This paper will present the advantages and disadvantages of quenching media options like HPGQ (high pressure gas quenching), Oil and Press Quenching, Austempering (salt) for steel, ADI (austempered ductile iron) and aluminum to achieve certain targets relating to automotive component heat treating. Each heat treating/quenching process provides unique solutions for automobile designers and plant engineers. However, there likely is no single process or material that provides all of the answers that one would desire. Therefore, what process or combination of processes will satisfy the overall need? Detail will be discussed that outlines how OEM’s and heat treaters can and do take advantage of a particular hardening process.

In the present study unalloyed spheroidal graphite iron was compared with a sample alloyed with copper and nickel (Cu- Ni). Samples of those materials were treated in salt bath (a composite of sodium borate, aluminum, iron-niobium and/or iron-vanadium) at 1000 °C for 2 hours. This resulted in layers of niobium carbide (NbC), vanadium carbide (VC) and ternary carbide of niobium and vanadium (NbVC2). Characterization of these layers was obtained by optical microscopy, X-ray diffraction and microhardness Vickers. The microhardness and the thickness results were statistically analyzed by the two factors variance analysis method. The efficiency of the layered surface in increasing corrosion resistance was demonstrated by submitting it to potentiodynamic polarization corrosion tests.

Austempering heat treatments of steels and cast irons are usually performed using salt bath quenching followed by isothermal transformation of austenite to bainite or ausferrite. High Pressure Gas Quenching (HPGQ) at 1-4 MPa gas pressures is increasingly used to replace oil quenching, but may also be used for austempering. However, to obtain sufficient heat transfer high gas speeds >25 m/s are required. Hot Isostatic Pressing (HIP) is widely used for densifying castings and powder-based materials. Recent equipment developments enable Uniform Rapid Quenching (URQ) under 200 MPa pressure and 0.3 m/s speed, providing uniform cooling. Superplastic conditions during austenitization and initially during URQ reduce residual stresses and eliminate internal porosity in castings and PM materials. Hardenability is increased due to stabilization of the close-packed austenite. The inherent freedom provided by HIP to select optimum levels and rates for temperatures and pressures has been shown to improve mechanical properties and reduce process duration.

Austempered Ductile Cast Iron (ADI) has emerged as an important engineering material in recent years. It has a combination of high strength, good ductility, good fatigue strength and fracture toughness. Because of these excellent properties, it is now extensively used in many structural applications such as automotive components, earth moving machineries etc. An investigation was carried out to develop ADI with a nano scale microstructure. This was achieved by high temperature deformation and subsequent austempering of ductile cast iron. The effect of processing parameters such as deformation temperature, strain rate, austempering temperature and austempering time on microstructural features such as volume fraction of phases, size and distribution of phases were examined.

Ductile cast iron can be heat-treated to obtain a significant property improvement austempering, resulting in Austempered Ductile Iron (ADI). Performance can be further improved by using boronized surface layers which are capable of reaching high hardnesses (2100 HV). In this work, samples of nodular cast iron alloyed with copper, copper-nickel and copper-nickel molybdenum were borided in a salt bath (borax + aluminum) at temperatures 850, 900 and 950 °C for 2 and 4 hours. After these treatments, the samples were directly austempered from the boriding temperature in salt baths at temperatures of 240, 300 and 360°C (boroaustempering) which avoided the need for a subsequent reheating for such processing. The boriding treatment produced uniform layers with thicknesses in the range 35-130 micrometers and hardness in the range from 1300 to 1700 HV.

Boriding thermochemical treatment produces layers with high hardness which improves the tribological performance of ductile cast iron while the austempering treatment improves the mechanical performance of the substrate. In this work, samples of the ductile cast iron alloyed with copper, copper-nickel and copper-nickel-molybdenum were borided in a salt bath (borax + aluminum) at temperatures of 850, 900 and 950°C during 2 and 4 hours. The data for the layers obtained were used to determine the diffusion coefficients and activation energies of this process. The results of the calculated diffusion coefficients were similar to those obtained by the direct measurements of the layer thicknesses. For the sample alloyed with Cu or Cu-Ni the activation energy obtained was 141.27 kJ/mol, and for the sample alloyed with Cu-Ni-Mo the value was 212.98 kJ/mol. The statistical parameters and the correlation coefficients (R) showed satisfactory agreement.

An investigation was carried out to examine the influence of cryogenic processing on the microstructure and mechanical properties of Austempered Ductile Cast Iron (ADI). ADI has emerged as a major engineering material in recent years because of its many attractive properties. These include high yield strength with good ductility, good fatigue strength, fracture toughness and wear resistance. In this investigation, compact tension and cylindrical tensile specimens were prepared from ductile cast iron as per ASTM standards and were austempered at a lower bainitic temperature of 288°C (550°F). These specimens were then cryogenically processed. The mechanical properties and fracture toughness of these samples were evaluated and compared with the noncryogenically treated samples. The influence of cryogenic heat treatment on the microstructure of these samples was also examined. Test results show that the cryogenic processing can improve the mechanical properties without compromising the fracture resistance of the material.

Austempered irons and steels offer the design engineer alternatives to conventional material/process combinations. Depending on the material and the application, Austempering may provide the following benefits to producers of powertrain components like gears and shafts: ease of manufacturing, increased bending and/or contact fatigue strength, better wear resistance and enhanced dampening characteristics resulting in lower noise. Austempered materials have been used to improve the performance of powertrain components in numerous applications for a wide range of industries, from gears and shafts to clutch plates and crankshafts. This paper focuses on Austempered solutions for powertrain applications with an emphasis on gear and shaft solutions.