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volatile organic compounds
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Published: 30 September 2015
Fig. 6 Polydimethyl siloxane fluid. VOC, volatile organic compound. R = methyl; n = 0 to 3000 n 0–1 2–25 30–250 300–1500 1800–3000 VOC exempt diluent Flow and anti-float Slip and mar resistance Defoaming, antiblocking Hammertone
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Image
Published: 30 September 2015
Fig. 2 Trend in volatile organic compound (VOC) emissions, 1940 to 1998. Environmental Protection Agency figures show the reversal of VOC emissions after hitting the highest around 1970. Note: Some fluctuations in the years before 1970 are the result of different methodologies. Source: Ref 7
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Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006051
EISBN: 978-1-62708-172-6
... be incorporated into the formulation; and volatile components such as solvents, or water in emulsions and their composition. It provides general information on volatile organic compounds. The article describes the film-forming mechanisms of various coating types, namely, lacquers, chemically converting coatings...
Abstract
A coating can be defined as a substance spread over a surface to provide protection or to serve decorative purposes. This article discusses two industrial coating components, namely, nonvolatile components such as the resin or binder, pigments, and any additives that may be incorporated into the formulation; and volatile components such as solvents, or water in emulsions and their composition. It provides general information on volatile organic compounds. The article describes the film-forming mechanisms of various coating types, namely, lacquers, chemically converting coatings, latex coatings, alkyds and other resins, which cure by oxidation, moisture-curing polyurethanes and inorganic zinc primers, and powder coatings. The article concludes with a discussion on the functions of the primer, intermediate coat, and topcoat in coating systems.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003050
EISBN: 978-1-62708-200-6
... and Recovery Act and Clean Air Act. The Clean Air Act requires all states to meet minimum emissions standards for nitrogen-oxygen compounds, volatile organic compounds, and carbon monoxide. ceramic environmental regulations glass in-process scrap industrial waste recycling LIKE MOST OTHER...
Abstract
Ceramic and glass manufacturers take environmental regulations into consideration during all stages of the product cycle, from research and development to purchasing, processing, end use, and disposal. Ceramic and glass products are finding application in the construction industry and as raw materials for other processes. This article describes the recycling of in-process scrap and industrial wastes (fly ash, red mud, metallurgical waste, and other waste products), and applications of these recycled products. It focuses on environmental regulations such as Resource Conservation and Recovery Act and Clean Air Act. The Clean Air Act requires all states to meet minimum emissions standards for nitrogen-oxygen compounds, volatile organic compounds, and carbon monoxide.
Image
Published: 01 January 1997
Fig. 9 Selected airborne emissions for the production, use, recycling, and reuse of different fender materials. NMVOC, nonmethane volatile organic compound. Source: Ref 1
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Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006060
EISBN: 978-1-62708-172-6
... and regulatory environments, and the importance of performance during the duty cycle. energy consumption environmental safety green coatings industrial paints recycling volatile organic compound emission GREEN COATINGS have become an important part of the world's industry and economy. The 2012...
Abstract
This article presents a background of green chemistry and green coatings, and a summary of the key concerns of the green coating procurement process. It includes a discussion on green marketing and the seven sins of greenwashing, an overview of the environmental certification standards and regulatory environments, and the importance of performance during the duty cycle.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001326
EISBN: 978-1-62708-170-2
...% beginning Jan 1993, 100% by Jan 1996. (Air Force will ban purchases after April 1994) Alternate Materials Innovative methods will be required to develop wipe solvent materials that will meet EPA requirements for the emission of volatile organic compounds, the reduction or elimination of hazardous...
Abstract
Wipe solvents are used to remove contaminants from a workpiece before it undergoes manufacturing operations that require clean surfaces, such as bonding, sealing, painting, welding, plating, specialized surface treatment procedures, and others. This article describes the evaluation parameters for wipe solvent cleaners, including methyl ethyl ketone, methyl isobutyl ketone, trichloroethene, tetrachloroethylene, acetone, toluene, dichloromethane, benzene, xylene, and other alternate wipe solvent cleaners. It contains a table that lists the compositions and properties of wipe solvent cleaners.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001325
EISBN: 978-1-62708-170-2
.... Its method of control is to designate the maximum allowable specific weight of volatile organic compounds (VOCs) per unit volume of material. In Rule 1124 the limits are expressed in grams per liter; other regulations may use pounds per gallon. Following are the definitions used in this rule...
