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zone refining
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Published: 01 December 2004
Fig. 21 Normal grain growth in zone-refined iron during isothermal anneals. Closed circles represent specimens for which statistical analysis of grain-size and grain-shape distributions was conducted.
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Image
Published: 01 December 2004
Fig. 22 Grain-size distribution in zone-refined iron during isothermal grain growth at 650 °C (923 K), using a scalar-adjusted grain diameter for each specimen. The plot indicates that the grain-size distribution remains essentially unchanged during normal grain growth.
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Image
Published: 01 December 2004
Fig. 23 Grain-shape distribution in zone-refined iron during isothermal grain growth at 650 °C (923 K), using the number of sides of individual grains. The plot indicates that the grain-shape distribution remains essentially unchanged during normal grain growth.
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Image
Published: 01 December 2004
Fig. 24 Zone-refined iron, cold rolled to a moderate reduction and annealed for recrystallization for several cycles to refine the penultimate grain size without introducing preferred orientation. Micrograph shows grain structure after normal grain growth at 800 °C (1470 °F) for 12 min. 2
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Image
Published: 01 January 2005
Fig. 23 Normal grain growth in zone-refined iron during isothermal anneals. Closed circles represent specimens for which statistical analysis of grain-size and grain-shape distributions was conducted.
More
Image
Published: 01 January 2005
Fig. 24 Grain-size distribution in zone-refined iron during isothermal grain growth at 650 °C (923 K), using a scalar-adjusted grain diameter for each specimen. The plot indicates that the grain-size distribution remains essentially unchanged during normal grain growth.
More
Image
Published: 01 January 2005
Fig. 25 Grain-shape distribution in zone-refined iron during isothermal grain growth at 650 °C (923 K), using the number of sides of individual grains. The plot indicates that the grain-shape distribution remains essentially unchanged during normal grain growth.
More
Image
Published: 01 January 2005
Fig. 26 Zone-refined iron, cold rolled to a moderate reduction and annealed for recrystallization for several cycles to refine the penultimate grain size without introducing preferred orientation. Micrograph shows grain structure after normal grain growth at 800 °C (1470 °F) for 12 min. 2
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Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001115
EISBN: 978-1-62708-162-7
... used methods for ultrapurification of metals produced by electrolytic processes, including fractional crystallization, zone refining, vacuum melting, distillation, chemical vapor deposition, and solid state refining techniques. In addition, it describes the trace element analysis and resistance-ratio...
Abstract
The electronic microcircuit industry has placed severe demands on metal suppliers to provide metals of the highest reproducible purity attainable as a result of the constant quest for the true values of physical and chemical properties of metals. This article describes the commonly used methods for ultrapurification of metals produced by electrolytic processes, including fractional crystallization, zone refining, vacuum melting, distillation, chemical vapor deposition, and solid state refining techniques. In addition, it describes the trace element analysis and resistance-ratio test methods used to characterize purity. Tables list the values for resistance ratios of zone-refined metals and their corresponding chemical compositions, and provide an example of the detection of impurities to concentrations in the parts per billion range, utilizing a combination of the glow discharge mass spectroscopy method and Leco combustion methods.
Book Chapter
Series: ASM Handbook
Volume: 4C
Publisher: ASM International
Published: 09 June 2014
DOI: 10.31399/asm.hb.v04c.a0005834
EISBN: 978-1-62708-167-2
..., heat treating, melting, joining (welding, brazing/soldering, and shrink fitting), coating, paint curing, adhesive bonding, and zone refining of semiconductors. The article also discusses the advantages of induction heating. coating electromagnetic induction induction coil induction hardening...
Abstract
Electromagnetic induction is a way to heat electrically conductive materials such as metals. This article provides a brief history of electromagnetic induction and the development of induction heating technology. It explores various applications such as heating prior to metalworking, heat treating, melting, joining (welding, brazing/soldering, and shrink fitting), coating, paint curing, adhesive bonding, and zone refining of semiconductors. The article also discusses the advantages of induction heating.
