Precipitation hardening is a hardening mechanism found in various steels and alloy systems, such as nickel-, cobalt-, titanium-, copper-, and iron-base alloys. This article provides a brief description of precipitation hardening process, furnace equipment, surface-related problems, and protective atmospheres used in heat treatment of iron-base precipitation-hardenable (PH) superalloys. It focuses on various factors to be considered in heat treating of PH stainless steels: cleaning prior to heat treatment, furnace atmospheres, time-temperature cycles, variations in cycles, and scale removal after heat treatment. The article describes the mechanical properties, solution treatment, and aging treatment for many martensitic PH alloys, including: Alloy 17-4 PH, Alloy 13-8 Mo, Alloy 15-5 PH, Custom 450, and Custom 455; as well as semiaustenitic PH stainless steels such as Alloy 17-7 PH, Alloy PH 15-7 Mo, AM-350, Pyromet 350, AM-355, and Pyromet 355; austenitic PH stainless steel, A-286; cast PH stainless steels; and iron-nickel PH superalloys.

This article focuses on the properties of conventional wrought superalloys based on nickel, iron, and cobalt, as well as on the properties of alloys produced from powder. The powder metallurgy (P/M) category includes alloys that were originally developed as casting alloys; new alloy compositions developed specifically to benefit from powder processing; and oxide dispersion strengthened alloys (particularly those produced by mechanical alloying). The article discusses some of the applications of superalloys and emphazises the interplay between chemical composition, microstructure, consolidation method, mechanical properties and surface stability of wrought nickel alloys. Vacuum melting processes are a necessity for many nickel- and iron-nickel-base alloys because of the presence of aluminum and titanium as solutes. Cobalt-base alloys do not usually contain these elements and may be melted in air. An appendix to this article presents the property data and corresponding information on a family of cobalt-chromium-tungsten-carbon alloys that use P/M processing.

Superalloys are nickel, iron-nickel, and cobalt-base alloys generally used for high-temperature applications. Superalloys are used in aircraft, industrial, marine gas turbines, nuclear reactors, spacecraft structures, petrochemical production, orthopedic and dental prostheses, and environmental protection applications. This article discusses the material characteristics, phases, structures, and systems of superalloys. It describes the processing of superalloys, including primary and secondary melting, deformation processing (conversion), powder processing, investment casting, and joining methods. The article also describes the properties, microstructure, and thermal exposure of superalloys. It further discusses the effects of environmental factors on superalloys, including oxidation and hot corrosion. Protective coatings are also discussed. The article provides information on the mechanical properties and chemical composition of nickel, iron, and cobalt-base superalloys in both the cast and wrought forms.

The initial cast superalloy developments in the United States centered on cobalt-base materials. Nickel-base and nickel-iron-base superalloys owe their high-temperature strength potential to their gamma prime content. For polycrystalline superalloy components, high-temperature strength is affected by the condition of the grain boundaries and, in particular, the grain-boundary carbide morphology and distribution. Vacuum induction melting offers more control over alloy composition and homogeneity than all other vacuum melting processes. The primary purification reaction occurring in the process is the removal of melt contained oxygen by means of a reaction with carbon to form carbon monoxide. A number of casting processes can provide near-net shape superalloy cast parts, but essentially all components are produced by investment casting. The solidification of investment cast superalloy components is precisely controlled so that the microstructure, which ultimately determines mechanical properties, remains consistent. Heat treating cast superalloys involves homogenization and solution heat treatments or aging heat treatments.

Oxide dispersion-strengthened (ODS) alloys are produced by mechanical alloying of fine inert oxide pArticles in a highly alloyed matrix to produce composite metal powders with a controlled microstructure. The process involves repeated fracturing and rewelding the mixture of powder pArticles in a highly energetic ball charge. This Article discusses the production, consolidation, property development, fabrication of mill products, and joining of mechanical alloying ODS (MA ODS) alloys. It also describes the nominal composition, microstructure, mechanical, physical, oxidation and hot-corrosion properties of different types of mechanically alloyed (MA) commercial alloys having nickel, iron, and aluminum-base alloy systems, namely, MA 754, MA 758, MA 956, MA 6000 and MA 760.

