This article describes the corrosion modes in a waste-to-energy boiler. It discusses the corrosion protection and alloy performance with an emphasis on two main areas of the boiler: furnace water walls and super heaters.

The primary fossil fuels are generally defined as coal, oil, natural gas, tar sands, and shale oil. This article discusses the characteristics and the types of fuels used in fossil and fuel industries. It describes the energy conversion in fuels and outlines the efficiency of a heat engine with the help of the Carnot equation.

This article describes the specific features and mechanisms of oxidation in thermal spray coatings. It discusses the two forms of hot corrosion in sulfur-containing combustion, namely high-temperature hot corrosion and low-temperature hot corrosion. The article reviews the behavior of corrosion-resistant coatings in boilers. The effects of high-temperature corrosion in waste incinerators are detailed. The article also examines the effects of erosion-corrosion in fluidized bed combustion boilers.

High-temperature exposure of materials occurs in many applications such as power plants (coal, oil, natural gas, and nuclear), land-based gas turbine and diesel engines, gas turbine engines for aircraft, marine gas turbine engines for shipboard use, waste incineration, high-temperature fuel cells, and missile components. This article discusses high-temperature corrosion in boilers, diesel engines, gas turbines, and waste incinerators. Boilers are affected by stress rupture failures, waterside corrosion failures, fireside corrosion failures, and environmental cracking failures. Contamination of combustion fuel in diesel engines can cause high-temperature corrosion. Gas turbine engines are affected by hot corrosion. Refractory-lined incinerators and alloy-lined incinerators are discussed. The article provides case studies for each component failure.

This article begins with a discussion on the driving forces for recycling composites. It reviews the recycling process of thermoset-matrix composites and thermoplastic-matrix composites. The recycling of thermoset-matrix composites includes regrind, chemical, energy recovery, and thermal processes. Thermoplastic-matrix composites are recycled by regrinding, compounding/blending and reprocessing. The article concludes with discussion on the properties of recycled composite fibers.

High temperature corrosion may occur in numerous environments and is affected by factors such as temperature, alloy or protective coating composition, time, and gas composition. This article explains a number of potential degradation processes, namely, oxidation, carburization and metal dusting, sulfidation, hot corrosion, chloridation, hydrogen interactions, molten metals, molten salts, and aging reactions including sensitization, stress-corrosion cracking, and corrosion fatigue. It concludes with a discussion on various protective coatings, such as aluminide coatings, overlay coatings, thermal barrier coatings, and ceramic coatings.

Failures in boilers and other equipment taking place in power plants that use steam as the working fluid are discussed in this article. The discussion is mainly concerned with failures in Rankine cycle systems that use fossil fuels as the primary heat source. The general procedure and techniques followed in failure investigation of boilers and related equipment are discussed. The article is framed with an objective to provide systematic information on various damage mechanisms leading to the failure of boiler tubes, headers, and drums, supplemented by representative case studies for a greater understanding of the respective damage mechanism.

Dew-point corrosion occurs when gas is cooled below the saturation temperature pertinent to the concentration of condensable species contained by a gas. This article discusses dew-point corrosion problems in the susceptible areas of dry flue gas handling systems. The corrosion problems associated with the nitrate stress-corrosion cracking in heat-recovery steam generators are also discussed. The article presents general comments on the materials selection; plant operation; use of neutralizing additives; and maintenance, good housekeeping, and lagging (insulation). It concludes with information on guidance for maintaining specific sections of the plant.

Ceramic and glass manufacturers take environmental regulations into consideration during all stages of the product cycle, from research and development to purchasing, processing, end use, and disposal. Ceramic and glass products are finding application in the construction industry and as raw materials for other processes. This article describes the recycling of in-process scrap and industrial wastes (fly ash, red mud, metallurgical waste, and other waste products), and applications of these recycled products. It focuses on environmental regulations such as Resource Conservation and Recovery Act and Clean Air Act. The Clean Air Act requires all states to meet minimum emissions standards for nitrogen-oxygen compounds, volatile organic compounds, and carbon monoxide.

The presence of certain impurities in coal and oil is responsible for the majority of fireside corrosion experienced in utility boilers. In coal, the primary impurities are sulfur, alkali metals, and chlorine. The most detrimental impurities in fuel oil are vanadium, sodium, sulfur, and chlorine. This article describes the two categories of fireside corrosion based on location in the furnace: waterwall corrosion in the lower furnace and fuel ash corrosion of superheaters and reheaters in the upper furnace. It discusses prevention methods, including changes to operating parameters and application of protective cladding or coatings.

