Martensitic stainless steels are an important group of steels for applications as knives, tools & molds and highly loaded parts in the food and plastics processing industry as well as for machinery components. Their typical hardening consists of quenching and (multiple) tempering (Q&T). As many of these steels contain at least smaller amounts of retained austenite (RA) after quenching, partitioning of carbon and nitrogen from the martensite into the RA can take place during tempering, changing it from Q&T to quenching & partitioning (Q&P). This contribution provides as systematic overview of such partitioning effects on the microstructure like the amount and stability of retained austenite as well as on subsequent effects on material properties such as hardness, toughness, strength and ductility. The various effects were investigated on several steel grades and cover also the effect of variation in heat treatment parameters like austenitizing temperature, quench rate, quenching temperature, number, duration and temperature of the tempering, respectively partitioning. The results clearly show that partitioning dominates over tempering effects at temperatures up to 500°C. Higher quenching temperatures can increase the RA-content similar to higher austenitizing temperatures. Lower quench rates can reduce it due to carbide (nitride) precipitation. Rising tempering (partitioning) temperatures up to 400°C enhances the austenite stabilization. Higher amounts of RA with reduced stability promotes transformation induced plasticity (TRIP), providing the possibility to optimized ductility and tensile strength but reduces yield strength. Increased amounts of RA with sufficient stability increases impact toughness at slightly reduced hardness. Increasing the tempering temperature above 500°C in contrast promotes, after a certain nucleation time, carbide and nitride precipitation, resulting in the elimination of the retained austenite and therefore a typical tempering condition.

Ductility dip cracking (DDC) is a detrimental solid-state cracking phenomenon that can occur during welding of copper-nickel (Cu-Ni) alloys used in naval vessels. The presence of these cracks has several deleterious effects, including reduced fatigue life and increased susceptibility to corrosion. The mechanism of DDC remains highly debated and understudied, especially in material systems outside of Ni-Cr-Fe alloys. The predominant mechanisms that have been proposed include: 1. Grain boundary sliding, 2. Precipitate-induced strain, and 3. Impurity element segregation. In the present body of research, thermal-mechanical testing over a wide range of strain rates and temperatures was performed using a Gleeble 3500. Both flow-stress and fracture morphology of wrought 70/30 Cu- Ni are considered. Following fracture, microstructural analyses using both scanning electron microscopy and optical microscopy were conducted to observe and quantify intergranular cracking and fracture surface features. Results show a strong correlation among fracture morphology, ductility, and temperature.

Determination of flow stress behavior of materials is a critical aspect of understanding and predicting behavior of materials during manufacturing and use. However, accurately capturing the flow stress behavior of a material at different strain rates and temperatures can be challenging. Non-uniform deformation and thermal gradients within the test sample make it difficult to match test results directly to constitutive equations that describe the material behavior. In this study, we have tested AISI 9310 steel using a Gleeble 3500 physical simulator and Digital Image Correlation system to capture transient mechanical properties at elevated temperatures (300°C – 600°C) while controlling strain rate (0.01 s -1 to 0.1 s -1 ). The data presented here illustrate the benefit of capturing non-uniform plastic strain of the test specimens along the sample length, and we characterize the differences between different test modes and the impact of the resulting data that describe the flow stress behavior.

During forging operations, strain can occur through three primary mechanisms: strain due to load applied through dies, strain due to thermal contraction, and strain due to creep. In materials behavior models, strain due to applied load and thermal contraction are directly considered and predictions are based on thermophysical properties and flow stress behaviors as inputs to the models. Strain due to creep after forging (during cooling) is often more difficult to predict and capture due to lack of materials data. In particular, data that capture the changing flow stress behavior during cooling (rather than from isothermal testing) are not commonly available. In this project, creep strain behavior during cooling was investigated by physical simulations using a Gleeble 3500. Standard cylinder-shaped Ti-6Al-4V samples with 10 mm diameter were heated to below β-transus temperature (1775°F) or above β-transus (1925°F), followed by constant cooling rates of 250°F/min and 1000°F/min with and without applied load during cooling to 1000°F. Total strain for the tests ranged from 2 – 6%. Characterization of prior microstructure and texture was carried out using XRD, optical microscopy, and SEM. The results provide insights on the relationship of flow stress behavior and microstructure as a function of temperature and cooling rate and are applicable to forging practices. These materials data can be used as input for future process modeling, potentially giving better prediction accuracy in industry applications.

