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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003692
EISBN: 978-1-62708-182-5
... deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described. hardening autooxidative...
Abstract
This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004125
EISBN: 978-1-62708-184-9
... with control primers containing chromates. Only one candidate, a water-borne coating, met all of the qualification requirements. Boeing conducted similar tests on these materials. They also included additional properties, such as sprayability, heat resistance, humidity resistance, thermal shock resistance...
Abstract
This article describes the protective coatings technology used in naval aircrafts. It reviews the future needs and trends of the protective coatings technology based on advancing technology, environmental concerns, and operational requirements. The article discusses the standard finishing systems for aircrafts: the surface pretreatment system, primer, topcoat, advanced-performance topcoat, self-priming topcoat, and specialty coatings. It presents safe compliant solutions to environmental problems associated with the protective coatings technology. These solutions include the use of environmental regulations and hazardous materials, nonchromated pretreatments, waterborne technology, high-solids technology, and touch-up paints. The article also deals with the use of electrodeposition coatings, powder coatings, adhesive films, paint application equipment, and non-chromated sealants in the protective coatings technology.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006071
EISBN: 978-1-62708-172-6
... for their Chempol MPS product, an innovative alkyd resin technology that enables paint and coating formulations with less than half the VOCs of traditional alkyd formulations. In 2011, the Sherwin-Williams Company (Cleveland, Ohio) was awarded the Presidential Green Chemistry Award for water-based acrylic alkyd...
Abstract
An alkyd is an ester-based polymer derived from the polycondensation reaction of polyhydric alcohol and polybasic acid. This article provides useful information on the chemistry, production, coating formulations, modification, commercial products, and application methods of alkyd resins. It also provides a section on drying oil, which is used in the manufacture of resins. The article describes the three categories of metals that have been used in drier compounds: primary driers (active or oxidation driers), secondary driers (through-driers), and auxiliary driers. It also provides information on the oil length of an alkyd resin and on solvents, which play a critical role in the formulation and use of the coating. The article concludes with a description of the concerns that a user, specifier, or applicator should be aware of when using alkyd coatings.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001277
EISBN: 978-1-62708-170-2
... particles are usually coated before being mixed into the paint to prevent chemical reaction with water, which would cause the mixture to generate gas. Water-reducible paints have a low volatile organic content (VOC) and comply with most environmental regulations. The advantages of water-borne paints include...
Abstract
Painting is a generic term for the application of a thin organic coating to the surface of a material for decorative, protective, or functional purposes. This article provides a detailed account of the types and selection factors of paints and the various application methods, including conventional air atomized, airless, and electrostatic spray; roller coating; dip coating; flow coating; curtain coating; tumble coating; electrocoating; and powder coating. Surface preparation methods and prepaint treatments for coating systems are also discussed. The article includes information on quality control procedures, causes of paint film defects, cost calculation, and safety and environmental precautions. The composition and characteristics of organic coatings, coating system selection factors, the types of paints for structural steel, and the applications of paint on structural steel are also reviewed.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006036
EISBN: 978-1-62708-172-6
... 15. Jorissen S.A. , Rumer R.W. , and Wicks D.A. , Higher Solids Polyurethane Coatings , Proceedings of the Nineteenth Water-Borne, Higher-Solids, and Powder Coatings Symposium , University of Southern Mississippi , 1992 , p 182 16. Jorissen S.A. , Polyurethane...
Abstract
Polyaspartic coating technology has found utility in a variety of coating applications, including corrosion protection and flooring topcoats, as these coatings are based on aliphatic polyisocyanates and aliphatic diamines. This article describes the chemistry of polyaspartic esters and curing characteristics and performance properties of polyaspartic coatings. It also provides information on curing corrosion protection coating systems, polyaspartic floor coatings, and safe-use recommendations for handling isocyanates.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006028
EISBN: 978-1-62708-172-6
.... Inorganic zinc-rich primers are offered as solvent- or water-borne systems. Inorganic zinc-rich silicates are also covered in the article “Zinc-Rich Coatings” in this Volume. Solvent-Borne Primers Solvent-borne primer compositions, based on partial hydrolyzates of tetra-ethoxy silane, are available...
