Supercritical water oxidation (SCWO) is an effective process for the destruction of military and industrial wastes including wastewater sludge. This article discusses the unique properties of supercritical water and lists the main technological advantages of SCWO. For many waste streams, corrosion continues to be one of the central challenges to the full development of the SCWO technology. The article presents a summary of selected materials exposed to various environments as well as the observed form of corrosion in a table. It also illustrates the necessity to adopt a synergistic approach incorporating feed chemistry control, reactor design modifications, and intelligent materials selection, for mitigating degradation of SCWO systems.

This article provides information on the municipal wastewater system components such as piping, pump stations, headworks, clarifiers, aeration structures, digesters, biosolids dewatering equipment, and sludge stabilization. It explains the major corrosion damage mechanisms to which those component parts of the system are exposed. It presents useful guidelines for selecting and using protective coatings in municipal sewerage collection systems and water reclamation facilities in wastewater treatment plants. The article includes annotated flow diagrams of a wastewater collection system, wastewater treatment plants, and spreadsheets listing the most widely used generic coating systems by structure and substrate material. It concludes with a section on quality watchouts when selecting or using protective coatings in municipal wastewater systems.

This article describes selected U.S. environmental statutes and regulations that are pertinent to material surface finishers. It provides information on the applicability, requirements, and permitting conditions of the Clean Air Act, the Resources Conservation and Recovery Act, the Superfund Amendments and Reauthorization Act, and the Clean Water Act.

Corrosion problems and materials selection for emissions control equipment can be difficult because of varied corrosive compounds present and the severe environments encountered. This article discusses the selection of materials for construction of flue gas desulfurization systems. It addresses the problems associated with materials for incinerator off-gas treatment equipment. The off-gases can be classified according to their corrosiveness as: industrial chemical, hospital, municipal solid, and sewage sludge. The article provides information on the selection of materials for the three most common types of dust collection equipment used in bulk solids processing, namely, fabric filters, electrostatic precipitators, and wet scrubbers. It also discusses a wide variety of corrosion problems encountered in chemical and pharmaceutical industries.

This article focuses on the types, composition, and applications of phosphate coatings and describes the characteristics of phosphate-coated ferrous and nonferrous materials, including steel and aluminum. It addresses five successive process fundamentals: cleaning, rinsing, phosphating, rinsing after phosphating, and chromic acid rinsing. The article describes the techniques for controlling the chemical composition of various phosphating solutions. It discusses the equipment and factors that influence equipment requirements in immersion and spray systems. The article also describes the controlling procedures of coating weight and crystal size. It provides guidelines for choosing phosphate coatings based on application, coating weight requirements, and recommended process parameters. The article concludes with a discussion on safety precautions and the treatment of effluents from phosphating plants.

This article discusses the methods of pulp production, pulp processing, pulp bleaching, and paper manufacturing. It describes various types of digesters, their construction materials, the corrosion problems encountered, and methods to protect these digesters from corrosion. The article examines the corrosion problems in high-yield mechanical pulping, sulfite process, neutral sulfite semichemical pulping, chemical recovery, tall oil plants, wastewater treatment, and recovery boilers. It explains the stages of chlorine-based and nonchlorine bleaching, process water reuse for elemental chlorine-free and nonchlorine bleaching stages, selection of material for bleaching equipment, developments in oxygen bleaching, and the use of highly corrosion-resistant materials for bleach plant equipment. The article reviews the materials used in the construction of paper machine components and specific corrosion problems that affect them. It discusses the composition and corrosive nature of white water. The article also addresses the corrosion and chemical recovery associated with kraft pulping liquors.

Mechanical plating is a method for coating ferrous metals, copper alloys, lead, stainless steel, and certain types of castings by tumbling the parts in a mixture of glass beads, metallic dust or powder, promoter or accelerator chemicals, and water. It offers a straightforward alternative method for achieving desired mechanical and galvanic properties with an extremely low risk of hydrogen embrittlement. This article provides a detailed description of the equipment, process steps, process capabilities, applicable parts, specific characteristics, advantages, limitations, post treatments, and waste treatment of mechanical plating.

Copper alloys are widely used as electroplated coatings. They can also be used with practically any substrate material that is suitable for electroplating. This article focuses on the solution composition and operating conditions for brass and bronze plating solutions. It describes the decorative and engineering applications of brass and bronze plating. The article also provides information on the treatment of waste water from brass and bronze plating operations.

This article provides an overview of the electrochemical nature of corrosion and analyzes corrosion-related failures. It describes corrosion failure analysis and discusses corrective and preventive approaches to mitigate corrosion-related failures of metals. These include: change in the environment; change in the alloy or heat treatment; change in design; use of galvanic protection; use of inhibitors; use of nonmetallic coatings and liners; application of metallic coatings; use of surface treatments, thermal spray, or other surface modifications; corrosion monitoring; and preventive maintenance.

Electrodeposition of tin alloys is used to protect steel against corrosion or wear, to impart resistance to etching, and to facilitate soldering. This article focuses on the compositions, operating conditions, advantages, and limitations of methane sulfonic acid plating solutions and fluoborate plating solutions for tin-lead. It briefly describes the solution compositions and operating conditions of tin-bismuth, tin-nickel, and tin-zinc.

