. has offered merchant heat treating in the northern NJ town of North Arlington for over 60 years. Their 10,000 sq ft facility, expanded in 1998, offers broad thermal processing capability in a compact plant. Diverse services offered include annealing, tempering, bright hardening, ageing and nitriding.

Plasma nitriding is a thermochemical surface heat treatment of steel components to produce nitride layers which increase wear-, corrosion- and fatigue resistance. Research into plasma nitriding lately showed that there is a significant and characteristic amount of ammonia formed off the process gases nitrogen and hydrogen. This research paper is aimed to analyze the influence of plasma treatment parameters, such as pressure, voltage, temperature and nitrogen to hydrogen ratio on the atmosphere and the formation of ammonia during plasma nitriding. The ammonia content is measured in the exhaust gas. By correlating the measured ammonia with the treatment parameters and modeling the nitriding process, the ammonia content can then be predicted. Further a plasma nitriding potential, comparable to the gas nitriding potential, based on ammonia content is calculated and its practicability as process control parameter is shown by correlating the potential with the nitriding results, e.g. the formation of ε and γ’ nitride phases.

Grain growth during heat treatment can affect mechanical properties. A large grain size can result in a lower strength and susceptibility to brittle failure. In order to control the prior austenite grain size, the effect of Austenitizing temperatures and holding times on the grain size and hardness in 4140 steel was experimentally investigated. Samples were heat treated at 900, 1000, and 1100 °C, and held for 1, 4, and 9 hours. After austenitizing, samples were cooled in the furnace to 850 °C before they were quenched in water at room temperature. Each sample was cut, mounted, and polished. Rockwell hardness and microhardness tests were performed on each sample. A Picric etch was used for grain size analysis. The grain size was measured following the E112 standard test method. It was found that the prior austenite grain size increased with temperature and time according to the standard grain growth model. It was also found that the as-quenched hardness decreased with an increase in grain size.

Energy Savings through Steady State Control Modern heat treat companies are faced with challenges trying to balance work-flow, processing time, and production/energy costs. Unnecessarily long processing times induce extra costs when an automated process cannot tell the true temperature of a load and the engineer must increase soak times to accommodate. These increased soak times use more energy and increase overall production costs. Typically, control or load thermocouples in an oven or furnace only show the wall temperature, and normally only parts of the load. However, the real interest is in what temperature the load actually has reached inside and when is the temperature uniform throughout the whole work piece. Normally, to accommodate for this lack of knowledge in a ramp/soak program, the dwell-time is extended to ensure that the temperature is uniform without truly knowing. Instead, using a method for predicting load uniformity, or Steady State Control, would save time, energy, and, most importantly, money.