Abstract
This article focuses on those areas of coatings technology where silicon-based technology (SBT) is the primary enabling technology and where SBT is used as an additive to provide unique properties to the coating film. It describes the chemistry and the uses of alkoxy silanes. The uses of silicates, siliconates, silicone fluids, and silicone resins in coatings are reviewed. The article discusses the various applications of SBT, namely, primers, heat-resistant coatings, industrial maintenance coatings, hygienic coatings, and abrasion-resistant coatings, and for marine biofouling control. It also provides information on the benefits of silicon-base additives.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006035
EISBN: 978-1-62708-172-6
... protective coating strategies in Generation 3 Plants. boiling water reactors coating nuclear energy pressurized water reactor protective coating thermal conductivity Surface coatings are essential in all facilities that process nuclear materials or use nuclear fission for power generation...
Abstract
Surface coatings are essential in all facilities that process nuclear materials or use nuclear fission for power generation. This article describes the coatings used in two basic types of Generation 3 nuclear reactor designs in the United States and their containment size. These reactors are the boiling water reactor (BWR) and pressurized water reactor (PWR). The article provides information on the loss-of-coolant accident (LOCA) identified as the design basis accident (DBA), which can rapidly de-water the core of an operating nuclear reactor. To avoid LOCA, both the BWR and the PWR include emergency core cooling systems. The article describes a DBA test and other coating performance parameters necessary for safety-related coating systems. It provides a detailed account of the selection criteria of coating types in a nuclear plant. The article concludes by highlighting protective coating strategies in Generation 3 Plants.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006046
EISBN: 978-1-62708-172-6
... resins for molding, coatings, and other applications. Chemistry and Varieties of Phenolic Resins Phenolic resins as used in coatings are principally derived from the products of a condensation reaction between phenol and an aldehyde. The reaction is catalyzed by acids or bases and yields water...
Abstract
Phenols are a class of aromatic organic compounds in which one or more hydroxyl groups are attached directly to the aromatic benzene ring, C6H6. This article describes the development of phenolic resin and the formation of novolac resin and resol resin. Phenolic resol resins are used in interior can coatings and tank linings as well as for heat exchanger tube coatings because of their high chemical and thermal resistance. The article concludes with a description of the concerns that a specifier, user, or applicator should be aware of regarding the use of phenolic coatings.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006073
EISBN: 978-1-62708-172-6
... with different properties than that of the reacted area. Similarly, the resin reactions around pigment particles and other paint constituents also have a different crosslinking density than that of the pure resin reaction. Solvents in solvent-borne coatings, and water in latex or waterborne coatings...
Abstract
This article discusses the environmental influences on protective coating films that can result in deterioration. These environmental factors can be classified into four groups: (1) energy: solar, heat; (2) permeation: moisture, solvent, chemical, and gas; (3) stress: drying and curing-internal stress, and vibration-external stress; and (4) biological influences such as microbiological, mildew, and marine fouling.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001325
EISBN: 978-1-62708-170-2
... , John Wiley and Sons , 1985 • Pulley D. , Naval Air Warfare Center , “Compliant Coatings for Aerospace Applications,” paper presented at the Water-Borne and Higher-Solids Coatings Symposium ( New Orleans, LA ), Feb 1989 • South Coast Air Quality Management District , Proposed...
Abstract
This article discusses coating products available for use in the aerospace industry that are compliant with regulations requiring reductions in emissions from organic solvents. The coating products addressed include primers, topcoats, and chemical milling maskants. It describes their characteristics and limitations compared to conventional noncompliant materials. The article addresses the methods and products commonly used achieve regulatory compliance: waterborne coatings, exempt-solvent-based coatings, high-solids coatings, powder coating, and electro-deposition.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006011
EISBN: 978-1-62708-172-6
... of polyurethane coatings include polyester, polyacrylate (acrylic), and polyether polyols. Isocyanate reactions with water and amines to form polyureas also have an important role in anticorrosion coatings. Single-component polyurethane coatings (i.e., moisture cured) are based on the reaction with water to form...
