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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001326
EISBN: 978-1-62708-170-2
... parameters for wipe solvent cleaners, including methyl ethyl ketone, methyl isobutyl ketone, trichloroethene, tetrachloroethylene, acetone, toluene, dichloromethane, benzene, xylene, and other alternate wipe solvent cleaners. It contains a table that lists the compositions and properties of wipe solvent...
Abstract
Wipe solvents are used to remove contaminants from a workpiece before it undergoes manufacturing operations that require clean surfaces, such as bonding, sealing, painting, welding, plating, specialized surface treatment procedures, and others. This article describes the evaluation parameters for wipe solvent cleaners, including methyl ethyl ketone, methyl isobutyl ketone, trichloroethene, tetrachloroethylene, acetone, toluene, dichloromethane, benzene, xylene, and other alternate wipe solvent cleaners. It contains a table that lists the compositions and properties of wipe solvent cleaners.
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Published: 01 January 1993
with acrylic resin and xylene thinner; powder-to-vehicle ratio, 70/30
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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001321
EISBN: 978-1-62708-170-2
...) 1330207 Xylenes (isomers and mixture) 95476 o-Xylenes 108383 m-Xylenes 106423 p-Xylenes 0 Antimony compounds 0 Arsenic compounds (inorganic including arsine) 0 Beryllium compounds 0 Cadmium compounds 0 Chromium compounds 0 Cobalt compounds 0 Coke oven emissions...
Abstract
This article describes selected U.S. environmental statutes and regulations that are pertinent to material surface finishers. It provides information on the applicability, requirements, and permitting conditions of the Clean Air Act, the Resources Conservation and Recovery Act, the Superfund Amendments and Reauthorization Act, and the Clean Water Act.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006041
EISBN: 978-1-62708-172-6
... 2 Percent solids and viscosity of fluoroethylene vinyl ether high-molecular-weight resin in various solvents Solvent Solids, wt% Brookfield viscosity, cP Xylene 49.5 630 t-butyl acetate 50.2 869 Acetone 50 250 Oxsol 100 (a) 48.6 6632 Methyl acetate 51.8 333...
Abstract
This article provides background information on the chemistry, coating properties, resin types, applications techniques, and performance characteristics of fluoroethylene vinyl ether (FEVE) resins. It describes the formulation methods of FEVE resins, namely, solvent-based coating formulations, water-based coating formulations, and powder coating formulations. The basic concerns to be addressed when formulating and using FEVE coatings are also discussed. The article concludes with a section on health and related safety regulations.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006071
EISBN: 978-1-62708-172-6
... with the early alkyd paints. The primary environmental concern was with the organic solvents used in formulating the product. Numerous solvents are used in alkyd coatings, including mineral spirits, toluene, xylene, and m distillates. The evaporation of these solvents, in both the alkyd resin production and end...
Abstract
An alkyd is an ester-based polymer derived from the polycondensation reaction of polyhydric alcohol and polybasic acid. This article provides useful information on the chemistry, production, coating formulations, modification, commercial products, and application methods of alkyd resins. It also provides a section on drying oil, which is used in the manufacture of resins. The article describes the three categories of metals that have been used in drier compounds: primary driers (active or oxidation driers), secondary driers (through-driers), and auxiliary driers. It also provides information on the oil length of an alkyd resin and on solvents, which play a critical role in the formulation and use of the coating. The article concludes with a description of the concerns that a user, specifier, or applicator should be aware of when using alkyd coatings.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003655
EISBN: 978-1-62708-182-5
... containing 15% hydrochloric acid combined with 13% xylene. Figure 4 shows the raw electrochemical current and 1/ R SLPR (analyzed by the SLPR method presented earlier, Ref 14 ) from the probe in the flow line just before and just after the line was “pigged.” The data indicates that fluctuations...
