Nitriding surface hardening is commonly used on steel components for high wear, fatigue and corrosion applications. Case hardening results from white layer formation and coherent alloy nitride precipitates in the diffusion zone. This paper evaluates the microstructure development in the nitrided case and its effects on the hardness in both the white layer and the substrate for two industry nitriding materials, Nitralloy 135M and AISI 4140. Computational thermodynamic calculations were used to identify the type and amount of stable alloy nitrides precipitation and helped explain the differences in the white layer hardness, degree of porosity at the surface, and the hardening effect within the substrate. Some initial insights toward designing nitriding alloys are shown.

The influence of microstructure on hydrogen embrittlement of high strength steels for fastener applications is explored in this study. Space limiting applications in areas such as the automotive or agricultural industries provide a need for higher strength fasteners. Albeit, hydrogen embrittlement susceptibility typically increases with strength. Using a 9260 steel alloy, the influence of retained austenite volume fraction in a martensitic matrix was evaluated with microstructures generated via quenching and partitioning. X-ray diffraction and scanning electron microscopy were used to assess the influence of retained austenite in the matrix with different quenching parameters. The quench temperatures varied from 160 °C up to 220 °C, and a constant partitioning temperature of 290 °C was employed for all quench and partitioned conditions. The target hardness for all testing conditions was 52-54 HRC. Slow strain rate tensile testing was conducted with cathodic hydrogen pre-charging that introduced a hydrogen concentration of 1.0-1.5 ppm to evaluate hydrogen embrittlement susceptibility of these various microstructures. The retained austenite volume fraction and carbon content varied with the initial quench temperature. Additionally, the lowest initial quench temperature employed, which had the highest austenite carbon content, had the greatest hydrogen embrittlement resistance for a hydrogen concentration level of 1.0-1.5 ppm.

Press hardening steel (PHS) applications predominately use 22MnB5 AlSi coated in the automotive industry. This material has a limited supply chain. Increasing the tensile strength and bendability of the PHS material will enable light-weighting while maintaining crash protection. In this paper, a novel PHS is introduced, and properties are compared to 22MnB5. The new Coating Free PHS (CFPHS) steel, 25MnCr, has increased carbon, with chromium and silicon additions for oxidation resistance. Its ultimate tensile strength (UTS) of 1.7 GPa with bending angle above 55° at 1.4 mm thickness improves upon the 22MnB5 grade. This steel is not pre-coated, is oxidation resistant at high temperature, thus eliminating the need for AlSi or shot blasting post processing to maintain surface quality. Microstructural mechanisms used to enhance bendability and energy absorption are discussed for the novel steel. Performance evaluations such as: weldability, component level crush and intrusion testing and e-coat adhesion, are conducted on samples from industrial coils.

Low pressure carbonitriding and pressurized gas quenching heat treatments were conducted on four steel alloys. Bending fatigue tests were performed, and the highest endurance limit was attained by 20MnCr5+B, followed by 20MnCr5, SAE 8620+Nb, and SAE 8620. The differences in fatigue endurance limit occurred despite similar case depths and surface hardness between alloys. Low magnitude tensile residual stresses were measured near the surface in all conditions. Additionally, nonmartensitic transformation products (NMTPs) were observed to various extents near the surface. However, there were no differences in retained austenite profiles, and retained austenite was mostly stable against deformation-induced transformation to martensite during fatigue testing, contrasting some studies on carburized steels. The results suggest that the observed difference in fatigue lives is due to differences in chemical composition and prior austenite grain size. Alloys containing B and Nb had refined prior austenite grain sizes compared to their counterparts in each alloy class.

Determination of flow stress behavior of materials is a critical aspect of understanding and predicting behavior of materials during manufacturing and use. However, accurately capturing the flow stress behavior of a material at different strain rates and temperatures can be challenging. Non-uniform deformation and thermal gradients within the test sample make it difficult to match test results directly to constitutive equations that describe the material behavior. In this study, we have tested AISI 9310 steel using a Gleeble 3500 physical simulator and Digital Image Correlation system to capture transient mechanical properties at elevated temperatures (300°C – 600°C) while controlling strain rate (0.01 s -1 to 0.1 s -1 ). The data presented here illustrate the benefit of capturing non-uniform plastic strain of the test specimens along the sample length, and we characterize the differences between different test modes and the impact of the resulting data that describe the flow stress behavior.

