Solidification of cast iron alloys brings about volumetric changes. This article describes direct measurements of volume changes with an illustration of the analysis of volumetric changes during solidification of cast iron with the use of a specially designed riser combined with a furnace. It provides a discussion on the dilatometer analysis that is generally used to measure linear displacement as a function of temperature for all types of materials, and the problems associated with volume-change measurements. The article presents a graphical representation of a consequence of the anisotropy, where the calculated volume change is illustrated as a function of temperature. It concludes with a review of kinetic of graphite expansion.

In the case of steels, heat treatment plays a fundamental role because no other process step can manipulate the microstructure in order to fulfill such a wide variety of possible in-service conditions. This article addresses heat treatment with regard to hardening and subsequent tempering of steel components in order to optimize tribological properties. It focuses on the heat treatment of tempering and bearing steels and on volume changes that take place due to phase transformations. Plastic deformations that occur due to shrinking and phase transformation are also discussed. The article also describes the generation of thermal, transformation, and hardening residual stresses.

In cast iron, residual stresses normally arise due to hindered thermal contraction, meaning that they are associated with the presence of constraints that prevent the natural, free volumetric variation of the material upon solid-state cooling. This article explains their mechanism of formation by introducing the scalar relation, known as the additive strain decomposition. The main factors influencing casting deformation are volume changes during solidification and cooling, phase transformations, alloy composition, thermal gradients, casting geometry, and mold stability. The article reviews the dimensional stability in cast iron and discusses macroscopic and microscopic stresses in cast iron.