Mechanically assisted degradation of metals is defined as any type of degradation that involves a corrosion mechanism and a wear or fatigue mechanism. This article provides a discussion on the mechanisms of five forms of degradation: erosion, fretting corrosion, fretting fatigue, cavitation and water drop impingement, and corrosion fatigue. It describes the factors affecting the severity of fretting corrosion. The article also illustrates the relationship between corrosion fatigue and stress-corrosion cracking.

Liquid impingement erosion has been defined as progressive loss of original material from a solid surface due to continued exposure to impacts by liquid drops or jets. This article focuses on the core nature of erosion by liquid impingement, due to the greater appreciation of the distinctions between the different forms of erosion. It discusses steam turbine blade erosion, aircraft rain erosion, and rain erosion of wind turbine blades. The article describes the mechanisms of liquid impact erosion and time dependence of erosion rate. It reviews critical empirical observations regarding both impingement variables (velocity, impact angle, droplet size, and physical properties of liquids) and erosion resistance of materials, including the correlation between erosion resistance and mechanical properties and the effects of alloying elements and microstructure. The article also provides information on the ways to combat erosion.

Spray quenching refers to a wide variety of quenching processes that involve heat removal facilitated by the impingement of a quenchant medium on a hot metal surface. This article provides information on the basic concepts of spray quenching, and discusses the most commonly used techniques in quench tank agitation to establish uniformity of the quenched part. Common techniques include quenchant stirring, quenchant circulation, and submerged jet/spray mixing. The article also describes the effect of quenching agitation and reviews heat-transfer characteristics of immersion quenching and spray quenching with water.

Erosion of a solid surface can be brought about by liquid droplet impingement (LDI), which is defined as "progressive loss of original material from a solid surface due to continued exposure to erosion by liquid droplets." In this article, the emphasis is placed on the damage mechanism of LDI erosion under the influence of a liquid film and surface roughness and on the prediction of LDI erosion. The fundamentals of LDI and processes involved in initiation of erosion are also discussed.

Erosion occurs as the result of a number of different mechanisms, depending on the composition, size, and shape of the eroding particles; their velocity and angle of impact; and the composition of the surface being eroded. This article describes the erosion of ductile and brittle materials with the aid of models and equations. It presents three examples of erosive wear failures, namely, abrasive erosion, erosion-corrosion, and cavitation erosion.

Erosion, cavitation, and impingement are mechanically assisted forms of material degradation that often contribute to corrosive wear. This article identifies and describes several tests that are useful for ranking the service potential of candidate materials under such conditions. The tests, designed by ASTM as G32, G73, G75, and G76, define specimen preparation, test conditions, procedures, and data interpretation. The article examines the relative influence of various test parameters on the incubation and intensity of cavitation, including temperature, pressure, flow velocity, and vibration dynamics. It concludes with a discussion on data correlations and the relationship between laboratory results and service expectations.

Erosion is the progressive loss of original material from a solid surface due to mechanical interaction between that surface and a fluid, a multicomponent fluid, an impinging liquid, or impinging solid particles. The detrimental effects of erosion have caused problems in a number of industries. This article describes the processes involved in erosion of ductile materials, brittle materials, and elastomers. Some examples of erosive wear failures are given on abrasive erosion, liquid impingement erosion, cavitation, and erosion-corrosion. In addition, the article provides information on the selection of materials for applications in which erosive wear failures can occur.

Induction heating for hardening of steels has advantages from the standpoint of quenching because parts are individually processed in a controlled manner. This article provides information on the effect of agitation, temperature, hardening, residual stresses, and quenching media, on quenching. It also describes various quenching methods for steel induction heat treating, namely, spray quenching, immersion quenching, self or mass quenching, and forced air quenching. The article also reviews quench system design and quenchants and their maintenance.

This article is a pictorial guide to forms of corrosion that draws attention to common pitfalls or situations that have caused premature corrosion, sometimes with expensive consequences. The examples used are not exhaustive; they highlight the necessity to fully examine materials, conditions, and specific circumstances that together can reduce the anticipated service life of a component or plant. The color images in this article are categorized according to the type of corrosion following the general order that is adopted in Volume 13A of ASM Handbook. The first table of the article provides a categorization of the forms of corrosion. It also provides a reference to articles or sections of articles in Volume 13A that detail the particular corrosion form or mechanism. The second table is a guide listing the figures in this article by material and by the corrosion form or mechanism illustrated.

This article briefly describes water and steam chemistry, which influence the effect of corrosion in boilers. The appropriate control measures to prevent corrosion in boilers are also presented. The article provides a discussion on the common causes of fluid-side corrosion such as flow-accelerated corrosion, oxygen pitting, chelant corrosion, caustic corrosion, acid corrosion, organic corrosion, phosphate corrosion, hydrogen damage, and corrosion-assisted cracking.

The use of thermal spray coatings to restore worn surfaces has provided a significant improvement in surface performance due to improved wear resistance. This article discusses the general use of thermal spray coatings in reducing predominant types of wear, namely, abrasive wear, erosive wear, adhesive wear, and surface fatigue.