Image
Published: 01 December 2009
Fig. 3 Log [ln 1/(1 – X )] plotted as a function of the logarithm of the annealing time at various temperatures in zone-refined aluminum containing 0.004% Cu cold rolled to 40% reduction at 0 °C. Source: Ref 13
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Image
Published: 01 November 2010
Fig. 35 Rate of boundary migration versus misorientation angle. (a) head at 300 °C (top) and 200 °C (bottom). (b) Measured activation energies versus misorientation angle for <100> tilt boundaries in zone-refined, lead. Source: Ref 91
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in Properties of Pure Metals
> Properties and Selection: Nonferrous Alloys and Special-Purpose Materials
Published: 01 January 1990
Fig. 45 Temperature dependence of the tensile yield stress of iron. (a) Stress at 0.1% strain. (b) Stress at 0.5% strain. The solid and open circles represent samples zone refined to residual resistivity ratio values of 3600 and >5000, respectively. Data from three other investigations
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Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003743
EISBN: 978-1-62708-177-1
... are plotted on a logarithmic scale, a straight line is drawn, with K as the intercept and n as the slope of the curve. The value of n , the time exponent in isothermal grain growth, is usually 0.5 or less. A typical example for isothermal grain growth in zone-refined iron is shown in Fig. 21...
Abstract
Recovery, recrystallization, and grain growth are the stages that a cold worked metal undergoes when it is annealed. This article describes the changes in the structure and properties that occur on annealing a cold-worked metal. It summarizes the experimental recrystallization studies by Burke and Turnbull with six laws of recrystallization. Applications of these laws of recrystallization are discussed in detail with examples. The article reviews the classification of grain growth according to the growth behavior of grains, namely, normal or continuous grain growth and abnormal or discontinuous grain growth. The latter has also been termed exaggerated grain growth, coarsening, or secondary recrystallization.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001090
EISBN: 978-1-62708-162-7
... 760 °C (1400 °F) to germanium metal powder, which is subsequently melted and cast into so-called first-reduction, or as-reduced, bars. These bars are then subjected to zone refining to produce intrinsic or electronic-grade germanium metal. Zone refining is ideally suited for the refining of germanium...
Abstract
Germanium is a semiconducting metalloid element found in Group IV A. Germanium is used in the field of electronics, infrared optics, and in the fields of gamma ray spectroscopy, catalysis, and fiber optics. This article discusses the sources, manufacturing, and processing of germanium, and focuses on the chemical properties of various germanium compounds, including germanium halides, germanates, germanides, germanes, inorganic, and organogermanium compounds. It also tabulates the physical, thermal, electronic, and optical properties of germanium, and explains the economical aspects and specifications of germanium. The article describes the analytical and test methods of germanium, including gravimetric method, titrimetric method, and spectral method. It provides a short note on toxicology, and concludes with the uses of germanium in different fields.
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0004019
EISBN: 978-1-62708-185-6
... in isothermal grain growth, is usually less than or, at most, equal to 0.5. A typical example for isothermal grain growth in zone-refined iron is shown in Fig. 23 . The deviation from a straight-line relationship for very short annealing times at low temperatures is due to recrystallization, and that for long...
Abstract
Recovery, recrystallization, and grain growth are microstructural changes that occur during annealing after cold plastic deformation and/or during hot working of metals. This article reviews the structure of the deformed state and describes the changes in the properties and microstructures of a cold-worked metal during recovery stage. It discusses the recrystallization that occurs by the nucleation and growth of grains. The article also reviews the growth behavior of the grains, explaining that the grain growth can be classified into two types: normal or continuous grain growth and abnormal or discontinuous grain growth. It also examines the key mechanisms that control microstructure evolution during hot working and subsequent heat treatment. These include dynamic recovery, dynamic recrystallization, metadynamic recrystallization, static recovery, static recrystallization, and grain growth.
Image
Published: 01 June 2024
Fig. 39 Overload fracture of an induction-hardened part. Fracture in the induction-hardened zone is dull compared to the core fracture zone, due to grain refinement during induction hardening. Fracture in the induction zone is intergranular. Fracture in the core is cleavage. Both mechanisms
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