Vacuum carburizing 9310 gear steel followed by austenitizing, oil quench, cryogenic treatment, and tempering is known to impact the residual stress state of the material. Residual stress magnitude and depth distribution can have adverse effects on part distortion during intermediary and finish machining steps. This study provides residual stress measurement, microstructural, and mechanical property data for test samples undergoing a specific heat treat sequence. Test rings of 9310 steel are subjected to a representative gear manufacturing sequence that includes normalizing, rough machining, vacuum carburizing to 0.03”, austenitizing, quench, cryo-treatment, temper, and finish machining. The rings along with metallurgical samples are characterized after each step in order to track residual stress and microstructural changes. The results presented here are particularly interesting because the highest compressive residual stresses appear after removal of copper masking, not after quenching as expected. Data can be used for future ICME models of the heat treat and subsequent machining steps. Analytical methods employed include X-ray diffraction, optical and electron microscopy, and hardness testing.

The work presented in this paper addresses a data gap that continues to be a hinderance to users of precipitation modeling tools, particularly those based on Langer-Schwartz theory. Thermodynamic and kinetic data required for precipitation models can be obtained from CALPHAD databases, but interfacial energies between the bulk and precipitate phases are not available for many alloy systems. In this work, a number of matrix-precipitate interfacial energies have been determined for influential precipitates in alloys of industrial importance, for example, carbides in Grade 22 low-alloy steels, delta phase in Ni 625 and 718, S-phase in Al 2024, and Q’ and β’’ in Al 6111.

Plain carbon steel cylinders were heat treated and quenched in order to study the effects of heat treating on residual stresses and microstructure. Residual stress measurements were obtained via X-ray diffraction using the sin 2 Ψ method and microstructure was characterized based on the associated peak widths. Measurements were made both at the surface and through depth following electropolishing. Triaxial stress gradients were observed in all test samples with concomitant varying microstructural characteristics. The method used to measure residual stresses in this study is typical and recommended for general practice.

As a novel manufacturing technology additive manufacturing (AM) has advantages such as energy saving, reduced material waste, faster design-to-build time, design optimization, reduction in manufacturing steps, and product customization compared to conventional manufacturing processes. Heat treatment is widely used to improve the properties of conventional manufactured steel parts. The response of additively manufactured steel parts to heat treatment may be different from conventionally manufactured steel parts due to variations in microstructure. An understanding of heat treatment processes for additively manufactured steel parts is necessary to develop their heat treatment process parameters. In the present work 20MnCr5 steel was selected to investigate the carburization heat treatment of additively manufactured parts. These parts were fabricated by selective laser melting (SLM) for the carburization study. It was found that the AM parts fabricated by the SLM process show the microstructure of tempered martensite while the microstructure of as-received wrought part is ferrite and pearlite. It was also experimentally found that the SLM process decarburizes the entire SLM part. Before carburizing, a normalization process was conducted on both SLM and wrought 20MnCr5 parts to reduce the effect of the pre-carburizing microstructure. The objective of this project is to determine the carburization performance of additively manufactured steel parts. The results for the SLM parts in terms of carbon concentration and microhardness profiles are compared with the results for the wrought steel. It was found that the carburized SLM part in the present work has higher carbon concentration near the surface, deeper case depth, and higher total carbon flux than the carburized wrought part.

Large slewing bearings are employed in wind turbines and other energy industry applications where they are subjected to harsh working conditions. In order to bear heavy dynamic loads, slewing ring tracks can be surface hardened by induction heating with a seamless process which allows for a uniform heat treatment without soft zones. In comparison with the traditional furnace carburizing, seamless induction hardening is faster, consumes less energy, and has been developed to achieve the same results utilizing medium carbon steel. The presence of a pre-heating coil, with an independent power source, allows for the adjustment of the heat input rate in order to tune the heating process according to the steel characteristics. The pre-heating operation allows for case depths up to 10 mm to be reached without a reduction in scanning speed or productivity. A mechanical tracking system adjusts the coils to compensate for ring deformation and thus assure a uniform heating pattern. Surface hardness tests and metallography have been performed in different process stages to verify the process consistency. A fine grain microstructure in the end zone has been obtained thanks to the pre-heating coil, which avoids surface overheating.