Abstract
This article discusses coating products available for use in the aerospace industry that are compliant with regulations requiring reductions in emissions from organic solvents. The coating products addressed include primers, topcoats, and chemical milling maskants. It describes their characteristics and limitations compared to conventional noncompliant materials. The article addresses the methods and products commonly used achieve regulatory compliance: waterborne coatings, exempt-solvent-based coatings, high-solids coatings, powder coating, and electro-deposition.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003691
EISBN: 978-1-62708-182-5
... of paints containing such pigments are effectively precluding their use in most new coating formulations. Similarly, restrictions regarding volatile organic compounds (VOCs) in coatings have been enacted gradually over the last 10 years in order to allow formulators to develop comparable paint materials...
Abstract
This article presents an overview of the different types of coating and lining materials available. It provides information on the various means of surface preparation and the equipment and techniques of coating application. The article discusses the coatings industry's response to the enacted as well as proposed legislation of limiting the use of potentially harmful or toxic raw materials or surface preparation and/or application techniques. The article summarizes the existing federal regulations affecting the coatings industry categorized according to the requirements of the Environmental Protection Agency and the Occupational Safety and Health Administration as well as the corresponding Code of Federal Regulation numbers.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001321
EISBN: 978-1-62708-170-2
...: Reduce or eliminate the use of volatile organic compounds (VOCs), which create smog through photochemical reactions. Most VOCs will be reduced, categorically, by industry group. Control, reduce, or eliminate 189 chemicals determined to be hazardous air pollutants (HAPs). Under the National Emission...
Abstract
This article describes selected U.S. environmental statutes and regulations that are pertinent to material surface finishers. It provides information on the applicability, requirements, and permitting conditions of the Clean Air Act, the Resources Conservation and Recovery Act, the Superfund Amendments and Reauthorization Act, and the Clean Water Act.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003212
EISBN: 978-1-62708-199-3
... related directly or indirectly to surface engineering processes. This is particularly applicable for solvent cleaning procedures, cadmium and chromium electroplating, chromate conversion coatings, and organic coatings containing high amounts of volatile organic compounds (solvents). The chemicals used...
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001317
EISBN: 978-1-62708-170-2
... 2 SO 4 V 2 O 5 /SiO 2 (pellet) Environmental processes: catalysts on monoliths Three-way catalyst automotive catalyst CO + hydrocarbons + NO → CO 2 + H 2 O + N 2 Pt, Rh, Pd/Al 2 O 3 /Ce Volatile organic compound destruction Hydrocarbons + O 2 → CO 2 + H 2 O Pt/Al 2 O 3...
Abstract
The chemical process being catalyzed should have a high productivity within a specified reactor volume with high reaction rates for the desired reactions and low rates for undesired reaction pathways. This article reviews the general catalyst preparation procedures, namely, impregnation, ion exchange, and precipitation. Catalyst carriers are usually high-surface-area inorganic materials with complex pore structures, into which catalytic materials such as palladium, platinum, cobalt, chromium oxide, and vanadium pentoxide are deposited using these procedures. The article also provides information on catalyst powder processing.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003693
EISBN: 978-1-62708-182-5
.... Vinyl and chlorinated rubber binders are not volatile-organic- compound compliant and are not currently in use. To manufacture a successful organic zinc-rich coating, one does not simply substitute the zinc- dust pigment for the normal inhibitive and filler pigments commonly used. Instead, skillful...
Abstract
This article describes the characteristics of zinc-rich coatings that can be subcategorized according to the type of binder material used. It discusses the formulations of zinc-rich coatings with organic binders. The three major groups of inorganic zinc-rich coatings categorized by the Society for Protective Coatings are also discussed. These include postcured water-based alkali metal silicates, self-cured water-based alkali metal silicates, and self-cured solvent-based alkyl silicates. The article concludes with information on comparisons of inorganic with organic zinc-rich coatings.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006028
EISBN: 978-1-62708-172-6
... and ethoxy groups, respectively. Larger alcohols can also be used, but these result in less reactive leaving groups and, on application, generate a higher level of volatile organic compounds (VOCs). Inorganic alkoxy functionality provides silanes with chemical benefits not available to organic polymers...