Abstract
Corrosion monitoring is important in the operation of modern industrial plants and in the use and maintenance of expensive assets such as bridges and aircrafts, because the damage caused by corrosion and the rate of the deterioration can be huge and the risks devastating. This article discusses the system considerations and installation techniques of different types of direct and indirect techniques in electrochemically based on-line corrosion monitoring process. It describes the importance of probe location and on-line corrosion monitoring techniques with examples.
Book: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005756
EISBN: 978-1-62708-171-9
Abstract
This article provides information on personal protective equipment (PPE), consistent with the Occupational Safety and Health Administration's Personal Protective Equipment Standard (29 CFR 1910.132-138). This standard is intended to protect individuals from the risk of injury by creating a barrier against workplace hazards. This article provides guidelines for establishing PPE programs with an overview of the responsibilities for employers, supervisors, and employees, assessing hazards associated with thermal spray operations, and training workers about PPE, as well as guidelines for selecting, using, and maintaining PPE. It presents an overview of eye, face, head, hand, foot, hearing, fall, and respiratory protection. Respiratory and hearing protection should be used in conjunction with industrial hygiene monitoring.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004143
EISBN: 978-1-62708-184-9
... with the insoluble manganese dioxide formed during the first stage of cleaning. Organic Solvents Organic solvents used to dissolve organic deposits include kerosene, xylene, toluene, xylene bottoms, heavy aromatic naphtha, 1,1,1-trichloroethane, N -methyl-2-pyrrolidone, alcohols, glycols, and ortho...
Abstract
This article describes the eight chemical cleaning methods, namely, circulation, fill and soak, cascade, foam, vapor-phase organic, steam-injected, on-line chemical, and mechanical cleaning. It presents information on deposit types, solvents used to remove them, and construction material incompatibilities in a table. The article summarizes the uses of chemical cleaning solutions, including hydrochloric acid, phosphoric acid, and sulfamic acid, as well as the additives used to neutralize their impact on corrosion. It discusses the chemical cleaning procedures, including selection of cleaning method and solvent, documentation of cleaning, and corrosion monitoring in chemical cleaning.
Book: Fractography
Series: ASM Handbook Archive
Volume: 12
Publisher: ASM International
Published: 01 January 1987
DOI: 10.31399/asm.hb.v12.a0001832
EISBN: 978-1-62708-181-8
...-stripping cleaning technique. Organic Solvents Organic solvents, such as xylene, naphtha, toluene, freon TF, ketones, and alcohols, are primarily used to remove grease, oil, protective surface coatings, and crack-detecting fluids from the fracture surface. It is important to avoid use...
Abstract
Fracture surfaces are fragile and subject to mechanical and environmental damage that can destroy microstructural features. This article discusses the importance of care and handling of fractures and the factors that need to be considered during the preliminary visual examination. It describes the procedures for sectioning a fracture and opening secondary cracks as well as the effect of nondestructive inspection on subsequent evaluation. The article provides information on the most common techniques for cleaning fracture surfaces. These techniques are dry air blast cleaning, replica stripping, organic-solvent cleaning, water-base detergent cleaning, cathodic cleaning, and chemical-etch cleaning.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003002
EISBN: 978-1-62708-200-6
... Alcohols Ethanol, cyclohexanol A A B A A A A A A A A A A A A A B Aldehydes Acetaldehyde, formaldehyde A A A A B B A A … C B … A … A B A Amines Aniline, triethanolamine … … … … … … C B … C C … A … A B B Aromatic hydrocarbons Toluene, xylene...
Abstract
This article is a comprehensive collection of engineering tables providing information on the mechanical properties of and the techniques for processing and characterizing polymeric materials, such as thermosets, thermoset-matrix unidirectional advanced composites, and unreinforced and carbon-and glass-reinforced engineering thermoplastics. Values are also provided for chemical resistance ratings for selected plastics and metals, and hardness of selected elastomers.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003695
EISBN: 978-1-62708-182-5
.... Polar and aromatic solvents attack NBR. It should not be used with such aromatic solvents as benzene, toluene, or xylene. Nitrile rubber is less permeable to gases than is NR or styrene-butadiene rubber. However, it exhibits significantly improved heat and aging resistance to a level of 93 °C (200 °F...