This article covers the current state of materials development of nickel-base superalloys for additive manufacturing (AM) processes and the associated challenges. The discussion focuses on nickel-base superalloy fusion AM processes, providing information on typically encountered cracking mechanisms in AM nickel-base superalloys, such as solid-solution-strengthened nickel-base superalloys and precipitate-strengthened nickel-base superalloys. The mechanisms include solidification cracking, strain-age cracking, liquation cracking, and ductility-dip cracking. The article also provides a short discussion on binder jet AM and powder recyclability.

A significant amount of the worldwide demand for metals is met with recycled materials acquired by metal producers in the form of purchased scrap. This article focuses primarily on the methods and technology used to process and repurpose the vast amounts of purchased scrap that recirculate in the industrial supply chain. It describes the U.S. market for iron and steel scrap, providing information on scrap use by industry, factors influencing demand, and the purchased scrap supply. Iron and steel recycling is discussed separately from stainless steel and superalloy recycling in this article, as the scrap industry treats them differently. The scrap processing of iron involves collection, separation and sorting, size reduction and compaction, detinning, blending, and incineration. The recycling of stainless steels and superalloys follows the same process, but requires several additional steps, including secondary nickel refining, degreasing, and separation of metallurgical wastes.

Superalloys are predominantly nickel-base alloys that are strengthened by solid-solution elements including molybdenum, tungsten, cobalt, and by precipitation of a Ni 3 (Al, Ti) type compound designated as gamma prime and/or a metastable Ni 3 Nb precipitate designated as gamma double prime. This article provides a discussion on the conventional processing, compositions, characteristics, mechanical properties, and applications of powder metallurgy (PM) superalloys. The conventional processing of PM superalloys involves production of spherical prealloyed powder, screening to a suitable maximum particle size, blending the powder to homogenize powder size distribution, loading powder into containers, vacuum outgassing and sealing the containers, and consolidating the powder to full density. PM superalloys include Rene 95, IN-100, LC Astroloy, Udimet 720, N18, ME16, RR1000, Rene 88DT, PA101, MERL 76, AF2-1DA, Inconel 706, AF115, and KM4. The article reviews specialized PM superalloy processes and technical issues in the usage of PM superalloys.

The process of making assemblies of solid-solution and precipitation hardening groups of alloys and superalloys often requires welding of dissimilar metals, welding of diffusion-bonded materials, and sometimes weld overlay cladding and even thermal spraying that in turn requires special knowledge and treatments developed specifically for each material. This article emphasizes the special metallurgical welding considerations for welding solid-solution and precipitation hardening nickel alloys, cobalt alloys, and superalloys.

This article describes the heat treatment of wrought solid-solution and precipitation-hardening alloys with a focus on the major families of wrought nickel alloys. It also provides information on the heat treatment of some representative solid-solution alloys in the Monel (Ni-Cu), Inconel (Ni-Cr-Mo), Hastelloy (Ni-Mo-Cr), and Incoloy (Ni-Fe-Cr) families of alloys. The heat treatment processes for gamma prime nickel alloys, gamma prime nickel-iron superalloys, and gamma double-prime nickel-iron superalloys are also included. The article also provides information on age-hardenable alloys, and the effects of cold work on aging response and grain growth with examples.

This article provides a discussion on forging methods, melting procedures, forging equipment, forging practices, grain refinement, and critical factors considered in forging process. It describes the different types of solid-solution-strengthened and precipitation-strengthened superalloys, namely, iron-nickel superalloys, nickel-base alloys, cobalt-base alloys, and powder alloys. The article discusses the microstructural mechanisms during hot deformation and presents processing maps for various superalloys. It concludes with a discussion on heat treatment of wrought heat-resistant alloy forgings.

This article discusses the specimen preparation of three types of cast and wrought heat-resistant alloys: iron-base, nickel-base, and cobalt-base. Specimen preparation involves sectioning, mounting, grinding, polishing, and etching. The article illustrates the microstructural constituents of cast and wrought heat-resistant alloys. It describes the identification of ferrite by magnetic etching. The transmission electron microscopy examination of the fine strengthening phases in wrought alloys and bulk extraction in heat-resistant alloys are included. The article also reviews the gamma prime phase, gamma double prime phase, eta phase, laves phase, sigma phase, mu phase, and chi phase in wrought heat-resistant alloys.