This article describes the uses of the liquid carburizing process carried out in low and high temperature cyanide-containing baths, and details the noncyanide liquid carburizing process which can be accomplished in a bath containing a special grade of carbon. It presents a simple formula for estimating total case depth, and illustrates the influence of carburizing temperature, duration of carburizing, quenching temperature, and quenching medium with the aid of typical hardness gradients. The article provides information on controlling of cyaniding time and temperature, bath composition, and case depth, and presents examples that relate dimensional change to several shapes that vary in complexity. It also provides information on the quenchant removal and salt removal processes, lists the applications of liquid carburizing in cyanide baths, and discusses the process and importance of cyanide waste disposal in detail.

This article provides a detailed account of the various alkaline and acid plating baths used for electrolytic copper plating. Dilute cyanide and Rochelle cyanide baths, high-efficiency sodium and potassium cyanide baths, alkaline noncyanide copper plating baths, and alkaline copper pyrophosphate baths, are discussed. The article reviews acid plating baths such as copper sulfate bath and copper fluoborate bath. It also presents information on the surface preparation considerations, bath composition, and operating variables of copper plating as well as the equipment used.

In high-iron-tonnage operations, the cupola remains the most efficient source of continuous high volumes of iron needed to satisfy high production foundries or the multiple casting machines of centrifugal pipe producers. This article explores successful improvement technologies in cupola equipment, including preheated air blast, recuperative hot blast systems, and duplex electric holders. It discusses the shell, intermittent or continuous tapping, tuyere and blower systems, refractory lining, water-cooled cupolas, emission-control systems, and storage and handling of the charge materials. The article provides a discussion on the control tests for cupola, including the chill test and mechanical test. It concludes with information on specialized cupolas such as the cokeless cupola and the plasma-fired cupola.

This article provides an overview of surface contaminants that may affect the heat treatment processes and end-product quality. It presents information on the chemicals used to clean different surface contaminants of steels. The article discusses three types of cleaning methods, namely, mechanical, chemical, and electrochemical and their effectiveness and applicability. The mechanical cleaning methods include grinding, brushing, steam or flame jet cleaning, abrasive blasting, and tumbling. Solvent cleaning, emulsion cleaning, alkaline cleaning, acid cleaning, pickling, and descaling are chemical cleaning methods. The electrochemical cleaning methods include electropolishing, electrolytic alkaline cleaning, and electrolytic pickling. The article provides information on cleanliness measurement methods such as qualitative tests and quantitative tests to ensure product quality. Health hazards that may be associated with each cleaning method and the general control measures to be used for each hazard are tabulated.

This article discusses the basic principles of inductively coupled plasma mass spectrometry (ICP-MS), covering different instruments used for performing ICP-MS analysis. The instruments covered include the sample-introduction system, ICP ion source, mass analyzer, and ion detector. Emphasis is placed on ICP-MS applications in the semiconductor, photovoltaic, materials science, and other electronics and high-technology areas.

This article reviews corrosion problems in the U.S. Department of Defense (DoD) and discusses management and maintenance aspects of the practices that address the cost and readiness. It describes the plans to institute corrosion prevention and control strategies under DoD directives in engineering design, material selection, and fabrication processes for new acquisitions. The article also suggests a long-term strategy to reduce the cost of corrosion control.

Various types of furnaces have been used for cast iron melting. In terms of tonnage, the primary melting methods used by iron casting facilities are cupola and induction furnaces. This article describes the operation and control principles of cupola furnace. It discusses the advantages of specialized cupolas such as cokeless cupola and plasma-fired cupola. Melting in iron foundries is a major application of induction furnaces. The article describes the operations of two induction furnaces: the channel induction furnace and the induction crucible furnace. It explains the teapot principle of pressure-actuated pouring furnaces and provides information on the effect of pouring magnesium-treated melts.

This article focuses on the effects of microscopic organisms and the by-products they produce on the electrochemical corrosion of metals. The general characteristics of the microorganisms that facilitate their influence on the electrochemistry of corrosion are discussed. The industries most often reported as being affected by microbiological corrosion are listed, along with the organisms usually implicated in the attack. The article explains that the influence of organisms can be addressed successfully for a corrosion control program by using four types of evidence: metallurgical, microbiological, chemical, and electrochemical. It provides information on the microbiologically influenced corrosion (MIC) of irons and steels, passive alloys (austenitic stainless steels), aluminum alloys, copper alloys, and composites. The article reviews the formation of microbial biofilms and macrofouling films. It also describes the general approaches taken to prevent MIC.

This article provides an overview of the identification systems for various grades of wrought stainless steels, namely, the American Iron and Steel Institute numbering system, the Unified Numbering System, and proprietary designations. It elaborates on five major families of stainless steels, as defined by the crystallographic structure. These include ferritic stainless steels, austenitic stainless steels, martensitic stainless steels, and precipitation-hardening stainless steels. The mechanism of corrosion protection for stainless steels is reviewed. The article examines the effects of composition, processing, design, fabrication, and external treatments on the corrosion of stainless steels. Various forms of corrosion, namely, general, galvanic, pitting, crevice, intergranular, stress-corrosion cracking, erosion-corrosion, and oxidation, are reviewed. Corrosion testing for; corrosion in atmosphere, water, and chemical environments; and the applications of stainless steels in various industries are also discussed.

This article presents the fundamentals and nomenclature of polymer quenchants and provides a detailed discussion on the polymers used for quenching formulation. The article describes the effect of polymer structure on the quenching mechanism. It also presents the factors affecting polymer quenchant performance. The article details the use of polymer quenchants for intensive quenching and then focuses on the wire patenting processes and polymer quenchant analysis. The article presents the application of polymer quenchants for induction hardening. Finally, it provides details on cooling curve analysis of polymer quenchants.