High-temperature corrosion can occur in numerous environments and is affected by various parameters such as temperature, alloy and protective coating compositions, stress, time, and gas composition. This article discusses the primary mechanisms of high-temperature corrosion, namely oxidation, carburization, metal dusting, nitridation, carbonitridation, sulfidation, and chloridation. Several other potential degradation processes, namely hot corrosion, hydrogen interactions, molten salts, aging, molten sand, erosion-corrosion, and environmental cracking, are discussed under boiler tube failures, molten salts for energy storage, and degradation and failures in gas turbines. The article describes the effects of environment on aero gas turbine engines and provides an overview of aging, diffusion, and interdiffusion phenomena. It also discusses the processes involved in high-temperature coatings that improve performance of superalloy.

This article focuses on the mineral and organic acid cleaning of iron and steel. It begins with a discussion on the application methods, process selection criteria, solution composition, equipment used, and control of process variables in mineral acid cleaning. The article then describes the advantages and disadvantages of organic acid cleaning. Applications, including boiler cleaning, stainless steel cleaning, and removal of iron- and copper-bearing deposits, are discussed. The article concludes with an overview of acid cleaning of nonferrous alloys.

This article focuses on high-temperature corrosion in synthetic gas (syngas) coolers. Extensive laboratory corrosion studies on both model and commercial alloys are summarized. The article describes the material selection criteria for long-term performance of materials in service. It provides information on the fuels with chlorine contents used in gasification plants.

This article explains the main types and characteristic causes of failures in boilers and other equipment in stationary and marine power plants that use steam as the working fluid with examples. It focuses on the distinctive features of each type that enable the failure analyst to determine the cause and suggest corrective action. The causes of failures include tube rupture, corrosion or scaling, fatigue, erosion, and stress-corrosion cracking. The article also describes the procedures for conducting a failure analysis.

This article discusses the methods of pulp production, pulp processing, pulp bleaching, and paper manufacturing. It describes various types of digesters, their construction materials, the corrosion problems encountered, and methods to protect these digesters from corrosion. The article examines the corrosion problems in high-yield mechanical pulping, sulfite process, neutral sulfite semichemical pulping, chemical recovery, tall oil plants, wastewater treatment, and recovery boilers. It explains the stages of chlorine-based and nonchlorine bleaching, process water reuse for elemental chlorine-free and nonchlorine bleaching stages, selection of material for bleaching equipment, developments in oxygen bleaching, and the use of highly corrosion-resistant materials for bleach plant equipment. The article reviews the materials used in the construction of paper machine components and specific corrosion problems that affect them. It discusses the composition and corrosive nature of white water. The article also addresses the corrosion and chemical recovery associated with kraft pulping liquors.

This article includes a collection of color images that aid in the identification and classification of forms of corrosion in industries and environments. It emphasizes the negative aspects of corrosion and examines the cost and the effort to test, evaluate, simulate, and prevent corrosion. The ability of corrosion to undo the best complex engineered systems has been documented.

The corrosion process that occurs in industrial systems is often difficult to discern until extensive deterioration has occurred. For boilers to function properly, the incoming water must be processed to meet the water quality required for the boiler. This article discusses pretreatment methods of the incoming water and preboiler corrosion protection methods. It analyzes internal treatment and condensate treatment of boilers. The article discusses three types of cooling systems: once-through systems, open recirculating systems, and closed recirculating systems. The corrosion processes which occur in water-recirculating systems and the effect of dissolved gases, temperature, pH, suspended solids, dissolved salts, and scale deposition on corrosivity of water, are also reviewed. The article also considers anodic and cathodic inhibitors and the control of corrosion in municipal water systems.

Low-alloy steels are used in a broad spectrum of applications. In some cases, corrosion resistance is a major factor in alloy selection; in other applications, it is only a minor consideration. This article reviews the applications of alloy steel products in four major industries, namely, oil and gas production, energy conversion systems, marine applications, and chemical processing. Emphasis is placed on the corrosion characteristics of the products, which are used in various applications of each industry.

This article provides a discussion on the mechanisms of wear and their interactions with gaseous corrosion. The wear mechanisms include abrasive, erosive, fretting, and sliding. The measurement of degradation on combustion walls in coal-fired boilers is discussed. The article concludes with information on the common coating techniques used for wear-corrosion control.