Ingot casting is the vital conduit between molten metal provided by primary production and recycling and the manufacture of aluminum and aluminum alloy products. A number of ingot casting processes have been developed to ensure the soundness, integrity, and homogeneity required by downstream manufacturing processes. This article starts with a review of the different forms of ingot and the molten-metal processing techniques involved in ingot casting. It then describes the open-mold casting and direct chill (DC) ingot casting processes. The process variations and solidification in the DC process are summarized. The article explains continuous processes, namely, twin-roll strip casting, slab casting, and wheel-belt processes. It concludes with information on postsolidification processes, including stress relief and scalping, and a discussion of safety practices for ingot casting.

Ingot casting is the vital conduit between molten metal provided by primary production and recycling, and the manufacture of aluminum and aluminum alloy products. This article discusses various ingot forms, such as remelt ingot, billets, ingots for rolling, fabricating ingot, and particle ingot and powder. It describes the molten metal processing and ingot casting process in terms of open-mold casting and direct chill process. The article examines the continuous processes that provide commercial alternatives to conventional ingot casting. It reviews the postsolidification processes in terms of stress relief, homogenization, and scalping. The article concludes with a discussion on safety limited to ingot casting.

This article describes the characteristics of tubing of heat exchangers with respect to general corrosion, stress-corrosion cracking, selective leaching, and oxygen-cell attack, with examples. It illustrates the examination of failed parts of heat exchangers by using sample selection, visual examination, microscopic examination, chemical analysis, and mechanical tests. The article explains corrosion fatigue of tubing of heat exchangers caused by aggressive environment and cyclic stress. It also discusses the effects of design, welding practices, and elevated temperatures on the failures of heat exchangers.

The fluidized bed provides a means for exchanging heat between a metal part, the solid particles, and the fluidizing gas and which is viable for quenching. This article briefly considers the design aspects of the gas distributor, plenum, container, immersed cooling tubes and surface air spray cooling system in the quenching fluidized bed. It describes the fundamental factors affecting quenching power of the fluidized beds, namely, particle size, particle material, fluidizing gas composition, fluidizing gas flow rate, bed temperature and pressure, and the arrangement of quenched parts with respect to one another and to the bed. The article discusses the advantages, disadvantages, various applications and processes, including conventional batch quenching, two-step batch quenching, and continuous quenching of fluidized bed quenching, in detail.

This article considers two mechanisms of cavitation failure: those for ductile materials and those for brittle materials. It examines the different stages of cavitation erosion. The article explains various cavitation failures including cavitation in bearings, centrifugal pumps, and gearboxes. It provides information on the cavitation resistance of materials and other prevention parameters. The article describes two American Society for Testing and Materials (ASTM) standards for the evaluation of erosion and cavitation, namely, ASTM Standard G 32 and ASTM Standard G 73. It concludes with a discussion on correlations between laboratory results and service.

Erosion of solid surfaces can be brought about solely by liquids in two ways: from damage induced by formation and subsequent collapse of voids or cavities within the liquid, and from high-velocity impacts between a solid surface and liquid droplets. The former process is called cavitation erosion and the latter is liquid-droplet erosion. This article emphasizes on manifestations of damage and ways to minimize or repair these types of liquid impact damage, with illustrations.

Heat exchangers are devices used to transfer thermal energy between two or more fluids, between a solid surface and a fluid, or between a solid particulate and a fluid at different temperatures. This article first addresses the causes of failures in heat exchangers. It then provides a description of heat-transfer surface area, discussing the design of the tubular heat exchanger. Next, the article discusses the processes involved in the examination of failed parts. Finally, it describes the most important types of corrosion, including uniform, galvanic, pitting, stress, and erosion corrosion.

This article discusses various control processes carried out in powder feeding, thermal spraying, and gas flow of the thermal spray process to standardize the coating quality. Quality of the entire powder feeding process can be achieved by controlling the processing of feeding equipment as well as the characteristics of the powder being fed. Gas flow control can be achieved by using rotameters, critical orifices, and thermal mass flowmeters, whose ability to provide useful information is defined by their resolution, accuracy, linearity, and repeatability. The commercial thermal spray controls discussed here include the open-loop input-based, open-loop output-based, closed-loop input-based, and closed-loop output-based or adaptive controls. The article discusses the common causes and practical solutions for arc starting problems. It also outlines certain important developments in measuring individual and collective particle velocities, temperature, and trajectories as well as other plume characteristics for the plasma spray process.

Copper and copper alloys are widely used in many environments and applications because of their excellent corrosion resistance, which is coupled with combinations of other desirable properties. This article lists the identifying characteristics of the forms of corrosion that commonly attack copper metals as well as the most effective means of combating each. General corrosion, galvanic corrosion, pitting, impingement, fretting, intergranular corrosion, dealloying, corrosion fatigue, and stress-corrosion cracking (SCC) are some forms of corrosion. The article also lists a galvanic series of metals and alloys valid for dilute aqueous solutions, such as seawater and weak acids. It provides useful information on the effects of alloy compositions, selection for specific environments, and atmospheric corrosion of selected copper alloys. The article also tabulates the corrosion ratings of wrought copper alloys in various corrosive media.