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006926
EISBN: 978-1-62708-395-9
... more aggressive if the detergent concentration is beyond its critical micelle concentration. This is probably because the detergent molecules are not aggregated below the critical micelle concentration. The addition of swelling agents to the water solution (such as xylene, which locates itself...
Abstract
The susceptibility of plastics to environmental failure, when exposed to organic chemicals, can limit their use in many applications. A combination of chemical and physical factors, along with stress, usually leads to a serious deterioration in properties, even if stress or the chemical environment alone may not appreciably weaken a material. This phenomenon is referred to as environmental stress cracking (ESC). The ESC failure mechanism for a particular plastics-chemical environment combination can be quite complex and, in many cases, is not yet fully understood. This article focuses on two environmental factors that contribute to failure of plastics, namely chemical and physical effects.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001452
EISBN: 978-1-62708-173-3
...), constructed with heating chamber higher than entrance and discharge ends. (b) Holding fixture fabricated from 3.2 mm ( 1 8 in.) thick sheet. (c) Incoming. (d) Exhaust. (e) Mixed to a slurry with acrylic resin and xylene thinner; powder-to-vehicle ratio, 70/30 Although...
Abstract
The quality of brazed stainless steel joints depends on the selection of the brazing process, process temperature, filler metal, and the type of protective atmosphere or flux. This article provides a detailed discussion on the applicability and brazeability of stainless steel and lays an emphasis on the selection of suitable filler metal, brazing processes, and its corresponding furnace atmosphere for brazing different grades of stainless steel. The types of brazing processes include torch brazing, furnace brazing in different atmospheres (dissociated ammonia, dry hydrogen, and vacuum atmosphere), dip brazing in salt bath, and high-energy-beam brazing. A complete list of the typical compositions and properties of standard brazing filler metals for brazing stainless steel is also provided.
Book Chapter
Series: ASM Handbook
Volume: 4B
Publisher: ASM International
Published: 30 September 2014
DOI: 10.31399/asm.hb.v04b.a0005991
EISBN: 978-1-62708-166-5
... 18,129 17,301 9.0 33.878 42.887 7.0 4.0 33.878 3.128 10.407 13.535 3.346 0.783 10.407 20 Xylene C 8 H 10 106.077 … … … 5155 … 18,410 … 10.5 39.524 50.024 8.0 5.0 39.524 3.168 10.540 13.708 3.318 0.849 10.540 21 Naphthalene C 10 H 8 128.062 … … … 5589...
Abstract
Heat treating involves the use of fuel gases for heating and gases in the furnace atmosphere. This article describes the hazards associated with furnace atmospheres and the related safety considerations. It discusses the effect of fuel on combustion efficiency. The article also contains tables that provide information on the physical, thermal and combustion properties of common gases and liquids, and the heat content of various gases.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003363
EISBN: 978-1-62708-195-5
... polyester resin composites Resin 75% H 2 SO 4 80 °C (175 °F) 15% NaOH 65 °C (150 °F) 5.25% NaOCl 65 °C (150 °F) Xylene Ambient Deionized water 100 °C (212 °F) Seawater 80 °C (180 °F) Isophthalic – – – + – – Chlorendic + – – + + + BPA fumarate – + – + – + Vinyl...
Abstract
This article provides an overview of the various types of unsaturated polyester resins and low-profile additives. The resins include general-purpose resins, isophthalic resins, bisphenol A fumarate resins, chlorendic resins, and vinyl ester resin. The article describes the mechanical and electrical properties, thermal and oxidative stability, and chemical and ultraviolet (UV) resistance of polyester resins. It concludes with a discussion on the flame-retardant polyester resins.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003365
EISBN: 978-1-62708-195-5
... methods or by chemical methods, described subsequently. Processing of Polyamide Acid Precursor Solution to Polyimide The polyamide acid solution can be converted thermally in solution to the polyimide by: the addition of a sufficient quantity of toluene or o-xylene, followed by azeotropic...