Abstract
Polyurethane is any polymer consisting of a chain of repeating organic units joined by urethane linkages. Polyurethane polymers are formed through step-growth polymerization by making a monomer containing at least two isocyanate functional groups to react with another monomer containing at least two hydroxyl (alcohol) groups. This article provides a detailed account of the protective coatings used in the building, infrastructure, and architectural markets. It focuses on the various types of polyurethane coatings used in these applications: moisture-cure and two-pack aromatic coatings as primers and topcoats, moisture-cure aromatic elastomeric high-build coatings, moisture-cure aliphatic topcoats, two-pack aliphatic polyurethane coatings as topcoats, and one- and two-pack polyurethane dispersion coatings as sealers and topcoats. It also includes a section on the health effects of isocyanates.
Book: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005718
EISBN: 978-1-62708-171-9
.../coating bonding, eliminating much of the porosity typically found in conventional flame-sprayed coatings. Process Equipment Basic components of a detonation gun system are much like that of a conventional flame spray system and include: Gas supply: oxygen, fuel, nitrogen Water cooling...
Abstract
This article presents the major thermal spray processes and their subsets, presenting each of the commercially significant processes together with some of their important variations. Each process is presented along with the attributes that influence coating structure and performance. The article summarizes the essential equipment components and necessary controls. The various thermal spray processes are conventional flame spray, detonation gun, high-velocity oxyfuel spray, electric arc spray, and plasma arc spray. Other processes, such as cold spray, underwater plasma arc spray, and extended-arc and other high-energy plasma arc spray, are also considered.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006041
EISBN: 978-1-62708-172-6
... formulations, water-based coating formulations, and powder coating formulations. The basic concerns to be addressed when formulating and using FEVE coatings are also discussed. The article concludes with a section on health and related safety regulations. coating fluoroethylene vinyl ether resin health...
Abstract
This article provides background information on the chemistry, coating properties, resin types, applications techniques, and performance characteristics of fluoroethylene vinyl ether (FEVE) resins. It describes the formulation methods of FEVE resins, namely, solvent-based coating formulations, water-based coating formulations, and powder coating formulations. The basic concerns to be addressed when formulating and using FEVE coatings are also discussed. The article concludes with a section on health and related safety regulations.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003217
EISBN: 978-1-62708-199-3
... film-forming materials dissolved in organic solvent. These dry primarily by solvent evaporation. Water-Borne Paints Water-borne paints are dilutable with water. There are three principal types: solutions, colloidal dispersions, and emulsions. Solution coatings are based on water-soluble binders...
Abstract
There are various coating techniques in practice to prevent the deterioration of steels. This article focuses on dip, barrier, and chemical conversion coatings and describes hot-dip processes for coating carbon steels with zinc, aluminum, lead-tin, and other alloys. It describes continuous electrodeposition for steel strip and babbitting and discusses phosphate and chromate conversion coatings as well. It also addresses painting, discussing types and selection, surface preparation, and application methods. In addition, the article describes rust-preventive compounds and their application. It also provides information on weld-overlay and thermal spray coating, porcelain enameling, and the preparation of enamel frits for steels. The article closes by describing methods and materials for ceramic coating.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001225
EISBN: 978-1-62708-170-2
... in ignition of the metal and destruction of the component. Paint Stripping Paint stripping in molten salts is a simple immersion process and is applicable to a wide variety of organic coatings, including solvent-based, water-borne, cured powders and high-performance coatings such as fluorinated...
Abstract
Molten salt baths are anhydrous, fused chemical baths used at elevated temperatures for a variety of industrial cleaning applications. This article discusses their applications in paint stripping, polymer removal, casting cleaning, glass removal, and plasma/flame spray removal. It provides an overview of the basic design and safety considerations of the salt bath equipment and describes the environmental impact of molten salt bath cleaning.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006040
EISBN: 978-1-62708-172-6
..., use acrylic latex or high-solids acrylic elastomers that have low film-stress properties. Fig. 9 Typical on-ground steel water storage tank coated externally with a zinc/epoxy/urethane coating system Historically, solvent-borne epoxy coatings were used extensively for water tank...