Modeling of as-tempered hardness in steel is essential to understanding final properties of heat-treated components. Most of the tempering mathematical models derive a tempering parameter using Hollomon-Jaffe formulation. Some recent models incorporate chemical composition into the general Hollomon-Jaffe relationship. This paper compares model predictions with a substantial set of actual tempered Jominy End Quench bars and the hardness data from them. Improvements to the models and direction for future work are discussed.

Vacuum carburizing with high pressure gas quenching is increasingly employed to reduce near-surface intergranular oxidation and quenching distortion. It has also been shown to reduce processing times because it can be conducted at higher temperatures, up to 1100 °C. These temperatures, however, may cause austenite grain coarsening, making steel more susceptible to fatigue failure. This paper presents a study showing how microalloying carburizing steels with Mo and Nb improves resistance to austenite grain growth. The control of grain size is attributed to solute and precipitation effects.

The Lehrer diagram often serves as a guide for selecting gas mixtures for nitriding alloy steels, but it is only accurate for ammonia gas nitriding processes when hydrogen is used as the diluting gas. This paper presents the results of a study showing that the use of pure nitrogen as a diluent has a marked effect on the phase boundary lines of the standard Lehrer diagram, essentially shifting them to the left. The paper also includes examples showing where the use of nitrogen is advantageous and where it is not.

Low pressure carbonitriding (LPCN) has the potential to improve the impact and fatigue strength of steel components through the enrichment of nitrogen and the effect of carburizing at higher temperatures. The work described in this paper investigates the influence of boron on the LPCN response of 20MnCr5 steel and the effect of niobium on that of 8620. LPCN treatments were developed to achieve a surface hardness of ~700 HV and case depth of 0.65-0.75 mm in four alloys: 20MnCr5, 20MnCr5 + B, 8620, and 8620 + Nb. The hardness and case microstructure of treated and quenched test samples are correlated with bending fatigue measured in Brugger fatigue specimens, which simulate the root of a gear tooth.

This paper reviews recent advances in the control of plasma ion nitriding processes and their effect on AR500 and 4140 steel and ductile and gray iron. The advanced discussed are primarily in the area of electrical power and gas flow control.

Controlled nitriding and ferritic nitrocarburizing can significantly improve the corrosion and wear resistance of carbon and low-alloy steels. The framework for maintaining these processes is based on standards, such as AMS 2759/10 and 2759/12A, that specify tolerances for control parameters. This work investigates the impact of admissible deviations in control parameters on the performance of treated alloy samples. The findings of the study demonstrate that although tolerances are allowed, precise control in specific furnace classes is necessary to consistently obtain superior results.

This paper evaluates the influence of niobium additions on the wear behavior of high-silicon steel, representative of the advanced high strength steels used in the automotive industry. It describes the alloy compositions of the test samples used, the heat treatments to which they were subjected, and the tests that were subsequently performed. It also interprets test results and outlines key findings.

Press quenching is often used to harden parts that are sensitive to distortion, but it is a difficult process to control due to the effects of tooling and the relatively large number of process parameters. In this paper, the authors show how they use finite element analysis to optimize the process and tooling design for a spiral bevel gear made of carburized 9310 steel. Several designs adaptations are assessed, one of which is shown to minimize radial shrinkage and taper distortion in the inner diameter of the bore.

Samples from forged and heat-treated steel products with known quench crack histories have been mapped in order to study a possible relation between banding segregation and quench cracking. The products were medium carbon low alloy steels produced by ingot and continuous casting. EDS X-ray mapping was used to characterize the banding pattern and tensile testing revealed corresponding properties. The experimental procedures are described in the paper along with test results and conclusions.