Abstract
This article discusses the properties and applications of two types of polyimide resins: condensation polyimides and addition-type polyimides. It describes the chemistry of condensation-type polyimides during synthesis, processing of polyamide acid precursor solution to polyimide, and preparation of polyimide films from thermoplastic polyamic acid precursors. The article reviews the chemistry of several addition-type polyimides, including phenylethynyl-containing imide oligomers, nadic end-capped polyimides, and LARC RP46. It explains the preparation processes of nadic end-capped amic acid oligomer resin solutions, including the preparation of resin powder and resin disks, adhesive film, adhesive bond specimens, and films.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004180
EISBN: 978-1-62708-184-9
... oxidation of xylene using cobalt, manganese, and hydrogen bromide (HBr) catalysts. In these processes, acetic acid is used as the reaction solvent. Even when chlorinated feedstocks such as mono- and dichloro-terephthalic acid are used, titanium can be made to work if the HCl that is generated...
Abstract
Organic acids represent a key group of industrial chemicals. This article provides information on the corrosion characteristics of organic acids. It focuses on corrosion caused by acetic, formic, and propionic acids on various metals and alloy groups. These include steel, aluminum, copper and its alloys, stainless steels, titanium, and nickel alloys. The article also provides information on longer-chain organic acids.
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002438
EISBN: 978-1-62708-194-8
... Tetrachloroethylene Toluene Trichloroethane Trichloroethylene Xylene(s) The chemicals and substances covered by NAAQS include: Carbon dioxide Hydrocarbons Nitrogen oxides Suspended particulates Photochemical oxidants Sulfur oxides Lead NESHAPS is a system of point...
Abstract
This article discusses Allenby's two streams for environmental aspects of design: generic and specific concerns. Generic concerns include guidelines that provide the structure in which specific techniques can be developed and used. Specific methods are environmentally responsible for design and specific information that engineers can use. These methods include life cycle assessment, environmental impact assessment, quality function deployment, design for “X”, failure modes and effects analysis, and design for disassembly.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001221
EISBN: 978-1-62708-170-2
Abstract
This article describes the basic attributes of the most widely used metal surface cleaning processes to remove pigmented drawing compounds, unpigmented oil and grease, chips, cutting fluids, polishing and buffing compounds, rust and scale from steel parts, and residues and lapping compounds from magnetic particle and fluorescent penetrant inspection. The cleaning processes include emulsion cleaning, electrolytic alkaline cleaning, acid cleaning, solvent cleaning, vapor degreasing, alkaline cleaning, ultrasonic cleaning, and glass bead cleaning. The article provides guidelines for choosing an appropriate process for particular applications and discusses eight well-known methods for determining the degree of cleanliness of the work surface.
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005777
EISBN: 978-1-62708-165-8
... solvents such as mineral spirits, lacquer thinner, xylene, methyl ethyl ketone, and other hydrocarbon degreasing solvents. Biosolvents are noncarcinogenic, nonozone depleting, nonflammable, and biodegradable. Emulsion Cleaning Emulsion cleaning ( Ref 6 , 8 , 12 , 13 ) is the most effective way...
Abstract
This article provides an overview of surface contaminants that may affect the heat treatment processes and end-product quality. It presents information on the chemicals used to clean different surface contaminants of steels. The article discusses three types of cleaning methods, namely, mechanical, chemical, and electrochemical and their effectiveness and applicability. The mechanical cleaning methods include grinding, brushing, steam or flame jet cleaning, abrasive blasting, and tumbling. Solvent cleaning, emulsion cleaning, alkaline cleaning, acid cleaning, pickling, and descaling are chemical cleaning methods. The electrochemical cleaning methods include electropolishing, electrolytic alkaline cleaning, and electrolytic pickling. The article provides information on cleanliness measurement methods such as qualitative tests and quantitative tests to ensure product quality. Health hazards that may be associated with each cleaning method and the general control measures to be used for each hazard are tabulated.
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