Abstract
This article presents information regarding the use of protective coatings in municipal potable water systems, including raw water collection and transmission, water treatment plants, and treated water distribution. It provides useful guidance for the selection and use of protective coatings in these municipal water systems. The most commonplace corrosion-damage mechanisms are highlighted. The article describes the most common materials of construction found in municipal water systems, namely, cast iron, ductile iron, carbon steel, precast concrete cylinder pipe and reinforced concrete pipe, prestressed concrete tanks, and stainless steel. It provides information on the most common generic coating systems used for new steel tanks and water storage tanks. It concludes with a discussion of quality watch-outs when selecting or using protective coatings in municipal water systems.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006037
EISBN: 978-1-62708-172-6
...), there are no standardized tests. (The author employs a boiling water/dry ice continuous-cycling method to compare products.) The best systems for thermal shock environments are urethane concretes, which have good thermal properties (minimal shrinkage, low LCTE, high T g ). Installation of Polymeric Floor Coatings...
Abstract
Polymeric floor coatings refer to flooring materials composed of multicomponent thermoset resins formulated with various fillers and pigments that are installed in situ, usually over concrete substrates. Polymeric flooring systems, specified for all industrial and commercial environments, use a variety of polymer chemistries and are constructed in a variety of methods and designs. This article provides a description of the service conditions for the polymeric flooring systems. It provides information on polymeric flooring systems, including thin-film coatings, self-leveling systems, membrane systems, broadcast systems, troweled systems, and terrazzo. The article also focuses on properties, applications, testing, and factors and requirements to be considered during the installation of polymeric floor coatings. It concludes with a discussion about coating failures, including bonding, cracking, chemical attack, and moisture that affect the polymeric floor coatings on concrete.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006060
EISBN: 978-1-62708-172-6
... Abstract This article presents a background of green chemistry and green coatings, and a summary of the key concerns of the green coating procurement process. It includes a discussion on green marketing and the seven sins of greenwashing, an overview of the environmental certification standards...
Abstract
This article presents a background of green chemistry and green coatings, and a summary of the key concerns of the green coating procurement process. It includes a discussion on green marketing and the seven sins of greenwashing, an overview of the environmental certification standards and regulatory environments, and the importance of performance during the duty cycle.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003689
EISBN: 978-1-62708-182-5
... are spun in the centrifuge to remove the excess zinc metal. This operation produces higher quality coatings on threaded articles. Most galvanized articles are air cooled after coating, although centrifuged parts and smaller items are often water cooled (quenched). Water quenching halts the alloying...
Abstract
This article provides a discussion on the two basic steps of the batch hot dip galvanizing process: surface preparation and galvanizing. It describes the factors affecting coating thickness and coating structure. The mechanical properties of the coating and steel substrate are also discussed. The article also provides information on the various factors that should be considered before galvanizing a material. It examines the performances of galvanized coatings in corrosion service. The joining of galvanized structural members by bolting and welding is also discussed. The article describes the synergistic effects of galvanized and painted systems. It explains the applications of hot dip galvanized steel. The article concludes with information on pertinent galvanizing specifications under the authority of the American Society for Testing and Materials.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005252
EISBN: 978-1-62708-187-0
... Coating cycle is long. Solvents are generally le. Water-borne novolaks Yield large volume of high-strength sand per pound of resin Contain less alcohol (fire hazard reduced) Coating cycle is shorter than with varnishes. Readily handled in bulk Slight caking tendency...
Abstract
Shell molding is used for making production quantities of castings that range in weight from a few ounces to approximately 180 kg (400 lb), in both ferrous and nonferrous metals. This article lists the limitations or disadvantages of shell mold casting. It describes the two methods for preparation of resin-sand mixture for shell molding, namely, mixing resin and sand according to conventional dry mixing techniques, and coating the sand with resin. Shaping of shell molds and cores from resin sand mixtures is accomplished in machines. The article discusses the major steps in producing a mold or core and describes the problems most frequently encountered in shell-mold casting. The problems include mold cracking, soft molds, low hot tensile strength of molds, peelback, and mold shift. The article concludes with information on examples that provide some relative cost comparisons between shell molding and green sand molding.
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