Nickel and nickel-base alloys are vitally important to modern industry because of their ability to withstand a wide variety of severe operating conditions involving corrosive environments, high temperatures, high stresses, and combinations of these factors. This article discusses the mining and extraction of nickel and describes the uses of nickel. It discusses the categories of nickel-base alloys, including wrought corrosion-resistant alloys, cast corrosion-resistant alloys, heat-resistant alloys (superalloys), and special-purpose alloys. The article covers the corrosion resistance of nickel with the inclusion of varying alloying elements. It provides useful information on the behavior of nickel and nickel alloys in specific environments describes its corrosion resistance in certain acids, alkalis, and salts.

Nonferrous metals and alloys are widely used to resist corrosion. This article describes the corrosion behavior of the most widely used nonferrous metals, such as aluminum, copper, nickel, and titanium. It also provides information on several specialty nonferrous products that cannot easily be categorized by elemental base.

Cobalt is used as an alloying element in alloys for various applications. This article provides a detailed account of the metallurgy of cobalt-base alloys. It focuses on the compositions, properties, and applications of cobalt-base alloys, which include wear-resistant cobalt alloys, heat-resistant cobalt alloys, and cobalt-base corrosion-resistant alloys. The article also describes the heat treatments such as annealing and aging, for these alloys.

This article, primarily focusing on atmospheric corrosion of carbon and low-alloy steels, describes the factors that must be considered by alloy casting users in material selection. It presents compositions of cast steels tested in atmospheric corrosion in a tabular form. The article graphically presents the results of a research program that compared the corrosion resistance of nine cast steels in marine and industrial atmospheres. It provides a comparison of corrosion rates of cast steels, malleable cast iron, and wrought steel after three years of exposure in two atmospheres. Conclusions drawn from these tests are also presented.

Stainless steels are highly alloyed materials in comparison to most other popular powder metallurgy (PM) materials, such as low-alloy steels, copper alloys, and aluminum alloys. This article provides an overview of the history of PM stainless steels.

The article provides an introduction on the importance of alloying elements on corrosion behavior of nickel alloys and describes the applications of heat-resistant alloys to resist corrosion. It focuses on the metallurgical effects, mainly the effect of internal factors, including chemical composition and microstructure of the alloy, and the external factors, including electrolyte composition, temperature, and electrode potential, on the corrosion behavior of corrosion-resistant alloys. The article also discusses the implication of changing the alloy microstructure by second-phase precipitation, cold working, and cast and wrought forms on the corrosion behavior of high-nickel alloys.

Cast stainless steels are widely used for their corrosion resistance in aqueous media at or near room temperature and for service in hot gases and liquids at elevated temperatures. This article provides a comparison between cast and wrought stainless steels in terms of composition, microstructure and properties. It discusses the grade designations and compositions of cast stainless steels. The article describes the mechanical properties, applications, and corrosion characteristics of corrosion-resistant steel castings and heat-resistant steel castings.

This article provides a detailed discussion on the most commonly employed tests and specific examples of the use of these tests in evaluating the corrosion resistance of powder metallurgy (P/M) stainless steels. It describes the influence of various processing parameters on the corrosion resistance of P/M stainless steels. The approaches used to improve the corrosion resistance of sintered stainless steels are discussed briefly. The article also presents a discussion on the manufacturing and corrosion characteristics of P/M superalloys.

This article addresses the cobalt and cobalt-base alloys most suited for aqueous environments and those suited for high temperatures. The performance of cobalt alloys in aqueous environments encountered in commercial applications is discussed. The article provides information on the environmental cracking resistance of the cobalt alloys. Three welding processes that are used for hardfacing with the high-carbon Co-Cr-W alloys, namely, oxyacetylene, gas tungsten arc, and plasma-transferred arc are also discussed. The article examines the effects of various modes of high-temperature corrosion. It describes the applications and fabrication of cobalt alloys for high-temperature service.

Cobalt finds its use in various applications owing to its magnetic properties, corrosion resistance, wear resistance, and its strength at elevated temperatures. This article discusses the mining and processing of cobalt and cobalt alloys. It describes the types of cobalt alloys, including wear-resistant alloys, high-temperature alloys, corrosion-resistant alloys, and special-purpose alloys. The article provides data on the chemical composition, mechanical properties, and physical properties of these alloys. Further, it provides information on the uses of cobalt in superalloys, cemented carbides, magnetic materials, low-expansion alloys, and high-speed tool steels.