In this paper, we study the energy absorption of metamaterials composed of unit cells whose special geometry makes the cross-sectional area and the volume of the bodies generated from them constant (for the same enclosing box dimensions). After a parametric description of such special geometries, we analyzed by finite element analysis the deformation of the metamaterials we have designed during compression. We 3D printed the designed metamaterials from plastic to subject them to real compression. The results of the finite element analysis were compared with the real compaction results. Then, for each test specimen, we plotted its compaction curve. By fitting a polynomial to the compaction curves and integrating it (area under the curve), the energy absorption of the samples can be obtained. As a result of these investigations, we drew a conclusion about the relationship between energy absorption and cell number.

This paper provides an overview of salt quench hardening and how it compares with oil quenching. It explains how salt quenching promotes hardenability, ductility, and strength as well as distortion control, heat extraction, and process reduction. It discusses equipment layout configurations, NFPA guidelines and safety practices, and salt quench processes for austempering, marquenching, and neutral hardening applications.

Blade curving due to quenching in the Japanese sword has been recognized by swordsmiths through the ages. In the late 1920s, Hattori noted that the sword curving is induced from not only martensitic transformation expansion in the near-edge region but also non-uniform elastic and plastic strains distributed in the section, based on his experimental results using cylindrical specimens. Our research for an updated explanation on the subject prepared Japanese sword (JS) type specimens made of the same steel and process as the Japanese sword, and model JS (MJS) type specimens with the almost same shape as the JS type specimens, which were machined from commercial carbon steel and austenite stainless steel bars. All specimens quenched by a swordsmith using the traditional way showed a usual curved shape with different curvatures. Curving, temperature, hardness, metallic structure and residual stress measurements for the specimens were performed to prepare their future simulation works.

Austempered Ductile Cast Iron (ADI) has emerged as an important engineering material in recent years. It has a combination of high strength, good ductility, good fatigue strength and fracture toughness. Because of these excellent properties, it is now extensively used in many structural applications such as automotive components, earth moving machineries etc. An investigation was carried out to develop ADI with a nano scale microstructure. This was achieved by high temperature deformation and subsequent austempering of ductile cast iron. The effect of processing parameters such as deformation temperature, strain rate, austempering temperature and austempering time on microstructural features such as volume fraction of phases, size and distribution of phases were examined.

Quench cracks became a challenge in large serial production of martensitic components. The geometry is simple, and concentrations of stresses from the geometry itself were not indicated by numerical simulation. Grain boundary ferrite is presented in the component surface from where the cracks start. An example from another application is interesting to consider; titanium grade 5. Grain boundary alpha on prior beta grain boundaries is not accepted for aerospace applications. The volume for plastic deformation in the phases along the grain boundaries is restricted. The ductile part of the fracture indicates forces from unbalanced quenching and elevated temperature at time of crack start. The general focus for improvement will be overcritical surface temperature, vapor phase break and mix of turbulent/lamellar flow. More effective quenching around the whole component is, in this case, assumed to be better than slower quenching.

This article addresses an investigation of the influence of plastic deformation on low-temperature surface hardening by gaseous nitriding of three commercial austenitic stainless steels: AISI 304, EN 1.4369 and Sandvik Nanoflex with various degrees of austenite stability. The materials were plastically deformed to different equivalent strains by uniaxial tension. Gaseous nitriding of the strained material was performed in ammonia at atmospheric pressure in the temperature range 693-703 K (420-430°C). Microstructural characterization of the as-deformed states and the nitrided case included X-ray diffraction analysis, reflected light microscopy and microhardness indentation. The results demonstrate that a case of expanded austenite develops and that, in particular, the presence of strain-induced martensite in the initial (deformed) microstructure has a large influence on the nitrided zone.