Abstract
This article focuses on those areas of coatings technology where silicon-based technology (SBT) is the primary enabling technology and where SBT is used as an additive to provide unique properties to the coating film. It describes the chemistry and the uses of alkoxy silanes. The uses of silicates, siliconates, silicone fluids, and silicone resins in coatings are reviewed. The article discusses the various applications of SBT, namely, primers, heat-resistant coatings, industrial maintenance coatings, hygienic coatings, and abrasion-resistant coatings, and for marine biofouling control. It also provides information on the benefits of silicon-base additives.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003698
EISBN: 978-1-62708-182-5
... the capabilities of correlation methods based on linearization of free energy and constants of volatility for estimation of the vapor pressure of organic VCIs. Ways to optimally choose a VCI and control modification of the structures of compounds belonging to various classes for achieving optimum volatility...
Abstract
This article discusses the definitions, classifications, structural features, vapor pressure values, corrosion inhibition mechanisms, and methods of evaluation of vapor-phase-corrosion inhibitors or volatile corrosion inhibitors (VCIs). Practical methods of using VCIs for corrosion protection of aluminum, ferrous, and nonferrous alloys are discussed with specific examples. The article contains tables that summarize the applications of different VCIs used for protecting ferrous metals, copper and its alloys, and silver.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001224
EISBN: 978-1-62708-170-2
... by the process control capability of the equipment. Volatile Organic Compounds (VOC) Volatile organic compounds (VOC) are emitted from the emulsion, particularly when it is heated, so adequate ventilation is vital. Depending on the type and volume of solvent discharge, the vent may need carbon absorption...
Abstract
Emulsion cleaning is an industrial cleaning process that uses an organic solvent as the main active agent. This article provides information on the applications, concerns and limitations, and process parameters of emulsion cleaning. It describes the processing variables and equipment for three main stages of emulsion cleaning: immersion cleaning, secondary cleaning, and spray cleaning. In addition, the classifications, composition, and selection criteria are also discussed.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006049
EISBN: 978-1-62708-172-6
... in the automotive industry. Vinyl and chlorinated rubber binders, although once popular, are not volatile organic compound compliant and are not currently in use. To manufacture a successful organic zinc-rich coating, one does not simply substitute the zinc-dust pigment for the normal inhibitive and filler...
Abstract
The use of zinc in corrosion-protective coatings is due to its higher galvanic activity relative to that of steel. Pure zinc dust provides the best sacrificial protection to steel in a galvanic couple. Zinc-rich coatings can be subcategorized according to the type of binder material used, namely, inorganic and organic zinc-rich coatings. Common inorganic binders such as post-cured water-based alkali metal silicates, self-cured water-based alkali metal silicates, and self-cured solvent-based alkyl silicates, are reviewed. The article also compares inorganic and organic zinc-rich coatings, and discusses the concerns regarding zinc-rich coatings.
Book Chapter
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0005754
EISBN: 978-1-62708-195-5
... stereolithography VHP vacuum hot pressing identical with SLS selective laser sintering VLS vapor-liquid-solid greater than SM standard modulus Vm volume fraction of matrix k much greater than SMC sheet molding compound VOC volatile organic compound greater than or equal to SMC-C sheet molding compound...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006037
EISBN: 978-1-62708-172-6
...) Ease of maintenance (seamless, permanent finish, maintain hygienic condition) Adhesion (permanent adhesion to substrate) Decorative and/or functional design options Solvent-free (or very low volatile organic compound, or VOC, formulations, easily meeting VOC and indoor air quality requirements...
Abstract
Polymeric floor coatings refer to flooring materials composed of multicomponent thermoset resins formulated with various fillers and pigments that are installed in situ, usually over concrete substrates. Polymeric flooring systems, specified for all industrial and commercial environments, use a variety of polymer chemistries and are constructed in a variety of methods and designs. This article provides a description of the service conditions for the polymeric flooring systems. It provides information on polymeric flooring systems, including thin-film coatings, self-leveling systems, membrane systems, broadcast systems, troweled systems, and terrazzo. The article also focuses on properties, applications, testing, and factors and requirements to be considered during the installation of polymeric floor coatings. It concludes with a discussion about coating failures, including bonding, cracking, chemical attack, and moisture that affect the polymeric floor coatings on concrete.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006029
EISBN: 978-1-62708-172-6
... resistance. With the rising cost of both labor and oil-based resins, the drive for reduction of volatile organic compounds (VOCs), and the demand for long-term durability, there is growing interest in polysiloxane hybrids. Polysiloxanes are used in premium topcoat finishes and have facilitated the trend...
Abstract
This article focuses on technologies in the protective coatings field, namely, polysiloxane hybrids and related materials. Industrial maintenance topcoats, including silicone alkyds, silicone epoxies, and polysiloxanes are reviewed. The article discusses two major application areas of protective coatings, namely, architectural coatings and automotive clear coats.
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