This article provides a discussion on cutting tools, their materials and design; cutting fluids; and various aspects of machining operations of heat-resistant alloys, with several examples. Operations such as turning, planing and shaping, broaching, drilling, reaming, counterboring and spotfacing, tapping and thread milling, milling, sawing, and grinding are discussed. Nominal compositions of wrought heat-resistant alloys and nickel-base heat-resistant casting alloys, as well as compositions of cobalt-base heat-resistant casting, iron-base heat-resistant casting, and mechanically alloyed (oxide dispersion strengthened) products are also listed.

Nickel and nickel-base alloys are vitally important to modern industry because of their ability to withstand a wide variety of severe operating conditions involving corrosive environments, high temperatures, high stresses, and combinations of these factors. This article discusses the mining and extraction of nickel and describes the uses of nickel. It discusses the categories of nickel-base alloys, including wrought corrosion-resistant alloys, cast corrosion-resistant alloys, heat-resistant alloys (superalloys), and special-purpose alloys. The article covers the corrosion resistance of nickel with the inclusion of varying alloying elements. It provides useful information on the behavior of nickel and nickel alloys in specific environments describes its corrosion resistance in certain acids, alkalis, and salts.

This article describes the metallurgy and microstructure of high-performance cobalt-base alloys. It discusses metallographic preparation procedures, including sectioning, mounting, grinding, polishing, etching, staining, and heat tinting. It examines the microstructure of cobalt alloys in cast, wrought, and powder metal forms, including magnetic alloys as well as several cobalt-base superalloys.

This article reviews some of the trends in superalloy development as they relate to U.S. strategic materials availability and the aerospace industry. It discusses the supply sources and availability of strategic materials and summarizes the status of U.S. resources and reserves. The article presents a list of several superalloys that have been used in gas turbine engines or that are emerging as replacements because of the promise of increased operating temperatures and higher efficiencies for the aircraft of the future. It concentrates on the objectives, results, and methodology of the NASA Conservation of Strategic Aerospace Materials (COSAM) program.

This article discusses special considerations relative to induction heating of stainless steels and nickel-base superalloys. It focuses on the various industrial and high-temperature applications of induction heating to stainless steel and superalloy components, namely, primary melting processes, preheating for primary and secondary forming processes, heat treatments, brazing, and thermal processing for fusion welds. The article also provides information on computational modeling of induction heating processes for super alloys and stainless steels.

Rolling is the process of reducing the thickness or changing the cross section of a workpiece by compressive forces applied through a set of rolls. This article emphasizes flat rolling and illustrates basic flat-rolling process used to reduce the thickness of a rectangular cross section. It provides a discussion on hot rolling, cold rolling, and warm rolling, as well as lubrication in rolling. The article reviews the lubrication for iron-base and nickel-base materials, light metals, copper-base alloys, and titanium alloys. It discusses the wear mechanism in rolling: abrasion, adhesion, and fatigue, as well as oxidative and corrosive wear. Surface modification techniques, such as hardening by induction heat treating, weld overlay, thermal spray coating, coating via physical vapor deposition (PVD), and laser surface treatment, are also discussed for improving roll service life.

This article describes the general root causes of failure associated with wrought metals and metalworking. This includes a brief review of the discontinuities or imperfections that may be the common sources of failure-inducing defects in bulk working of wrought products. The article discusses the types of imperfections that can be traced to the original ingot product. These include chemical segregation; ingot pipe, porosity, and centerline shrinkage; high hydrogen content; nonmetallic inclusions; unmelted electrodes and shelf; and cracks, laminations, seams, pits, blisters, and scabs. The article provides a discussion on the imperfections found in steel forgings. The problems encountered in sheet metal forming are also discussed. The article concludes with information on the causes of failure in cold formed parts.

Cobalt finds its use in various applications owing to its magnetic properties, corrosion resistance, wear resistance, and its strength at elevated temperatures. This article discusses the mining and processing of cobalt and cobalt alloys. It describes the types of cobalt alloys, including wear-resistant alloys, high-temperature alloys, corrosion-resistant alloys, and special-purpose alloys. The article provides data on the chemical composition, mechanical properties, and physical properties of these alloys. Further, it provides information on the uses of cobalt in superalloys, cemented carbides, magnetic materials, low-expansion alloys, and high-speed tool steels.