This article reviews the corrosion behavior in various environments for seven important nickel alloy families: commercially pure nickel, Ni-Cu, Ni-Mo, Ni-Cr, Ni-Cr-Mo, Ni-Cr-Fe, and Ni-Fe-Cr. It examines the behavior of nickel alloys in corrosive media found in industrial settings. The corrosive media include: hydrochloric acid, sulfuric acid, phosphoric acid, hydrofluoric acid, hydrobromic acid, nitric acid, organic acids, salts, seawater, and alkalis. The modes of high-temperature corrosion include oxidation, carburization, metal dusting, sulfidation, nitridation, corrosion by halogens, and corrosion by molten salts. Applications where the corrosion properties of nickel alloys are important factors in materials selection include the petroleum, chemical, and electrical power industries. Most nickel alloys are much more resistant than the stainless steels to reducing acids, such as hydrochloric, and some are extremely resistant to the chloride-induced phenomena of pitting, crevice attack, and stress-corrosion cracking (to which the stainless steels are susceptible). Nickel alloys are also among the few metallic materials able to cope with hot hydrofluoric acid. The conditions where nickel alloys suffer environmentally assisted cracking are highly specific and therefore avoidable by proper design of the industrial components.

This article describes the metallurgy and microstructure of high-performance cobalt-base alloys. It discusses metallographic preparation procedures, including sectioning, mounting, grinding, polishing, etching, staining, and heat tinting. It examines the microstructure of cobalt alloys in cast, wrought, and powder metal forms, including magnetic alloys as well as several cobalt-base superalloys.

This article describes the physical properties of powder metallurgy (PM) stainless steels. These include thermal diffusivity, conductivity, thermal expansion coefficient, Poisson's ratio, and elastic modulus. The article contains a table that lists the characteristics of various grades of PM stainless steels. It discusses the applications of various PM stainless steels such as rearview mirror brackets, anti-lock brake system sensor rings, and automotive exhaust flanges and sensor bosses.

This article discusses two categories of stainless steel casting alloys and their nomenclature. It provides information on two situations in which welding of stainless steel castings is required. These situations are based on casting defects and selection of welding processes. The article presents compositions and typical microstructures of corrosion-resistant stainless steel casting alloys in tabular form. It presents special considerations for the welding of martensitic stainless steel castings. The article reviews the two most serious problems encountered in the welding of stainless steel castings, namely, solidification hot cracking and heat-affected zone hot cracking. It concludes with a discussion on the some useful considerations for welding corrosion-resistant alloys to avoid defects.

Stainless steels are primarily alloys of iron and chromium. They are grouped into five families, primarily based on their microstructure: ferritic, austenitic, martensitic, duplex, and precipitation hardening. Three out of the five families of stainless steels, namely, austenitic, ferritic, and martensitic, are well suited for manufacture via conventional powder metallurgy (PM) processes. This article presents the iron-chromium partial phase diagram to illustrate the changes in the temperature range when pure iron is alloyed with chromium. It describes AISI and UNS numbering systems, which are used as an identification system for stainless steels. The article tabulates the material designations of stainless steels in accordance with the Metal Powder Industries Federation. It also details the characteristics and chemical composition of wrought and PM stainless steels.

This article provides a general overview of physical and mechanical properties, alloy compositions, applications, and product forms of cobalt-base alloys as wear-resistant, corrosion-resistant, and/or heat-resistant materials. The discussion is largely focused on cobalt-base alloys for wear resistance, as this is the single largest application area of cobalt-base alloys.

This article discusses the mechanical properties of carbon steels, low-alloy steels, wear-resistant steels, corrosion-resistant steels, heat-resistant steels, and common alloys at both room and elevated temperature. It also provides information on the corrosion-resistant and heat-resistant applications of the common alloys.

This article reviews the concepts considered important for an understanding of the processes used for preparing cobalt-chromium alloy implants, the microstructures resulting from this processing, and the resulting material properties. The review includes solidification of alloys, diffusionless (martensitic) phase transformation as occurs with face-centered cubic to hexagonal close-packed transformation in cobalt-chromium alloys, and stacking faults and twins and their role in this transformation. It also discusses the strengthening mechanisms that are responsible for the mechanical properties of cast and wrought cobalt alloys. The article contains tables that list the commonly used cobalt alloys and their biomedical applications and chemical compositions. It discusses the mechanical and corrosion properties of cobalt alloys, and provides a description of the microstructure of cobalt alloys.

The aluminum alloy 4043 is recommended as a filler metal when resistance to salt water corrosion is required, especially when welding such aluminum alloys as 5052, 6061, and 6063. This datasheet provides information on key alloy metallurgy, and processing effects on tensile properties of this 4xxx series alloy.

This article reviews high-temperature corrosion of furnace parts used in heat-treating furnaces. It provides a comparison of cast and wrought materials in the context of their general considerations, advantages, and applications. The article provides information on the heat-resistant alloys used for parts that go through the furnaces, including trays, fixtures, conveyor chains and belts, and quenching fixtures and parts, and the parts that remain in the furnace such as combustion tubes, radiant tubes, burners, thermowells, roller and skid rails, baskets, pots, retorts, muffles, and drive and idler drums. The article also reviews the material characteristics of silicon/silicon carbide composite and reaction-bonded silicon carbide as used in radiant tubes.